(2,4,6-triisopropylphenyl)2SnBr2 | 211488-37-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,4,6-triisopropylphenyl)2SnBr2
• CAS: 211488-37-8
• 化学式: C₃₀H₄₆Br₂Sn
• 分子量: 685.213
• InChiKey: ZIDKQIIMOUZIMQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.34
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2,4,6-triisopropylphenyl)2SnBr2 、 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 、 正戊烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  ATTEMPTED SYNTHESIS OF A TRANSITION-METAL STANNAPHOSPHENE COMPLEX

  摘要：

  Fluoro-, chloro- and bromostannylphosphines (8-10) complexed on phosphorus by tungsten pentacarbonyl have been synthesized by reaction between lithium mesityl(tungsten pentacarbonyl)phosphide 4 and the corresponding dihalo(diisityl)tin (isityl: 2,4,6-triisopropylphenyl). Reaction of 8 with tert-butyllithium afforded the stable lithium fluorostannylphosphide 11. Addition of Me3SiCl or MgBr2 to 11 gave the corresponding chloro- and bromoderivatives 14 and 15. Similar compounds 16 and 17 were obtained from 9 and 10 and DBU. 11, 14, 15, 16 and 17 present a large (1)J(SnP) coupling constant (2099.0 to 2151.4 Hz) indicating a partial Sn-P double bond.

  DOI：

  10.1080/10426509708043555
• 作为产物：
  描述：

  2-溴-1,3,5-三异丙苯 在 magnesium 作用下， 以 四氢呋喃 、 正庚烷 、 二氯甲烷 、 水 为溶剂， 反应 2.0h， 生成 (2,4,6-triisopropylphenyl)2SnBr2
  参考文献：
  名称：

  通过盐复分解和卤化物交换从格氏试剂选择性制备位阻二芳基二卤化锡

  摘要：

  开发了从容易获得但空间要求高的2,6-二取代或2,4,6-三取代芳基格氏试剂ArylMgBr和四氯化锡选择性制备二氯化二芳基锡，二溴化物和二碘化物的一般方法。在后处理过程中，最初获得的卤化物混合物被转化为单一物质。使如此获得的二芳基二氯化锡反应以生成二氢化物芳基2 SnH 2。这些具有高的热稳定性和中等的耐氧性。

  DOI：

  10.1002/ejic.201900180

文献信息

• Nickel-Triad Complexes of a Side-on Coordinating Distannene
  作者：Christian P. Sindlinger、Sebastian Weiß、Hartmut Schubert、Lars Wesemann

  DOI：10.1002/anie.201411025

  日期：2015.3.23

  and Pt precursor complexes to cleanly yield the respective metal complexes featuring a three‐membered ring moiety Sn‐Sn‐M along with carbene transfer onto the metal and complete substitution of the starting ligands. Thus the easily accessible NHC adducts to stannylenes are shown to be valuable precursors for transition‐metal complexes with an unexpected SnSn bond. The complexes have been studied

  使亚锡Trip 2 Sn（Trip = 2,4,6-三异丙基苯基）的NHC加合物与零价Ni，Pd和Pt前体络合物反应，以纯净地产生各自具有三元环部分Sn-Sn的金属络合物‐M以及卡宾转移到金属上，并完全取代了起始配体。因此，易于获得的NHC与亚锡基的加合物被证明是具有意外的Sn valuable Sn键的过渡金属配合物的有价值的前体。配合物已通过X射线衍射和NMR光谱以及DFT计算进行了研究。具有distannametallacycle的结构基序的化合物，该化合物由[（NHC）2 M 0 ]片段和Sn 2 Trip 4组成代表了众所周知的烯烃配合物的稀有高级同源物。DFT计算表明，在第一个示例中，对于与零价过渡金属对称配位的非环状二烯，存在π型Sn-Sn相互作用。
• Hexakis(2,4,6-triisopropylphenyl)cyclotristannoxane - a Molecular Diorganotin Oxide with Kinetically Inert Sn-O Bonds
  作者：Jens Beckmann、Klaus Jurkschat、Stephanie Rabe、Markus Schürmann

  DOI：10.1002/1521-3749(200110)627:10<2413::aid-zaac2413>3.0.co;2-h

  日期：2001.10

  The single-crystal X-ray structure analysis of hexakis(2,4,6-triisopropylphenyl)cyclotristannoxane, cyclo-[(2,4,6-i-Pr-3-C6H2)(2)SnO](3) (1), is reported and reveals this compound to contain an almost planar six-membered ling. Redistribution reactions of 1 with cyclo-(t-Bu2SnO)(3) and t-Bu2SiCl2, respectively, failed and indicate an unusual kinetic inertness of the Sn-O bonds in 1 as compared to related molecular diorganotin oxides containing less bulkier substituents. The redistribution reaction of cyclo-(t-Bu2SnO)(3) with cyclo-(t-Bu2SnS)(2) leads to an equilibrium involving the trimeric diorganotin oxysulphides cyclo-t-Bu2Sn(OSnt-Bu-2)(2)S (2a) and cyclo-t-Bu2Sn(SSnt-Bu-2)(2)O (2b).
• Selective Preparation of Sterically Encumbered Diaryltin Dihalides from Grignard Reagents via Salt Metathesis and Halide Exchange
  作者：Beate G. Steller、Roland C. Fischer

  DOI：10.1002/ejic.201900180

  日期：2019.6.10

  A general route for the selective preparation of diaryltin dichlorides, dibromides, and diiodides from readily accessible but sterically demanding, 2,6‐disubstituted or 2,4,6‐trisubstituted aryl Grignard reagents ArylMgBr and tin tetrachloride was developed. During work‐up, the initially obtained mixture of halides is converted into a single species. The thus obtained diaryltin dichlorides were reacted

  开发了从容易获得但空间要求高的2,6-二取代或2,4,6-三取代芳基格氏试剂ArylMgBr和四氯化锡选择性制备二氯化二芳基锡，二溴化物和二碘化物的一般方法。在后处理过程中，最初获得的卤化物混合物被转化为单一物质。使如此获得的二芳基二氯化锡反应以生成二氢化物芳基2 SnH 2。这些具有高的热稳定性和中等的耐氧性。
• ATTEMPTED SYNTHESIS OF A TRANSITION-METAL STANNAPHOSPHENE COMPLEX
  作者：A. Kandri Rodi、H. Ranaivonjatovo、J. Escudié、A. Kerbal

  DOI：10.1080/10426509708043555

  日期：1997.7.1

  Fluoro-, chloro- and bromostannylphosphines (8-10) complexed on phosphorus by tungsten pentacarbonyl have been synthesized by reaction between lithium mesityl(tungsten pentacarbonyl)phosphide 4 and the corresponding dihalo(diisityl)tin (isityl: 2,4,6-triisopropylphenyl). Reaction of 8 with tert-butyllithium afforded the stable lithium fluorostannylphosphide 11. Addition of Me3SiCl or MgBr2 to 11 gave the corresponding chloro- and bromoderivatives 14 and 15. Similar compounds 16 and 17 were obtained from 9 and 10 and DBU. 11, 14, 15, 16 and 17 present a large (1)J(SnP) coupling constant (2099.0 to 2151.4 Hz) indicating a partial Sn-P double bond.