[5-(2-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-acetic acid 2-(5-methoxycarbonylmethyl-tetrahydro-furan-2-yl)-1-methyl-ethyl ester | 211036-93-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [5-(2-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-acetic acid 2-(5-methoxycarbonylmethyl-tetrahydro-furan-2-yl)-1-methyl-ethyl ester
• CAS: 211036-93-0
• 化学式: C₂₆H₃₈O₇
• 分子量: 462.584
• InChiKey: SJNMXAZMRJRNNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.35
• 重原子数：
  33.0
• 可旋转键数：
  12.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  80.29
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  [5-(2-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-acetic acid 2-(5-methoxycarbonylmethyl-tetrahydro-furan-2-yl)-1-methyl-ethyl ester 在 三甲基氯硅烷 、 sodium iodide 作用下， 以 乙腈 为溶剂， 反应 6.0h， 生成 [5-(2-{2-[5-(2-Hydroxy-propyl)-tetrahydro-furan-2-yl]-acetoxy}-propyl)-tetrahydro-furan-2-yl]-acetic acid methyl ester
  参考文献：
  名称：

  Structural features for the promotion of optimal stacking in the solid state

  摘要：

  Nano-tubes are generated by taking advantage of the geometry of cyclic substructures that can be stacked on top of each other analogous the way garden chairs can be stacked. This concept of generating stacks depends solely on the geometry of the building blocks. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)00427-x
• 作为产物：
  描述：

  chloro acetic acid 1-(2-benzyloxypropyl)-4-hydroxyl-butyl ester 在 4-二甲氨基吡啶 、 lithium hydroxide 、 sodium methylate 、 戴斯-马丁氧化剂 、 2,3-二脱氧胞啶 作用下， 以 甲醇 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 18.75h， 生成 [5-(2-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-acetic acid 2-(5-methoxycarbonylmethyl-tetrahydro-furan-2-yl)-1-methyl-ethyl ester
  参考文献：
  名称：

  Structural features for the promotion of optimal stacking in the solid state

  摘要：

  Nano-tubes are generated by taking advantage of the geometry of cyclic substructures that can be stacked on top of each other analogous the way garden chairs can be stacked. This concept of generating stacks depends solely on the geometry of the building blocks. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(98)00427-x

文献信息

• Structural features for the promotion of optimal stacking in the solid state
  作者：Markus Kalesse、Rudolf Wartchow

  DOI：10.1016/s0040-4020(98)00427-x

  日期：1998.7

  Nano-tubes are generated by taking advantage of the geometry of cyclic substructures that can be stacked on top of each other analogous the way garden chairs can be stacked. This concept of generating stacks depends solely on the geometry of the building blocks. (C) 1998 Elsevier Science Ltd. All rights reserved.