N-(1,1,3,3-tetramethyl-butyl)-methacrylamide | 58778-83-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(1,1,3,3-tetramethyl-butyl)-methacrylamide
• 英文别名: N-(1,1,3,3-Tetramethyl-butyl)-methacrylamid；Methacrylsaeure-(1,1,3,3-tetramethyl-butylamid)；2-Methacryloylamino-2,4,4-trimethyl-pentan；2-methyl-N-(2,4,4-trimethylpentan-2-yl)prop-2-enamide
• CAS: 58778-83-9
• 化学式: C₁₂H₂₃NO
• 分子量: 197.321
• InChiKey: WPFTVIVHDBZTSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  异辛烯 、 甲基丙烯腈 在 硫酸 、 溶剂黄146 作用下， 生成 N-(1,1,3,3-tetramethyl-butyl)-methacrylamide
  参考文献：
  名称：

  A New Reaction of Nitriles. VI. Unsaturated Amides¹

  摘要：

  DOI：

  10.1021/ja01153a005

文献信息

• [EN] POLYMERIZABLE COMPOSITION COMPRISING AN OXIME SULFONATE AS THERMAL CURING AGENT<br/>[FR] COMPOSITION POLYMÉRISABLE COMPRENANT UN SULFONATE D'OXIME EN TANT QU'AGENT DE DURCISSEMENT THERMIQUE
  申请人：BASF SE

  公开号：WO2012101245A1

  公开（公告）日：2012-08-02

  The present invention relates to a polymerizable composition comprising at least one ethylenically unsaturated, polymerizable compound and at least one oxime sulfonate compound of the formula (I) QAaBbCc where a is 0, 1, 2, 3, 4 or 6, b is 0, 1, 2, 3, 4 or 6, and c is 0, 1, 2, 3, 4 or 6, where the sum of a + b + c is 1, 2, 3, 4 or 6 where (A) is a group (B) is a group (C) is a group where # denotes the point of attachment to Q; X is S or NR14 and Q, R1, R2, R3 and R14 are as defined in claim 1 and in the description. The present invention also relates to the use of the this composition, to novel oxime sulfonates and the use of the oxime sulfonates as thermal curing promoter.

  本发明涉及一种可聚合的组成，包括至少一种乙炔基不饱和的可聚合化合物和至少一种具有公式（I）QAaBbCc的亚硝基亚磺酸酯化合物，其中a为0、1、2、3、4或6，b为0、1、2、3、4或6，c为0、1、2、3、4或6，其中a+b+c的总和为1、2、3、4或6，其中（A）是一个基团，（B）是一个基团，（C）是一个基团，其中#表示与Q连接的点；X是S或NR14，Q、R1、R2、R3和R14如权利要求1和说明书中所定义。本发明还涉及使用这种组成物，新型亚硝基亚磺酸酯及其作为热固化促进剂的应用。
• Use Of Polyisobutenyl Succinic Anhydride-Based Block Copolymers In Cosmetic Preparations
  申请人：Wendel Volker

  公开号：US20080199420A1

  公开（公告）日：2008-08-21

  The invention relates to novel cosmetic preparations comprising an O/W emulsion, where the O/W emulsion comprises at least one amphiphilic polymer comprising one or more hydrophobic units A and one or more hydrophilic units B, where the hydrophobic units A are formed from polyisobutenes modified with terminal, polar groups, at least one component with an HLB value in the range from 8 to 20, and at least one oil and/or fat phase and water.

  这项发明涉及一种新型化妆品制剂，包括一种O/W乳液，其中该O/W乳液包括至少一种含有一个或多个疏水单元A和一个或多个亲水单元B的两性聚合物，其中疏水单元A由末端极性基团改性的聚异丁烯形成，至少包括一个HLB值在8到20范围内的成分，以及至少一个油脂相和水。
• Ampholytic anionic copolymers
  申请人：Nguyen-Kim Son

  公开号：US20070141013A1

  公开（公告）日：2007-06-21

  Ampholytic copolymers which contain a molar excess of anionogenic and/or anionic groups, polyelectrolyte complexes which contain such an ampholytic copolymer, cosmetic and pharmaceutical compositions which contain at least one such copolymer or polyelectrolyte complex and the use of these copolymers and polyelectrolyte complexes are described.

  本文描述了含有阴离子和/或负离子基团的摇摆共聚物，含有这种摇摆共聚物的聚电解质复合物，含有至少一种这样的共聚物或聚电解质复合物的化妆品和药物组合物，以及这些共聚物和聚电解质复合物的用途。
• Anionic, Ampholytic Copolymers for Low-Voc-Compositions
  申请人：Kim Son Nguyen

  公开号：US20080219934A1

  公开（公告）日：2008-09-11

  The present invention provides cosmetic compositions containing a copolymer obtainable by the copolymerization of at least one methacrylic acid ester, methacrylic acid, acrylic acid, optionally at least one compound containing amino groups and polymerizable by free radical polymerization, and optionally other olefinically unsaturated compounds polymerizable by free radical polymerization. The copolymerization can be carried out in the presence of silicones f) containing polyalkylene oxide.

  本发明提供了一种化妆品组合物，其中包含由至少一种甲基丙烯酸酯，甲基丙烯酸，丙烯酸，可选地至少一种含有氨基团的自由基聚合可聚合化合物以及可选地由自由基聚合可聚合的其他烯烃类不饱和化合物共聚而成的共聚物。共聚反应可以在含有聚烷基氧化物的硅烷f）的存在下进行。
• [EN] OXIME SULFONATE DERIVATIVES<br/>[FR] DÉRIVÉS DE SULFONATE D'OXIME
  申请人：BASF SE

  公开号：WO2016030790A1

  公开（公告）日：2016-03-03

  Oxime sulfonate compounds of the formula (I), wherein R 1 is O(CO)R 4, COOR 5 or CONR 6R 7; n is 1 or 2; R 2 for example is C 1-C 8alkyl, C 3-C 6cycloalkyl or benzyl; R 3 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 4 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 5 is for example C 3-C 20alkyl, C 3-C 14cycloalkyl, C 2-C 8alkenyl, C 1-C 12alkyl which is substituted for example by one or more halogen; or R 5 is phenyl or naphthyl, which are unsubstituted; R 6 and R 7 each independently of one another for example are hydrogen, C 1-C 12alkyl, C 1-C 4haloalkyl, phenyl-C 1-C 4alkyl, C 2-C 8alkenyl or C 3-C 6cycloalkyl, phenyl or naphthyl; or R 6 and R 7, together with the N-atom to which they are attached, form a 5- or 6-membered ring; are suitable as thermal radical initiators.

  化合物的氧肟磺酸盐，其化学式为（I），其中R1为O（CO）R4，COOR5或CONR6R7; n为1或2; R2例如为C1-C8烷基，C3-C6环烷基或苄基; R3例如为C1-C8烷基，C3-C6环烷基，C1-C8卤代烷基，C2-C8烯基，苄基，苯基或萘基，可以选择性地被取代; R4例如为C1-C8烷基，C3-C6环烷基，C1-C8卤代烷基，C2-C8烯基，苄基，苯基或萘基，可以选择性地被取代; R5例如为C3-C20烷基，C3-C14环烷基，C2-C8烯基，C1-C12烷基，例如被一个或多个卤素取代; 或者R5是未被取代的苯基或萘基; R6和R7各自独立地例如为氢，C1-C12烷基，C1-C4卤代烷基，苯基-C1-C4烷基，C2-C8烯基或C3-C6环烷基，苯基或萘基; 或者R6和R7与它们所连接的N原子一起形成一个5-或6-成员环; 适用于热引发自由基反应剂。