[N-butyl-3-(hydroxy-κO)-3-(3-tetrahydrofuran-3-yl)-acrylamidato-κO'](difluoro)boron | 1144554-10-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四氢呋喃
• 英文名称: [N-butyl-3-(hydroxy-κO)-3-(3-tetrahydrofuran-3-yl)-acrylamidato-κO'](difluoro)boron
• CAS: 1144554-10-8
• 化学式: C₁₁H₁₈BF₂NO₃
• 分子量: 261.077
• InChiKey: NDXPQWMNRZFMQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [N-butyl-3-(3-furyl)-3-(hydroxy-κO)acrylamidato-κO'](difluoro)boron 在 palladium 10% on activated carbon 、 氢气 作用下， 以 四氢呋喃 为溶剂， 25.0 ℃ 、100.0 kPa 条件下， 反应 24.0h， 以66%的产率得到[N-butyl-3-(hydroxy-κO)-3-(3-tetrahydrofuran-3-yl)-acrylamidato-κO'](difluoro)boron
  参考文献：
  名称：

  Hydrogenation of BF2 complexes with 1,3-dicarbonyl ligands

  摘要：

  The catalytic hydrogenation (H-2, Pd/C) of a set of BF2 complexes with a 1,3-dicarbonyl Structural unit leading to monocarbonyl compounds has been studied. The transformation presented is general for the aryl-substituted derivatives and occurs under mild conditions (H-2, 1 bar, 25 degrees C) in methanol or THF. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.01.017

文献信息

• Hydrogenation of BF2 complexes with 1,3-dicarbonyl ligands
  作者：Bogdan Štefane、Slovenko Polanc

  DOI：10.1016/j.tet.2009.01.017

  日期：2009.3

  The catalytic hydrogenation (H-2, Pd/C) of a set of BF2 complexes with a 1,3-dicarbonyl Structural unit leading to monocarbonyl compounds has been studied. The transformation presented is general for the aryl-substituted derivatives and occurs under mild conditions (H-2, 1 bar, 25 degrees C) in methanol or THF. (C) 2009 Elsevier Ltd. All rights reserved.