2-hydroxy-2-phenylethyl acrylate | 5309-66-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-hydroxy-2-phenylethyl acrylate
• 英文别名: (2-Hydroxy-2-phenylethyl) prop-2-enoate
• CAS: 5309-66-0
• 化学式: C₁₁H₁₂O₃
• 分子量: 192.214
• InChiKey: NSIHCJDYMGWYKW-UHFFFAOYSA-N

物化性质

• 沸点：
  323.7±35.0 °C(Predicted)
• 密度：
  1.140±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-hydroxy-2-phenylethyl acrylate 、 氯化锆(IV) 在 对甲酚 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  CN115677502

  摘要：

  公开号：
• 作为产物：
  描述：

  氧化苯乙烯 、 丙烯酸 在 2,6-di-tert-butyl-4-hydroxytoluene 、 四正丁基溴化膦 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以94%的产率得到2-hydroxy-2-phenylethyl acrylate
  参考文献：
  名称：

  季鎓盐催化环氧化物与氧亲核试剂的高效开环反应

  摘要：

  探索了由多种季鎓盐（例如铵盐或鏻盐）催化的环氧化物与氧亲核试剂的开环反应。结果表明，盐中的四丁基溴化鏻 (TBPB) 是该过程最有效的催化剂，并且使用该盐促进了与包括羧酸和苯酚在内的各种含氧亲核试剂的环氧化物开环反应，导致在优良的产量。

  DOI：

  10.5012/bkcs.2013.34.8.2286

文献信息

• RADICAL POLYMERIZABLE COMPOSITION, CURED PRODUCT, AND PLASTIC LENS
  申请人：DIC Corporation

  公开号：US20140148525A1

  公开（公告）日：2014-05-29

  There are provided a radical polymerizable composition having a low viscosity suitable for coating, a cured product obtained by curing the composition, the cured product having a high refractive index and high toughness and being not easily cracked or chipped when cutting, and a plastic lens obtained by curing the composition. A radical polymerizable composition includes phenylbenzyl(meth)acrylate (A), a urethane(meth)acrylate (X) having an aromatic ring in its molecular structure, and a radical polymerization initiator (Y) as essential components.

  提供了一种适用于涂层的低粘度的基础聚合物组合物，以及通过固化该组合物获得的固化产物，该固化产物具有高折射率和高韧性，在切割时不容易裂开或削掉，并通过固化该组合物获得的塑料透镜。基础聚合物组合物包括苯基苄基（甲基）丙烯酸酯（A），具有分子结构中芳香环的聚氨酯（甲基）丙烯酸酯（X）和自由基聚合引发剂（Y）作为必要组分。
• ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION, MANUFACTURING METHOD FOR ACTIVE ENERGY RAY-CURABLE RESIN COMPOSITION, COATING MATERIAL, COATING FILM, AND FILM
  申请人：DIC Corporation

  公开号：US20150361293A1

  公开（公告）日：2015-12-17

  Provided are a coating with good blocking resistance, transparency, and scratch resistance, a laminated film including such a coating, an active-energy-radiation-curable resin composition, and a method for manufacturing such a resin composition. The laminated film includes a coating layer and a plastic film layer. The coating layer is made of a resin composition containing, as essential components, fine inorganic particles (A) and a resin component (b) in a mass ratio [(A)/(b)] of 30/70 to 60/40. The coating has an arithmetic mean roughness (Ra) of 1 to 30 nm and a haze of 1.4 or less for a thickness of 100 μm or less.

  提供了一种具有良好阻塞抗性、透明性和耐刮擦性的涂层、包括这样一种涂层的层压膜、一种活性能量辐射固化树脂组合物以及一种制造这样的树脂组合物的方法。层压膜包括涂层层和塑料膜层。涂层层由含有精细无机颗粒(A)和树脂成分(b)的树脂组合物制成，其中(A)/(b)的质量比为30/70至60/40。对于100μm或更薄的厚度，涂层的算术平均粗糙度(Ra)为1至30nm，混浊度为1.4或更低。
• Process for producing a resin composition for powder coatings.
  申请人：UNITIKA LTD.

  公开号：EP0314447A2

  公开（公告）日：1989-05-03

  A resin composition for powder coatings that comprises a composition (A) and a blocked polyisocyanate compound (B), the composition (A) being based on both a carboxyl group containing polyester resin having a hydroxyl value of 10 to 100 and a softening point of 50 to 150°C and a glycidyl group containing acrylic resin having a hydroxyl value of 30 to 150 and a softening point of 50 to 150°C, and further containing a copolymer prepared by reaction between said polyester and acrylic resins. This resin composition is capable of providing an ideal paint film that possesses the features of a paint film prepared from polyester resins (high degrees of smoothness, gloss and strength) and those of a paint film prepared from acrylic resins (high levels of hardness, stain resistance and weatherability).

  一种用于粉末涂料的树脂组合物，由组合物（A）和封端多异氰酸酯化合物（B）组成，组合物（A）基于含羧基的聚酯树脂（羟基值为 10 至 100，软化点为 50 至 150°C）和含缩水甘油基的丙烯酸树脂（羟基值为 30 至 150，软化点为 50 至 150°C），还包含由上述聚酯树脂和丙烯酸树脂反应制备的共聚物。这种树脂组合物能够提供理想的漆膜，既具有聚酯树脂制备的漆膜的特点（高平滑度、光泽度和强度），又具有丙烯酸树脂制备的漆膜的特点（高硬度、抗污性和耐候性）。
• Electrochromic device
  申请人：NIPPON OIL CO., LTD.

  公开号：EP0752612A1

  公开（公告）日：1997-01-08

  An electrochromic device having a pair of electrically conductive counter plates (A, B, C), an ion conductive material (6) placed between the electrically conductive counter plates, a layer (4) containing an electrochromic material provided in at least one of locations between the ion conductive material and the electrically conductive counter plates, at least one of the electrically conductive counter plates being a transparent electrically conductive plate (A, B) having a transparent substrate (1a, 1b) and a transparent electrode (2a, 2b) disposed inside the transparent substrate, and at least one of the transparent electrically conductive plate having an ultraviolet absorbing layer (3) containing an organic ultraviolet absorber between the transparent substrate and the transparent electrode.

  一种电致变色装置，具有一对导电反板（A、B、C）、置于导电反板之间的离子导电材料（6）、在离子导电材料和导电反板之间的至少一个位置提供的含有电致变色材料的层（4）、导电反板中至少有一块是透明导电板（A、B），该板具有透明基板（1a、1b）和设置在透明基板内部的透明电极（2a、2b），透明导电板中至少有一块在透明基板和透明电极之间具有包含有机紫外线吸收剂的紫外线吸收层（3）。
• Cross-linkable, electrically conductive composition, electric conductor and process for forming the same
  申请人：NITTO CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0837112A2

  公开（公告）日：1998-04-22

  An anticorrosive composition comprising (a') an acidic group-containing, self-doping type soluble, electrically conducting polymer.

  一种防腐组合物，包含 (a') 一种含酸性基团、自掺杂型可溶性导电聚合物。