1-Hydroximino-4-phenyl-3-buten-2-on | 41113-26-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Hydroximino-4-phenyl-3-buten-2-on
• 英文别名: 2-oxo-4-phenyl-but-3-enal oxime；2-Oxo-4-phenyl-but-3-enal-oxim；α'-Isonitroso-α-benzyliden-aceton；α'-Isonitroso-α-benzal-aceton；Oximinomethyl-styryl-keton；Styrylglyoxal-aldoxim；1-Hydroxyimino-4-phenylbut-3-en-2-one；1-hydroxyimino-4-phenylbut-3-en-2-one
• CAS: 41113-26-2
• 化学式: C₁₀H₉NO₂
• 分子量: 175.187
• InChiKey: JERZJIWWECMCAI-UHFFFAOYSA-N

物化性质

• 熔点：
  137-139 °C
• 沸点：
  352.4±35.0 °C(Predicted)
• 密度：
  1.06±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-Hydroximino-4-phenyl-3-buten-2-on 在 乙酸酐 作用下， 生成 cinnamoyl cyanide
  参考文献：
  名称：

  Borsche; Walter, Chemische Berichte, 1926, vol. 59, p. 463

  摘要：

  DOI：
• 作为产物：
  描述：

  苄叉丙酮 、 亚硝酸异戊酯 在 盐酸 作用下， 生成 1-Hydroximino-4-phenyl-3-buten-2-on
  参考文献：
  名称：

  CXCI.—2-苯基-5-苯乙烯基恶唑

  摘要：

  DOI：

  10.1039/ct9130301768

文献信息

• Dornow; Gellrich, Justus Liebigs Annalen der Chemie, 1955, vol. 594, p. 177,181
  作者：Dornow、Gellrich

  DOI：——

  日期：——
• Rupe; Kessler, Chemische Berichte, 1909, vol. 42, p. 4718
  作者：Rupe、Kessler

  DOI：——

  日期：——
• Carbon and nitrogen partitioning in either fruiting or non-fruiting grapevines: effects of nitrogen limitation before and after veraison
  作者：BEGOÑA RODRIGUEZ-LOVELLE、JEAN-PIERRE GAUDILLÈRE

  DOI：10.1111/j.1755-0238.2002.tb00216.x

  日期：2002.7

  Fruit effects on carbon (C) balance between reproductive and vegetative growth, and between shoots and roots, were studied under low versus high nitrogen (N) availability before and after veraison. Fruiting vines were compared with non-fruiting vines, and N was supplied at either a low or high rate, and either continuously or as a split application before and after veraison. In non-fruiting grapevines, leaf growth was greatly affected by N supply, but root growth was little affected. Low N supply before veraison favoured berry development, whereas after veraison enlarging fruits. were disadvantaged by low N supply. Fruit growth was highly competitive with root growth, particularly before veraison, when N supply was low. Whole plant C and N accumulation rates were lower in fruiting plants. Berry amino acid content was influenced by all combinations of N treatments. Overall, fruit development was favoured by ensuring a low N supply rate before veraison, but this occurred at the expense of root growth as well as C and N uptake by the grapevines. After veraison, fruit can express a high sink strength if N is made available, probably because photosynthetic activity increases. These results provide new insights into how N may be managed in order to control grapevine C partitioning, to encourage berry development, and to sustain overall C and N uptake by grapevines.
• Mills, Chemical news and journal of industrial science, 1903, vol. 88, p. 228
  作者：Mills

  DOI：——

  日期：——
• Harries; Mills, Justus Liebigs Annalen der Chemie, 1904, vol. 330, p. 248
  作者：Harries、Mills

  DOI：——

  日期：——