9-Oxo-dec-2-en-saeure | 2575-01-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 9-Oxo-dec-2-en-saeure
• 英文别名: 9-Oxo-decenoic acid；9-oxodec-2-enoic acid
• CAS: 2575-01-1
• 化学式: C₁₀H₁₆O₃
• 分子量: 184.235
• InChiKey: INJRDZMWIAYEMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2918300090

反应信息

• 作为反应物：
  描述：

  9-Oxo-dec-2-en-saeure 在 sodium hydroxide 、 肼 作用下， 生成 正癸酸
  参考文献：
  名称：

  Barbier,M.; Lederer,E., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1960, vol. 250, p. 4467 - 4469

  摘要：

  DOI：
• 作为产物：
  描述：

  3-(6-oxoheptyl)oxolane-2,5-dione 在 吡啶 、 lead(IV) acetate 、 sodium hydroxide 、 methyl 9-oxo-3-decenoate 、 水 、 copper diacetate 作用下， 以 甲醇 为溶剂， 反应 19.75h， 生成 9-Oxo-dec-2-en-saeure
  参考文献：
  名称：

  Dhokte, U. P.; Rao, A. S., Synthetic Communications, 1987, vol. 17, # 3, p. 355 - 368

  摘要：

  DOI：

文献信息

• METHOD OF SYNTHESISING AMINO ACID BY METATHESIS, HYDROLYSIS, THEN HYDROGENATION
  申请人：ARKEMA FRANCE

  公开号：US20160002147A1

  公开（公告）日：2016-01-07

  A method of synthesising an amino acid from an unsaturated fatty compound I that includes at least the following steps: cross-metathesis with a short unsaturated compound II, one of compounds I or II comprising a nitrile function and the other of these compounds II or I an ester function, so as to obtain and recover at least one monounsaturated nitrile ester NEU; hydrolysis of the NEU in unsaturated acid nitrile NAU; hydrogenation of the NAU to saturated amino acid AA; and then purification of the AA, if applicable, in particular by crystallisation. Also, a polymer obtained by polymerisation using the amino acid synthesised according to the method.

  一种从不饱和脂肪化合物I合成氨基酸的方法，包括至少以下步骤：与短链不饱和化合物II进行交叉转化反应，其中化合物I或II中的一个包含腈基，而另一个化合物II或I包含酯基，以获得和回收至少一种单不饱和腈酯NEU；将NEU水解为不饱和酸腈NAU；将NAU加氢为饱和氨基酸AA；然后通过结晶等方法对AA进行纯化，如果需要的话。此外，通过使用根据该方法合成的氨基酸进行聚合得到的聚合物。
• COMBINED SYNTHESIS OF A NITRILE-ESTER/ACID AND OF A DIESTER/DIACID
  申请人：ARKEMA FRANCE

  公开号：US20160016894A1

  公开（公告）日：2016-01-21

  A method for the combined synthesis of a mono-unsaturated nitrile-ester(acid) and of a bi-functional carbonyl compound, wherein it includes a step including the cross metathesis mc1 of an unsaturated fatty acid/ester compound with an unsaturated nitrile compound, in which mc1 is performed with partial conversion such as to obtain and recover, separately, at least the following products: a mono-unsaturated nitrile-ester/acid and a symmetrical compound, diester or diacid respectively including a double bond located in the middle of the molecular chain of compound, and subsequently a step including the oxidation cleavage cp2 of the double bond of compound, such as to form a single type of carbonyl compound having formula R2-(CH2)n-COR′, in which R′ is H or OH, depending on the operating conditions selected for the oxidation cleavage cp2. Also, the production of monomers for the polymer industry.

  一种用于合成单不饱和腈酯（酸）和双官能羰基化合物的联合合成方法，其中包括一步骤，包括将不饱和脂肪酸/酯化合物与不饱和腈化合物进行交叉重排mc1的步骤，其中mc1是以部分转化进行的，以便分别获得和回收至少以下产品：单不饱和腈酯/酸和对称化合物，二酯或二酸，分别包括分子链中间位置的双键，并随后包括氧化裂解化合物的双键的步骤cp2，以形成具有化学式R2-(CH2)n-COR′的一种类型的羰基化合物，其中R′为H或OH，取决于选择用于氧化裂解cp2的操作条件。此外，用于聚合工业的单体的生产。
• Compositions and Methods for Making and Modifying Oils
  申请人：Lam David

  公开号：US20080305531A1

  公开（公告）日：2008-12-11

  The invention provides novel methods for making or modifying oils, e.g., plant, animal or microbial oils, such as vegetable oils or related compounds, that are low in a particular fatty acid(s), for example, low linoleic oils, low linolenic oils, low palmitic oils, low stearic oils or oils low in a combination thereof.

  该发明提供了制备或修改油脂的新方法，例如植物、动物或微生物油脂，如低亚油酸油、低亚麻酸油、低棕榈酸油、低硬脂酸油或低上述组合油的植物油或相关化合物。
• COMPOSITIONS AND METHODS FOR MAKING AND MODIFYING OILS
  申请人：DSM IP ASSETS B.V.

  公开号：US20160168604A1

  公开（公告）日：2016-06-16

  The invention provides novel methods for making or modifying oils, e.g., plant animal or microbial oils, such as vegetable oils or related compounds, that are low in a particular fatty acid(s), for example, low linoleic oils, linolenic oils, low palmitic oils, low stearic oils or oils low in a combination thereof.

  该发明提供了一种制造或修改油的新方法，例如植物、动物或微生物油，如低亚油酸油、亚麻酸油、低棕榈酸油、低硬脂酸油或低以上脂肪酸组合的油。
• Propranolol immunogens, antibodies thereto, test device and compounds for propranolol immuno assay
  申请人：MILES LABORATORIES, INC.

  公开号：EP0095639A2

  公开（公告）日：1983-12-07

  Propanol immunogens which are 3-(1-naphthoxy)-2-hydroxypropylamine and 3-N-[2-hydroxy-3-(1-naphthoxy)-1-propyl] aminobutyric acid coupled to an immunogenic carrier; antibodies prepared therefrom, a labelled conjugate of 3-N-[2-hydroxy-3-(1-naphthoxy)-1-propyl] aminobutyric acid intermediates; an immunoassay method; a test kit and test device.

  丙醇免疫原，即 3-(1-萘氧基)-2-羟基丙胺和 3-N-[2-羟基-3-(1-萘氧基)-1-丙基]氨基丁酸与免疫原载体偶联；由此制备的抗体、3-N-[2-羟基-3-(1-萘氧基)-1-丙基]氨基丁酸中间体的标记共轭物；免疫测定方法；试剂盒和测试装置。