allyl dibutylcarbamate | 106775-55-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: allyl dibutylcarbamate
• 英文别名: O-allyl-N,N-dibutylcarbamate；Carbamic acid, dibutyl-, 2-propenyl ester；prop-2-enyl N,N-dibutylcarbamate
• CAS: 106775-55-7
• 化学式: C₁₂H₂₃NO₂
• 分子量: 213.32
• InChiKey: TYLBQZMDLJZFPT-UHFFFAOYSA-N

物化性质

• 沸点：
  271.4±10.0 °C(Predicted)
• 密度：
  0.917±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  碳酸烯丙基苯酯 、 二正丁胺 以 N,N-二甲基甲酰胺 为溶剂， 生成 allyl dibutylcarbamate 、 苯酚
  参考文献：
  名称：

  Mikheev, V. V.; Svetlakov, N. V.; Garipov, R. M., Journal of Organic Chemistry USSR (English Translation), 1982, vol. 18, # 10, p. 1865 - 1868

  摘要：

  DOI：

文献信息

• Liquid chromatography stationary phases with reduced silanol interactions
  申请人：Millipore Corporation

  公开号：US05374755A1

  公开（公告）日：1994-12-20

  Novel carbamate compounds, novel silylcarbamate compounds and novel reversed phase materials comprising a silica substrate modified with a modified novel silylcarbamate compound are disclosed which may, for example, be used as stationary phases for liquid chromatography applications. Attached to the carbamate group are several reversed or normal phase producing groups such as cyanoalkyl, tertiary butyl, dibutyl, octyl, dodecyl, tetradecyl, octadecyl or benzyl. The new stationary phases may be endcapped with a short chain alkyl silane. One particular advantage of these stationary phases is decreased interaction with basic samples due to shielding of the unreacted silanol groups on the silica surface. The new phases are particularly useful in the chromatographic analysis of basic samples or more generally for samples having an undesirable interaction with the unmodified silanols.

  揭示了新型碳酸酯化合物、新型硅基碳酸酯化合物和新型反相材料，其中包括用修改后的新型硅基碳酸酯化合物改性的硅基底物，可以用作液相色谱应用的固定相。与碳酸酯基团相连的是几个反向或正向相产生基团，如氰烷基、三丁基、二丁基、辛基、十二烷基、十四烷基、十八烷基或苄基。新的固定相可以用短链烷基硅烷进行端基封闭。这些固定相的一个特点是与碱性样品的相互作用减少，因为硅基表面上未反应的硅烷醇基团被屏蔽。新相在色谱分析中特别适用于碱性样品或更一般地用于与未改性硅烷醇发生不良相互作用的样品。
• Polyethylene Glycol–Enhanced Chemoselective Synthesis of Organic Carbamates from Amines, CO₂, and Alkyl Halides
  作者：De-Lin Kong、Liang-Nian He、Jin-Quan Wang

  DOI：10.1080/00397911.2010.517890

  日期：2011.11.15

  An efficient and environmentally benign method for the synthesis of organic carbamates was developed. Amines, CO2, and alkyl halides underwent a three-component reaction with the aid of K2CO3 and polyethylene glycol (PEG, MW 400), affording the organic carbamates under ambient conditions. PEG could presumably act as a solvent and phase-transfer catalyst (PTC). Notably, the presence of PEG could also depress the alkylation of both the amine and the carbamate, thus resulting in enhanced selectivity toward the target carbamate.Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.
• HORI YUJI; NAGANO YOSHIAKI; NAKAO JUNJI; FUKUHARA TAKASHI; TANIGUCHI HIRO+, CHEM. EXPRESS, 1,(1986) N 4, 224-227
  作者：HORI YUJI、 NAGANO YOSHIAKI、 NAKAO JUNJI、 FUKUHARA TAKASHI、 TANIGUCHI HIRO+

  DOI：——

  日期：——
• US5374755A
  申请人：——

  公开号：US5374755A

  公开（公告）日：1994-12-20