2,2-Bis-tert.-pentylepidioxy-propan | 3052-70-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 2,2-Bis-tert.-pentylepidioxy-propan
• 英文别名: 2,2-Di-(t-amylperoxy)-propan；bis-(1,1-dimethyl-propyl) 1-methyl-ethane-1,1-diyl bis-peroxide；2,2-di(t-amylperoxy)propane；2,2-Bis(tert-amylperoxy)propane；2-methyl-2-[2-(2-methylbutan-2-ylperoxy)propan-2-ylperoxy]butane
• CAS: 3052-70-8
• 化学式: C₁₃H₂₈O₄
• 分子量: 248.363
• InChiKey: PHIGUQOUWMSXFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  特戊基过氧化氢 、 丙酮 在 盐酸 、 calcium chloride 作用下， 生成 2,2-Bis-tert.-pentylepidioxy-propan
  参考文献：
  名称：

  Nazarova,Z.F. et al., Journal of general chemistry of the USSR, 1964, vol. 34, p. 2444 - 2446

  摘要：

  DOI：

文献信息

• Fluorinated crosslinker and composition
  申请人：——

  公开号：US20020111518A1

  公开（公告）日：2002-08-15

  Fluorinated multifunctional alcohols containing at least 3 primary hydroxyl groups are disclosed. Such alcohols allow for easy synthesis of multifunctional crosslinkers such as acrylates, epoxies and vinyl ethers. The multifunctional crosslinkers are used in fluorinated optical coating and waveguide compositions to increase curing speed and crosslinking density.

  揭示了含有至少3个主要羟基的氟化多功能醇。这些醇可用于易于合成多功能交联剂，如丙烯酸酯、环氧树脂和乙烯醚。多功能交联剂用于氟化光学涂层和波导组合物中，以增加固化速度和交联密度。
• Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
  申请人：Esseghir Mohamed

  公开号：US20080085973A1

  公开（公告）日：2008-04-10

  Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

  在可交联聚合物（例如EPDM）的自由基交联过程中，通过在熔融处理和交联之前将TEMPO化合物的衍生物（优选为醚、酯或脲衍生物）的防燃剂添加到聚合物中，可以抑制烧焦。本发明的防燃剂在类似的聚合物组合物和相似条件下，与其4-羟基四氢碳基哌啶-1-氧基衍生物相比，在防燃和最终交联程度方面表现得同样好，甚至更好，但在聚合物组合物中挥发性和迁移性都较小。
• Foamable compositions
  申请人：HENKEL LOCTITE CORPORATION

  公开号：US20040063800A1

  公开（公告）日：2004-04-01

  This invention relates to latent foamable compositions for use in or as adhesives, sealants and/or coatings. The compositions include a curable component or a thermoplastic component, together with a latent foaming agent. In curable versions of the inventive compositions, a cure initiator or catalyst may also be included.

  本发明涉及用于粘合剂、密封剂和/或涂料的潜伏性发泡组合物。该组合物包括可固化组分或热塑性组分，以及潜伏性发泡剂。在本发明组合物的可固化版本中，还可以包括固化引发剂或催化剂。
• DIACYLOXYSILANE-BASED, MOISTURE-CROSSLINKABLE ETHENE POLYMERS
  申请人：Daiss Juergen Oliver

  公开号：US20130022770A1

  公开（公告）日：2013-01-24

  Polyethylene homo or copolymers which further contain grafted or copolymerized vinyldiacyloxysilanes are easily processable without premature crosslinking, are easily formed into shaped articles by conventional processing methods, and yet rapidly crosslink to form crosslinked polymers.

  聚乙烯同质或共聚物，进一步含有嫁接或共聚的乙烯二酰氧基硅烷，可在没有过早交联的情况下轻松加工，可通过传统的加工方法轻松成型，并快速交联形成交联聚合物。
• PRIMER MIXTURE OF CROSSLINKING INITIATOR AND PROMOTER
  申请人：ARKEMA FRANCE

  公开号：US20150239997A1

  公开（公告）日：2015-08-27

  A primer mixture intended for crosslinking polyethylene, including at least an initiator of free radicals chosen from organic peroxides, azo compounds or mixtures thereof, wherein the mixture has said free-radical initiator and at least one crosslinking promoter chosen from the cycloalkanes having 5 to 7 carbon atoms, substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the aromatic compounds substituted by 1 to 3 vinyl, allyl or isopropenyl groups, the methacrylate, acrylate and maleimide monomers being multi-substituted, and in that the weight ratio of free-radical initiator to the crosslinking promoter is greater than or equal to 1, and preferably between 1.5 and 4. Also, a method and to a use related to this primer mixture.

  一种用于交联聚乙烯的底漆混合物，包括至少一种自由基引发剂，所述自由基引发剂选择自有机过氧化物、偶氮化合物或其混合物中的一种，其中混合物具有所述自由基引发剂和至少一种选择自于环戊烷、环己烷、环庚烷的交联促进剂，所述交联促进剂被1至3个乙烯基、丙烯基或异丙烯基取代的，被1至3个乙烯基、丙烯基或异丙烯基取代的芳香族化合物，以及多取代的甲基丙烯酸酯、丙烯酸酯和马来酰亚胺单体，其中自由基引发剂与交联促进剂的重量比大于或等于1，且优选在1.5至4之间。此外，还涉及一种与该底漆混合物相关的方法和用途。