1,1,2-trichloro-3-methyl-but-1-ene | 49580-74-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,1,2-trichloro-3-methyl-but-1-ene
• 英文别名: 1,1,2-Trichlor-3-methyl-but-1-en；1,1,2-Trichloro-3-methylbut-1-ene
• CAS: 49580-74-7
• 化学式: C₅H₇Cl₃
• 分子量: 173.47
• InChiKey: MDPZHUJBBDGFFR-UHFFFAOYSA-N

物化性质

• 沸点：
  149-151 °C(Press: 756 Torr)
• 密度：
  1.249±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  四氯乙烯 、 triisopropyl indium 反应 12.0h， 生成 1,1,2-trichloro-3-methyl-but-1-ene
  参考文献：
  名称：

  New triad alkylation reagent. Cross coupling of indium trialkyls with alkenyl halides

  摘要：

  DOI：

  10.1021/ja00033a070

文献信息

• Method for producing fluorine-containing olefin
  申请人：ASAHI GLASS COMPANY, LIMITED

  公开号：US10421702B2

  公开（公告）日：2019-09-24

  A method for producing at least one compound selected from the group consisting of a compound represented by the following formula (10), a compound represented by the following formula (11), a compound represented by the following formula (12), and a compound represented by the following formula (13), which the method containing reacting a compound represented by the following formula (2) with a compound represented by the following formula (7), in the presence of at least one compound selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (3), a compound represented by the following formula (4), a compound represented by the following formula (8), and a compound represented by the following formula (9).

  一种生产至少一种选自由下式(10)代表的化合物、下式(11)代表的化合物、下式(12)代表的化合物和下式(13)代表的化合物组成的组的化合物的方法，该方法包括使下式(2)代表的化合物与下式(7)代表的化合物反应、在至少一种选自由下式 (1) 所代表的化合物、下式 (3) 所代表的化合物、下式 (4) 所代表的化合物、下式 (8) 所代表的化合物和下式 (9) 所代表的化合物组成的组中的化合物存在的情况下。
• Schmerling; West, Journal of the American Chemical Society, 1949, vol. 71, p. 2016
  作者：Schmerling、West

  DOI：——

  日期：——
• Schmerling, Journal of the American Chemical Society, 1946, vol. 68, p. 1653
  作者：Schmerling

  DOI：——

  日期：——
• Schmerling; West, Journal of the American Chemical Society, 1949, vol. 71, p. 2018
  作者：Schmerling、West

  DOI：——

  日期：——
• METHOD FOR PRODUCING FLUORINE-CONTAINING OLEFIN
  申请人：Asahi Glass Company, Limited

  公开号：US20180086684A1

  公开（公告）日：2018-03-29

  A method for producing at least one compound selected from the group consisting of a compound represented by the following formula (10), a compound represented by the following formula (11), a compound represented by the following formula (12), and a compound represented by the following formula (13), which the method containing reacting a compound represented by the following formula (2) with a compound represented by the following formula (7), in the presence of at least one compound selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (3), a compound represented by the following formula (4), a compound represented by the following formula (8), and a compound represented by the following formula (9).