2-[(E)-2-[2,5-dibutoxy-4-[(E)-2-(1-methylpyrrol-2-yl)ethenyl]phenyl]ethenyl]-1-methylpyrrole | 399521-60-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-[(E)-2-[2,5-dibutoxy-4-[(E)-2-(1-methylpyrrol-2-yl)ethenyl]phenyl]ethenyl]-1-methylpyrrole
• CAS: 399521-60-9
• 化学式: C₂₈H₃₆N₂O₂
• 分子量: 432.606
• InChiKey: WKKVLGMJJXSANV-WXUKJITCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  32
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  28.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  方酸 、 2-[(E)-2-[2,5-dibutoxy-4-[(E)-2-(1-methylpyrrol-2-yl)ethenyl]phenyl]ethenyl]-1-methylpyrrole 以 正丁醇 、 苯 为溶剂， 以38%的产率得到
  参考文献：
  名称：

  A Novel Approach Toward Low Optical Band Gap Polysquaraines

  摘要：

  [GRAPHICS]Polycondensation of 2,5-dialkoxydivinylbenzene-bridged bispyrroles and squaric acid resulted in extensively conjugated polymers with strong near-infrared (NIR) absorption around 800-1000 nm, which is a signature of their low band gap (E-g). Conjugated polymers with such a strong NIR absorption are rare. One of the synthesized polysquaraines showed a significantly low E-g of 0.79 eV with an intrinsic conductivity of 5.3 X 10(-4) S/cm.

  DOI：

  10.1021/ol016284p
• 作为产物：
  描述：

  (2,5-Dibutoxy-4-phosphonomethyl-benzyl)-phosphonic acid 、 N-甲基-2-吡咯甲醛 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 以63%的产率得到2-[(E)-2-[2,5-dibutoxy-4-[(E)-2-(1-methylpyrrol-2-yl)ethenyl]phenyl]ethenyl]-1-methylpyrrole
  参考文献：
  名称：

  A Novel Approach Toward Low Optical Band Gap Polysquaraines

  摘要：

  [GRAPHICS]Polycondensation of 2,5-dialkoxydivinylbenzene-bridged bispyrroles and squaric acid resulted in extensively conjugated polymers with strong near-infrared (NIR) absorption around 800-1000 nm, which is a signature of their low band gap (E-g). Conjugated polymers with such a strong NIR absorption are rare. One of the synthesized polysquaraines showed a significantly low E-g of 0.79 eV with an intrinsic conductivity of 5.3 X 10(-4) S/cm.

  DOI：

  10.1021/ol016284p

文献信息

• Chemically sensitive sensor comprising arylene alkenylene oligomers
  申请人：INTERUNIVERSITAIR MICRO-ELEKTRONICA CENTRUM VZW

  公开号：EP0878711A1

  公开（公告）日：1998-11-18

  Chemically sensitive sensors, suitable for detecting analytes in fluids (in gaseous or liquid phase), characterised in that the chemically sensitive sensors comprise a chemically sensitive probe, which comprises one or a blend of several arylene alkenylene oligomers.

  化学敏感传感器，适用于检测流体（气相或液相）中的分析物，其特征在于化学敏感传感器包括一个化学敏感探针，该探针由一种或多种芳基烯烃低聚物混合而成。
• US6042788A
  申请人：——

  公开号：US6042788A

  公开（公告）日：2000-03-28
• US6572826B1
  申请人：——

  公开号：US6572826B1

  公开（公告）日：2003-06-03
• A Novel Approach Toward Low Optical Band Gap Polysquaraines
  作者：A. Ajayaghosh、J. Eldo

  DOI：10.1021/ol016284p

  日期：2001.8.9

  [GRAPHICS]Polycondensation of 2,5-dialkoxydivinylbenzene-bridged bispyrroles and squaric acid resulted in extensively conjugated polymers with strong near-infrared (NIR) absorption around 800-1000 nm, which is a signature of their low band gap (E-g). Conjugated polymers with such a strong NIR absorption are rare. One of the synthesized polysquaraines showed a significantly low E-g of 0.79 eV with an intrinsic conductivity of 5.3 X 10(-4) S/cm.