2,2-Di-pent-4-enyl-malonic acid | 855342-42-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2,2-Di-pent-4-enyl-malonic acid
• 英文别名: Di(4-pentenyl)malonic acid；2,2-bis(pent-4-enyl)propanedioic acid
• CAS: 855342-42-6
• 化学式: C₁₃H₂₀O₄
• 分子量: 240.299
• InChiKey: GCKUNEMFMXEHDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2-Di-pent-4-enyl-malonic acid 在 4-二甲氨基吡啶 作用下， 以 萘烷 为溶剂， 以12.3 g的产率得到2-戊-4-烯基庚-6-烯酸
  参考文献：
  名称：

  ADMET Synthesis of Polyolefins Targeted for Biological Applications

  摘要：

  A series of "N-terminus" amino acid and peptide branched, chiral polyolefins, termed bioolefins, have been prepared using acyclic diene metathesis (ADMET) polycondensation chemistry, using a minimal amount of solvent and Grubbs' second generation catalyst. The carboxylic acid functional groups were protected with methyl, benzyl, and tert-butyl esters to enhance both the polymerizability of the monomers themselves and the solubility of the resulting polymers. A number of these polymers are semicrystalline, exhibiting melt transitions of up to 132 and 74 degreesC for the amino acid and dipeptide branched polymers, respectively. Adding a succinic acid spacer between the amino acid entity and the polymer backbone alters the melting behavior of the polymer, increasing the peak melting point by 27 degreesC when compared to a polymer having the same amino acid directly attached to the polymer backbone.

  DOI：

  10.1021/ma035289u
• 作为产物：
  描述：

  diethyl 2,2-di-(4-pentenyl) malonate 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 反应 24.0h， 生成 2,2-Di-pent-4-enyl-malonic acid
  参考文献：
  名称：

  ADMET Synthesis of Polyolefins Targeted for Biological Applications

  摘要：

  A series of "N-terminus" amino acid and peptide branched, chiral polyolefins, termed bioolefins, have been prepared using acyclic diene metathesis (ADMET) polycondensation chemistry, using a minimal amount of solvent and Grubbs' second generation catalyst. The carboxylic acid functional groups were protected with methyl, benzyl, and tert-butyl esters to enhance both the polymerizability of the monomers themselves and the solubility of the resulting polymers. A number of these polymers are semicrystalline, exhibiting melt transitions of up to 132 and 74 degreesC for the amino acid and dipeptide branched polymers, respectively. Adding a succinic acid spacer between the amino acid entity and the polymer backbone alters the melting behavior of the polymer, increasing the peak melting point by 27 degreesC when compared to a polymer having the same amino acid directly attached to the polymer backbone.

  DOI：

  10.1021/ma035289u

文献信息

• Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof
  申请人：Baugh S. Lisa

  公开号：US20050137369A1

  公开（公告）日：2005-06-23

  The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH 2 —, unit B represents and unit D represents where R 1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

  本发明涉及一种具有重复单元A、B和D的线性功能聚合物。单元A代表—CH2—，单元B代表，单元D代表其中R1代表极性官能团。每个B单元、每个D单元和每个B和D单元之间至少有四个A单元。值y表示B单元的总数，是大于或等于1的整数。D单元的总数由h表示，是大于或等于0的整数。x表示A单元的总数，是一个足够使线性功能聚合物中B和D单元的摩尔分数由方程式j定义的整数，j=y+hx+y+h≤0.032。本发明还涉及一种制备这种线性功能聚合物的方法，通过共聚第一极性取代单体和第二非极性未取代单体。
• Linear functional copolymers of ethylene with precise and minimum run length distributions and methods of making thereof
  申请人：ExxonMobil Research and Engineering Company

  公开号：US07504465B2

  公开（公告）日：2009-03-17

  The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

  本发明涉及一种具有重复单元A、B和D的线性功能聚合物。单元A表示-CH2-，单元B表示，单元D表示其中R1表示一个极性功能基团。每个B单元、每个D单元以及每个B和D单元之间至少有四个A单元。值y表示B单元的总数，是大于或等于1的整数。D单元的总数由h表示，是大于或等于0的整数。x表示A单元的总数，是一个足够大的整数，以使线性功能聚合物中B和D单元的摩尔分数由方程式定义的值j表示：j=y+hx+y+h≤0.032。本发明还涉及通过共聚第一极性取代单体和第二非极性未取代单体来制备这种线性功能聚合物的方法。
• LINEAR FUNCTIONAL COPOLYMERS OF ETHYLENE WITH PRECISE AND MINIMUM RUN LENGTH DISTRIBUTIONS AND METHODS OF MAKING THEREOF
  申请人：ExxonMobil Research and Engineering Company

  公开号：EP1704172A1

  公开（公告）日：2006-09-27
• US7402642B2
  申请人：——

  公开号：US7402642B2

  公开（公告）日：2008-07-22
• US7504465B2
  申请人：——

  公开号：US7504465B2

  公开（公告）日：2009-03-17