dibenzo[a:c](dipyrido[2,3-h:2',3'-j])phenazine | 132467-99-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: dibenzo[a:c](dipyrido[2,3-h:2',3'-j])phenazine
• 英文别名: 2,5,14,17-Tetrazaheptacyclo[16.12.0.03,16.04,9.010,15.019,24.025,30]triaconta-1,3,5,7,9,11,13,15,17,19,21,23,25,27,29-pentadecaene
• CAS: 132467-99-3
• 化学式: C₂₆H₁₄N₄
• 分子量: 382.424
• InChiKey: WQBIVOJVSIQTQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 Ru(tpy)(Cl)₃ 、 水 、 dibenzo[a:c](dipyrido[2,3-h:2',3'-j])phenazine 在 silver tetrafluoroborate 作用下， 以 N,N-二甲基甲酰胺 、 丙酮 、 正丁醇 为溶剂， 以52%的产率得到[(2,2':6',6''-terpyridine)Ru(N(C14H7)N(C12H6N2))]PF6*2H2O
  参考文献：
  名称：

  Dibenzo[a:c](dipyrido[2,3-h:2′,3′-j])phenazine (dbdpzH2) mono and dinuclear cyclometallated ruthenium complexes

  摘要：

  The mono and dimetallic cyclometallated ruthenium complexes of dibenzo[a:c](dipyrido[2,3-h:2',3'-j])phenazine (dbdpzH(2)) have been prepared. The monocyclometallation of this potentially dicyclometallating bridging ligand in the dimetallic complex: [(tpy)Ru(dbdpzH)Ru(H2O)(tpy)](3+) has been attributed to the distortion of the ligand upon binding to the first metal ion, which increases the size of the second binding site, inhibiting the second cyclometallation. The mono and dimetallic cyclometallated ruthenium complexes of dibenzo[a:c](dipyrido[2,3-h:2',3'-j]) phenazine (dbdpzH(2)) have been prepared. The monocyclometallation of this potentially dicyclometallating bridging ligand in the dimetallic complex has been attributed to distortion of the second chelating site by the first complexation which inhibits the second cyclometallation. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01242-2
• 作为产物：
  描述：

  泛喹酮 、 9,10-二氨基菲 以 二甲基亚砜 为溶剂， 反应 2.0h， 以75%的产率得到dibenzo[a:c](dipyrido[2,3-h:2',3'-j])phenazine
  参考文献：
  名称：

  One-Step Syntheses of Tetrapyrido[2,3-a:3',2'-c:2'',3''-h:3'', 2'' '-j] Phenazine and Dibenzo[a:c](Dipyrido[2,3-h:2',3'-j]) Phenazine

  摘要：

  The one-step syntheses of two fully aromatic planar bis-terdentate bridging ligands are described.

  DOI：

  10.1080/00397919708004166