6-peroxy-7(9)-dehydro-2,3,6,7-tetrahydrogeranyl acetate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 6-peroxy-7(9)-dehydro-2,3,6,7-tetrahydrogeranyl acetate
• 英文别名: (6-Hydroperoxy-3,7-dimethyloct-7-enyl) acetate；(6-hydroperoxy-3,7-dimethyloct-7-enyl) acetate
• 化学式: C₁₂H₂₂O₄
• 分子量: 230.304
• InChiKey: MHAOGLXADUGTJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  乙酸香茅酯 在 bis(dimethyl-di-n-octylammonium) molybdate 、 双氧水 作用下， 以 环己烷 、 水 为溶剂， 反应 6.6h， 以66%的产率得到(7-Hydroperoxy-3,7-dimethyloct-5-enyl) acetate
  参考文献：
  名称：

  Synergy between bis(dimethyldioctylammonium) molybdate and tetraethylene glycol monooctyl ether: A winning combination for interfacial catalysis in thermo-controlled and switchable microemulsions

  摘要：

  A simple thermo-responsive one-phase microemulsion (mu em) is designed to enable the dark singlet oxidation of organic substrates while allowing a straightforward separation of the catalytic surfactant and products in two distinct phases by cooling down the reaction medium. This latter is prepared by combining a small amount (1%) of the catalytic surfactant bis(dimethyldioctylammonium) molybdate, [DiC(8)]a[MoO4], with the nonionic amphiphile tetraethylene glycol monooctyl ether, C8E4. Tensiometry and dynamic light scattering are used to rationalize the synergy between the two surfactants which strongly interact. The oxidation takes place in the effective one-phase Winsor IV system which separates into two phases (mu em + oil, i.e. Winsor I) just by temperature change thanks to the presence of the thermosensitive C8E4. The thermal-controlled nanostructured reaction medium is applied to the ene reaction, [4+2] cycloaddition and sulfide oxidation. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2014.11.003