[Ag(saccharinato)(N,N-bis(pyridin-2-ylmethyl)amine)](n) | 1226813-79-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Ag(saccharinato)(N,N-bis(pyridin-2-ylmethyl)amine)](n)
• 英文别名: [Ag(sac)(bpma)](n)
• CAS: 1226813-79-1
• 化学式: C₁₉H₁₇AgN₄O₃S
• 分子量: 489.303
• InChiKey: ODXWTUYNMMELPC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ag(saccharinato)(N,N-bis(pyridin-2-ylmethyl)amine)](n) 在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 银
  参考文献：
  名称：

  Dimeric and polymeric silver(I) saccharinato complexes of two bis(pyridine) ligands: Synthesis, structural, spectroscopic, fluorescent and thermal properties

  摘要：

  The reaction of silver(I) with 1,2-bis[1-(pyridin-2-yl)ethylidene]hydrazine (bpeh) and N,N-bis(pyridin-2-ylmethyl)amine (bpma) in the presence of Na(sac) (sac = saccharinate) yielded [Ag-2(sac)(2)(bpeh)] (1) and [Ag(sac)(bpma)](n) (2) with conformational chirality. Both complexes have been characterized by elemental analysis, IR, thermal analysis and X-ray single crystal diffraction. Complex 1 displays a binuclear composition, in which each silver(I) ion is bound to one monodentate sac ligand and one of the bidentate pyridylimino groups of the bpeh ligand in a distorted trigonal coordination geometry. Complex 2 is a one-dimensional helical polymer, in which silver(I) centers are bridged by tridentate bpma ligands, and each silver(I) ion is coordinated in a distorted tetrahedral geometry by one monodentate sac ligand, a bidentate pyridylamine group of one bpma ligand, and a pyridylimino group of another bpma ligand. Weak intermolecular C-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi interactions lead to assembly of 1 and 2 into threedimensional supramolecular frameworks. Spectral and thermal analysis data for 1 and 2 are in agreement with the crystal structures. In addition, both complexes in the solid state display intraligand pi-pi* fluorescence. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.01.019
• 作为产物：
  描述：

  sodium saccharinate dihydrate 、 二甲基吡啶胺 、 silver nitrate 以 further solvent(s) 为溶剂， 以90%的产率得到[Ag(saccharinato)(N,N-bis(pyridin-2-ylmethyl)amine)](n)
  参考文献：
  名称：

  Dimeric and polymeric silver(I) saccharinato complexes of two bis(pyridine) ligands: Synthesis, structural, spectroscopic, fluorescent and thermal properties

  摘要：

  The reaction of silver(I) with 1,2-bis[1-(pyridin-2-yl)ethylidene]hydrazine (bpeh) and N,N-bis(pyridin-2-ylmethyl)amine (bpma) in the presence of Na(sac) (sac = saccharinate) yielded [Ag-2(sac)(2)(bpeh)] (1) and [Ag(sac)(bpma)](n) (2) with conformational chirality. Both complexes have been characterized by elemental analysis, IR, thermal analysis and X-ray single crystal diffraction. Complex 1 displays a binuclear composition, in which each silver(I) ion is bound to one monodentate sac ligand and one of the bidentate pyridylimino groups of the bpeh ligand in a distorted trigonal coordination geometry. Complex 2 is a one-dimensional helical polymer, in which silver(I) centers are bridged by tridentate bpma ligands, and each silver(I) ion is coordinated in a distorted tetrahedral geometry by one monodentate sac ligand, a bidentate pyridylamine group of one bpma ligand, and a pyridylimino group of another bpma ligand. Weak intermolecular C-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi interactions lead to assembly of 1 and 2 into threedimensional supramolecular frameworks. Spectral and thermal analysis data for 1 and 2 are in agreement with the crystal structures. In addition, both complexes in the solid state display intraligand pi-pi* fluorescence. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.01.019