N,N-(dithiodiethylene)bis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide | 897583-81-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-(dithiodiethylene)bis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide
• 英文别名: 4-methyl-N-[2-[2-[2-[[2-[(4-methylphenyl)sulfonylamino]phenyl]methylideneamino]ethyldisulfanyl]ethyliminomethyl]phenyl]benzenesulfonamide
• CAS: 897583-81-2
• 化学式: C₃₂H₃₄N₄O₄S₄
• 分子量: 666.91
• InChiKey: BQDLDONWWWHVQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  44
• 可旋转键数：
  15
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  184
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  N,N-(dithiodiethylene)bis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide 、 镉 在 tetramethylammonium perchlorate 作用下， 以 乙腈 为溶剂， 以60%的产率得到[Cd(N,N-(dithiodiethylenebis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide(-H))]
  参考文献：
  名称：

  双阴离子四齿席夫碱配体锌(II)和镉(II)配合物的电化学合成与表征

  摘要：

  阳极金属（锌或镉）在潜在螯合席夫碱 N,N-（二硫二亚乙基双（亚氨甲基亚甲基）双（1,2-亚苯基）二甲苯磺酰胺（H2L）的乙腈溶液中的电化学氧化得到稳定的经验式 [ML] 配合物） . [ZnL]·CH3CN (1) 和 [CdL] (2) 的晶体和分子结构已通过 X 射线衍射确定。在这两种配合物中，金属原子处于扭曲的四面体环境中，席夫碱作为四齿 N4 供体. 讨论了配合物的光谱数据（IR、ES MS 和 1H NMR 光谱）并与结构信息相关。

  DOI：

  10.1002/zaac.200700209
• 作为产物：
  描述：

  cystamine dihydrochioride 、 N-(2-甲酰基苯基)-4-甲基苯磺酰胺 在 sodium acetate 作用下， 以 甲醇 为溶剂， 反应 1.0h， 生成 N,N-(dithiodiethylene)bis(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide
  参考文献：
  名称：

  Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides

  摘要：

  On the basis of new ligand systems, bis-azomethines of N-tosylaminobenzaldehyde and alkyl(aryl)diaminodisulfides, mono- and binuclear chelates with 4N- and 2N2S-ligand arrangement were chemically (from metal acetates) or electrochemically (from metals in the zero oxidation state) first synthesized and characterized. Mononuclear chelates have a tetrahedral structure. In binuclear copper complexes the magnetic exchange interaction of the antiferromagnetic type was observed. Bisazomethines of disulfides were used as additives to lubricant oils.

  DOI：

  10.1134/s1070363209030128

文献信息

• Electrochemical synthesis and crystal structure of iron(II), cobalt(II), nickel(II) and copper(II) complexes of dianionic tetradentate N4 Schiff base ligand
  作者：Laura Rodríguez、Elena Labisbal、Antonio Sousa-Pedrares、José Arturo García-Vázquez、Jaime Romero、Antonio Sousa

  DOI：10.1016/j.ica.2010.01.034

  日期：2010.4

  Abstract The electrochemical oxidation of anodic metal (iron, cobalt, nickel and copper) in an acetonitrile solution of the potentially chelating Schiff base N,N(dithiodiethylenebis-(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide (H2L) afforded stable complexes of empirical formula [ML]. The compounds obtained have been characterized by microanalysis, IR spectroscopy and ES-MS mass spectrometry

  摘要在可能螯合的席夫碱N，N（二硫代二亚乙基双-（亚酰胺基甲基丙烯基）-双（1,2-亚苯基）二甲苯磺酰胺（H2L））的乙腈溶液中对阳极金属（铁，钴，镍和铜）进行电化学氧化[FeL]·CH3CN（1）[CoL]·CH3CN（2），[ NiL]·CH3CN（3）和[CuL]·CH3CN（4）已通过X射线衍射在所有配合物中测定，金属原子处于扭曲的四面体环境中，席夫碱为四齿N4供体。
• Electrochemical Synthesis and Characterization of Zinc(II) and Cadmium(II) Complexes of Dianionic Tetradentate Schiff Base Ligand
  作者：Laura Rodríguez、Elena Labisbal、Antonio Sousa-Pedrares、Jaime Romero、José-Arturo García Vázquez、Antonio Sousa

  DOI：10.1002/zaac.200700209

  日期：2007.9

  oxidation of anodic metal (zinc or cadmium) in acetonitrile solution of the potentially chelating Schiff base N,N-(dithiodiethylenebis(aminylydenemethylydene)bis(1,2-phenylene)ditosylamide (H2L) afforded stable complexes of empirical formula [ML]. The crystal and molecular structures of [ZnL]·CH3CN (1) and [CdL] (2) have been determined by X-ray diffraction. In both complexes the metal atom is in a distorted

  阳极金属（锌或镉）在潜在螯合席夫碱 N,N-（二硫二亚乙基双（亚氨甲基亚甲基）双（1,2-亚苯基）二甲苯磺酰胺（H2L）的乙腈溶液中的电化学氧化得到稳定的经验式 [ML] 配合物） . [ZnL]·CH3CN (1) 和 [CdL] (2) 的晶体和分子结构已通过 X 射线衍射确定。在这两种配合物中，金属原子处于扭曲的四面体环境中，席夫碱作为四齿 N4 供体. 讨论了配合物的光谱数据（IR、ES MS 和 1H NMR 光谱）并与结构信息相关。
• Electrochemical synthesis, structure, magnetic and tribochemical properties of metallochelates of new azomethine ligands, bis-[2-(N-tosylaminobenzylidenealkyl(aryl)]disulfides
  作者：A. S. Burlov、S. A. Mashchenko、O. A. Ivashchenko、D. A. Garnovskii、A. I. Uraev、M. S. Korobov、I. G. Borodkina、G. G. Chigarenko、A. G. Ponomarenko、A. D. Garnovskii

  DOI：10.1134/s1070363209030128

  日期：2009.3

  On the basis of new ligand systems, bis-azomethines of N-tosylaminobenzaldehyde and alkyl(aryl)diaminodisulfides, mono- and binuclear chelates with 4N- and 2N2S-ligand arrangement were chemically (from metal acetates) or electrochemically (from metals in the zero oxidation state) first synthesized and characterized. Mononuclear chelates have a tetrahedral structure. In binuclear copper complexes the magnetic exchange interaction of the antiferromagnetic type was observed. Bisazomethines of disulfides were used as additives to lubricant oils.