N,N'-dimethyl-N,N'-diphenyl-1,4-benzenedicarboxamide | 36360-29-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dimethyl-N,N'-diphenyl-1,4-benzenedicarboxamide
• 英文别名: N,N'-dimethylterephthalic dianilide；Terephthalsaeure-bis-(N-methyl-anilid)；N,N'-dimethyl-N,N'-diphenylterephthalamide；Terephthalsaeure-bis-methylanilid；N,N'-Dimethyl-N,N'-diphenyl-terephthalamid；Terephthalic acid, diamide, N,N'-dimethyl-N,N'-diphenyl-；1-N,4-N-dimethyl-1-N,4-N-diphenylbenzene-1,4-dicarboxamide
• CAS: 36360-29-9
• 化学式: C₂₂H₂₀N₂O₂
• mdl: MFCD01212594
• 分子量: 344.413
• InChiKey: VHQIQHOWOUXCLB-UHFFFAOYSA-N

物化性质

• 沸点：
  535.7±46.0 °C(Predicted)
• 密度：
  1.211±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-dimethyl-N,N'-diphenyl-1,4-benzenedicarboxamide 在 氯 作用下， 以 四氯化碳 、 氯苯 为溶剂， 生成 1-N,4-N-bis(chloromethyl)-1-N,4-N-diphenylbenzene-1,4-dicarboxamide
  参考文献：
  名称：

  Reimlinger,H. et al., Chemische Berichte, 1978, vol. 111, p. 1619 - 1626

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N-二甲基苯胺 、 对苯二甲酰氯 生成 N,N'-dimethyl-N,N'-diphenyl-1,4-benzenedicarboxamide
  参考文献：
  名称：

  Bogert; Nisson, Proceedings of the National Academy of Sciences of the United States of America, vol. 10, p. 423

  摘要：

  DOI：

文献信息

• Facile amidation of esters with aromatic amines promoted by lanthanide tris (amide) complexes
  作者：Zhao Li、Chenjun Guo、Jue Chen、Yingming Yao、Yunjie Luo

  DOI：10.1002/aoc.5517

  日期：2020.4

  The development of catalysts capable of catalyzing amidation of esters with amines to construct amides under mild conditions is of great importance. Compared to aliphatic amines, the direct catalytic amidation of esters with less nucleophilic aromatic amines is rather difficult. Employing simple lanthanide tris (amide) complexes Ln[N (SiMe3)2]3(μ‐Cl)Li (THF)3 as the catalysts, it was found a broad

  在温和条件下开发能够催化酯与胺酰胺化以构建酰胺的催化剂非常重要。与脂族胺相比，酯与较少亲核芳族胺的直接催化酰胺化相当困难。采用简单的镧系元素三（酰胺）络合物LN [N（森达3）2 ] 3（μ -Cl）的Li（THF）3作为催化剂，已发现宽范围的芳族胺和酯的被有效地转换成以各种酰胺在温和的条件下丰产。从镧系元素三（酰胺）配合物与底物胺之间的酰胺交换反应开始，实验上证实了这种转化的合理机制。
• Cellulose Compound Film, Optical Compensation Sheet, Polarizing Plate, and Liquid Crystal Display Device
  申请人：Nozoe Yutaka

  公开号：US20070259134A1

  公开（公告）日：2007-11-08

  A cellulose compound film containing a cellulose compound having two or more substituents whose polarizability anisotropies Δα calculated by mathematical formula (1) are different from each other, wherein substitution degrees of the following substituents A and B in the cellulose compound satisfy relationship as defined by mathematical formula (A1), in which the substituent A has the lowest Δα and the substituent B has the highest Δα: Δ ⁢ ⁢ α = α ⁢ ⁢ x - α ⁢ ⁢ y + α ⁢ ⁢ z 2 Mathematical ⁢ ⁢ formula ⁢ ⁢ ( 1 ) wherein, in characteristic values obtained after diagonalization of polarizability tensor, αx is the largest component, αy is the second largest component, and αz is the smallest component; DS B 2+ DS B 3− DS B 6≧−0.1   Mathematical formula (A1) wherein DS B 2, DS B 3, and DS B 6 represent a substitution degree of the substituent B at the 2-, 3-, or 6-position of a β-glucose ring constituting unit of cellulose, respectively; and an optical compensation film, a polarizing plate, and a liquid crystal display device, using the cellulose compound film.

  一种纤维素化合物薄膜，其含有具有两个或更多取代基的纤维素化合物，其极化率各向异性Δα通过数学公式（1）计算得出，其中以下取代基A和B的取代度满足数学公式（A1）所定义的关系，其中取代基A具有最低的Δα，而取代基B具有最高的Δα：Δα = αx-αy + αz2数学公式（1）其中，在极化率张量对角化后获得的特征值中，αx是最大分量，αy是第二大分量，αz是最小分量;DSB2 + DSB3-DSB6≥-0.1数学公式（A1）其中DSB2、DSB3和DSB6分别表示取代基B在纤维素构成单位β-葡萄糖环的2-、3-或6-位置的取代度;以及使用该纤维素化合物薄膜的光学补偿膜、偏光板和液晶显示装置。
• Cellulose Acylate Film, Method of Producing the Same, Cellulose Derivative Film, Optically Compensatory Film Using the Same, Optically-Compensatory Film Incorporating Polarizing Plate, Polarizing Plate and Liquid Crystal Display Device
  申请人：Haruta Hiromoto

  公开号：US20090290100A1

  公开（公告）日：2009-11-26

  A method of producing a cellulose derivative film, the method comprising: forming a film with a solvent cast method from a dope including a cellulose derivative satisfying following conditions (a) and (b): (a) at least one among three hydroxyl groups included in a glucose unit of cellulose is substituted by a substituent of which a polarizability anisotropy Δα represented as following Expression (1) is 2.5×10 −24 cm 3 or higher: Expression (1): Δα=αx−(αy+αz)/2, wherein αx, αy and αz is as defined in the specification; and (b) when a substitution degree by a substituent of which Δα is 2.5×10 −24 cm 3 or higher is P A , and a substitution degree by a substituent of which Δα is lower than 2.5×10 −24 cm 3 is P B , the P A and P B satisfy following Expressions (3) and (4): Expression (3): 2P A +P B >3.0; and Expression (4): P A >0.2.

  一种生产纤维素衍生物薄膜的方法，该方法包括：使用包括满足以下条件（a）和（b）的纤维素衍生物的溶胶，通过溶剂浇铸法形成薄膜：（a）纤维素的葡萄糖单元中的三个羟基中的至少一个被取代为极化率各向异性Δα（以下表达式（1）表示）为2.5×10-24cm3或更高的取代基：表达式（1）：Δα=αx-（αy+αz）/ 2，其中αx，αy和αz如规范中定义的；并且（b）当Δα为2.5×10-24cm3或更高的取代基的取代度为PA时，Δα低于2.5×10-24cm3的取代基的取代度为PB，PA和PB满足以下表达式（3）和（4）：表达式（3）：2PA + PB> 3.0；表达式（4）：PA> 0.2。
• Horner,L.; Weissbach,R., Justus Liebigs Annalen der Chemie, 1972, vol. 757, p. 69 - 74
  作者：Horner,L.、Weissbach,R.

  DOI：——

  日期：——
• Bogert; Nisson, Proceedings of the National Academy of Sciences of the United States of America, vol. 10, p. 423,424
  作者：Bogert、Nisson

  DOI：——

  日期：——