Room-temperature stable, one-component, thermally-conductive, flexible epoxy adhesives
申请人:HE HOLDINGS, INC. dba HUGHES ELECTRONICS
公开号:EP0754741A2
公开(公告)日:1997-01-22
A flexible thermally-conductive epoxy-based adhesive composition and method for making the same are provided. The present adhesive composition comprises (a) a polymer mixture comprising at least one polyepoxide resin having a hardness not exceeding a durometer Shore D reading of about 45, when cured with a stoichiometric amount of diethylene triamine ("DETA"), and a substantially stoichiometric amount of at least one latent epoxy resin curing agent; and (b) a thermally-conductive filler. Optional components include secondary epoxy resins, non-reactive flexibilizers, diluents, and processing aids. The present adhesive composition is rheologically stable for weeks or even months at room temperature and is curable in less than one hour at a temperature ranging from about 100°C to 140°C, whereupon the cured adhesive composition exhibits a durometer Shore A of less than about 90 and a thermal conductivity exceeding 0.4 BTU/hr-ft-°F (0.7 W/m-K).
提供了一种柔性导热环氧基粘合剂组合物及其制造方法。本粘合剂组合物包括:(a) 聚合物混合物,该混合物包含至少一种聚环氧树脂,该树脂在用一定量的二乙三胺("DETA")和一定量的至少一种潜伏环氧树脂固化剂固化时,硬度不超过硬度计 Shore D 读数约 45;(b) 热导性填料。可选成分包括辅助环氧树脂、非反应性柔顺剂、稀释剂和加工助剂。本粘合剂组合物在室温下具有数周甚至数月的流变稳定性,并可在约 100°C 至 140°C 的温度下在一小时内固化,固化后的粘合剂组合物的硬度计邵氏 A 值小于约 90,导热系数超过 0.4 BTU/hr-ft-°F (0.7 W/m-K)。