2-Tridecensaeuremethylester

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-Tridecensaeuremethylester
• 英文别名: 2-Tridecenoic acid methylester；Methyl tridec-2-enoate；methyl tridec-2-enoate
• 化学式: C₁₄H₂₆O₂
• 分子量: 226.359
• InChiKey: FZKILUWDXTYCDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  甲醇 、 1-十二烯十二碳烯α-十二碳烯α-十二碳烯 、 一氧化碳 在 1-methyl-3-(3-sulfopropyl)-imidazolium para-toluenesulfonate 、 palladium diacetate 、 三苯基膦 作用下， 69.84 ℃ 、2.0 MPa 条件下， 反应 1.67h， 生成 2-Tridecensaeuremethylester 、 methyl 2-methylenedodecanoate
  参考文献：
  名称：

  Brønsted acidic ionic liquid as an efficient and recyclable promoter for hydroesterification of olefins catalyzed by a triphenylphosphine–palladium complex

  摘要：

  Several Bronsted acidic ionic liquids (BAILs) with different acidic scales were synthesized and employed as acid promoters for the hydroesterification of olefins catalyzed by a triphenylphosphine-palladium complex. The results showed that catalysts with BAIL promoters resulted in moderate to high conversions to the ester product with excellent selectivity, depending on the acidity of BAIL used. The reaction conversion reached a plateau when the catalyst was promoted using BAIL with a Hammett acidity function less than or equal to -0.11. This catalyst system could be reused several times for the hydroesterification of 1-hexene without a considerable decrease in the catalytic performance. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2010.05.025

文献信息

• Room-temperature Pd-catalyzed methoxycarbonylation of terminal alkynes with high branched selectivity enabled by bisphosphine-picolinamide ligand
  作者：Ding Liu、Miaolin Ke、Tong Ru、Yingtang Ning、Fen-Er Chen

  DOI：10.1039/d1cc06098h

  日期：——

  The challenging room temperature Pd-catalyzed methoxycarbonylation for a wide array of alkynes with excellent branched selectivity has been developed.

  已开发出具有出色支链选择性的广泛烯烃室温Pd催化的甲氧羰基化反应。
• Regioselective Hydromethoxycarbonylation of Terminal Alkynes Catalyzed by Palladium(II)–Tetraphos Complexes
  作者：Werner Oberhauser、Andrea Ienco、Francesco Vizza、Barbara Trettenbrein、Dennis Oberhuber、Christof Strabler、Teresa Ortner、Peter Brüggeller

  DOI：10.1021/om3003812

  日期：2012.7.9

  An in situ generated dinuclear palladium hydride complex bearing cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphanyl)cyclobutane catalyzed the hydromethoxycarbonylation of terminal alkynes, giving the corresponding branched α,β-unsaturated ester (A) with high regioselectivity.

  原位生成的双核氢化钯配合物，带有顺，反，顺- ，1,2,3,4-四（二苯基膦基）环丁烷，催化末端炔烃的加氢甲氧基羰基化反应，得到相应的支链α，β-不饱和酯（A），具有高区域选择性。