3-butoxystyrene | 156660-60-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-butoxystyrene
• 英文别名: 1-Butoxy-3-ethenylbenzene
• CAS: 156660-60-5
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: OSCMAPTUPNVIAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  乙酸乙烯酯 、 2-(3-butoxyphenyl)-1,3,2-dioxaborolane 在 potassium phosphate 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 2-甲基-2-丁醇 、 1,4-双(二苯基膦)丁烷 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以88%的产率得到3-butoxystyrene
  参考文献：
  名称：

  铑催化有机硼化合物与乙酸乙烯酯的交叉偶联

  摘要：

  一个新的偶联伙伴：醋酸乙烯酯在铑催化剂的存在下与有机硼化合物偶联；碳-碳键的形成发生在与乙酰氧基相连的乙烯基碳上。发现常规的镍和钯催化剂对该反应无效。

  DOI：

  10.1002/anie.200903146

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。
• Process for preparing star compounds
  申请人：SEKISUI CHEMICAL CO., LTD.

  公开号：EP0464408A1

  公开（公告）日：1992-01-08

  A process for preparing a three-branched or four-branched star compound comprising polymerizing an olefin compound represented by the formula wherein A is a single bond or phenylene group, and R3 is a hydrogen atom or methyl group and R4 is a monovalent organic group when A is a single bond, or R3 is a hydrogen atom and R4 is an alkyl group when A is a phenylene group, using as an initiator the adduct of a polyfunctional alkenyl ether represented by the formula (I) wherein R1 is a hydrogen atom or methyl group, n is an integer of 3 or 4, and R2 is a trivalent organic group when n is 3 or a tetravelent organic group when n is 4 with a cation-donating compound.

  一种制备三支链或四支链星状化合物的工艺，包括聚合由式表示的烯烃化合物 其中 A 为单键或亚苯基，R3 为氢原子或甲基，当 A 为单键时，R4 为单价有机基团，或当 A 为亚苯基时，R3 为氢原子，R4 为烷基，以式(I)表示的多官能团烯基醚的加合物作为引发剂 其中 R1 是氢原子或甲基，n 是 3 或 4 的整数，当 n 为 3 时，R2 是三价有机基团，当 n 为 4 时，R2 是四价有机基团。
• LOW-HYGROSCOPICITY LOW-BIREFRINGENCE RESIN COMPOSITIONS, MOLDING MATERIAL OBTAINED THEREFROM, SHEET OR FILM, AND OPTICAL PART
  申请人：HITACHI CHEMICAL COMPANY, LTD.

  公开号：EP1205517A1

  公开（公告）日：2002-05-15

  Low-hygroscopicity low-birefringence resin compositions, One of the compositions is a resin composition (a) comprising the following polymers (A), and (B) and/or (C). Another is a resin composition (b) comprising the following polymers (A), (B) and (H). Still another is a polymer comprising the following polymers (I) and (J), diphenylsilicone (D), and a phenolic antioxidant (E). (A) A polymer comprising one or more kinds of indene and indene derivatives represented by the following general formula (I). (B) A.polymer comprising polystyrene or a polystyrene derivative. (C) A polymer comprising a monomer copolymerizable with styrene or a styrene derivative. (H) A graft polymer having a structure wherein a polymer comprising at least one kind of indene and an indene derivative represented by the general formula (I) bonds to a side chain of a polymer comprising a monomer copolymerizable with styrene or a styrene derivative. (I) A polymer comprising one or more kinds of indene and indene derivatives represented by the general formula (I), wherein the polymer has a heterocyclic structure in a side chain thereof. (J) A polymer comprising styrene or a styrene derivative, and a monomer copolymerizable with styrene or a styrene derivative, wherein the polymer has a carboxyl group and/or a phenolic hydroxyl group in a side chain thereof.

  低吸湿性低双折射树脂组合物，其中一种组合物是由下列聚合物（A）、（B）和/或（C）组成的树脂组合物（a）。另一种是由以下聚合物（A）、（B）和（H）组成的树脂组合物（b）。还有一种是由以下聚合物（I）和（J）、二苯基硅酮（D）和酚类抗氧化剂（E）组成的聚合物。(A) 由一种或多种茚和茚衍生物组成的聚合物，其代表通式如下（I）。(B) 由聚苯乙烯或聚苯乙烯衍生物组成的聚合物。(C) 由可与苯乙烯或苯乙烯衍生物共聚的单体组成的聚合物。(H) 具有以下结构的接枝聚合物：由通式(I)代表的至少一种茚和茚衍生物组成 的聚合物与由可与苯乙烯或苯乙烯衍生物共聚的单体组成的聚合物的侧链键 合。(I) 由通式（I）代表的一种或多种茚和茚衍生物组成的聚合物，其中聚合物的侧链具有杂环结构。(J) 由苯乙烯或苯乙烯衍生物和可与苯乙烯或苯乙烯衍生物共聚的单体组成的聚 合物，其中聚合物的侧链中含有羧基和/或酚羟基。
• PROCESS FOR PRODUCTION OF NUCLEUS-HYDROGENATED AROMATIC VINYL /(METH)ACRYLATE COPOLYMERS
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2177541A1

  公开（公告）日：2010-04-21

  A safe and stable production method of a hydrogenated polymer having high transparency, which is a production method of a hydrogenated polymer by hydrogenating aromatic rings of an aromatic vinyl compound- (meth) acrylate copolymer, in which (1) a solvent solution of the copolymer is added to a reactor, which has a solvent and a supported palladium catalyst charged therein, under a hydrogen atmosphere at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction, and then such an operation is performed repeatedly that (2) a hydrogenated polymer is obtained from 30 to 90% by mass of the resulting reaction mixed solution, and a fresh solvent solution of the copolymer is added to the reactor, in which the residual reaction mixed solution is left, or to which the residual reaction mixed solution is returned, at a rate of from 0.01 to 15 g/hour in terms of the copolymer per unit mass (g) of the supported palladium catalyst, thereby performing hydrogenation reaction.

  一种安全稳定地生产具有高透明度的氢化聚合物的方法，它是通过氢化芳香族乙烯基化合物-(甲基)丙烯酸酯共聚物的芳香环来生产氢化聚合物的方法，其中(1)在氢气气氛下，将共聚物的溶剂溶液加入反应器中，该反应器中装有溶剂和支撑钯催化剂，以每单位质量(克)共聚物0.01至15克/小时（以每单位质量（克）的共聚物计），从而进行氢化反应，然后重复进行这样的操作，即(2)得到氢化聚合物，其质量占所得到的反应混合溶液的30%至90%，然后向反应器中加入新的共聚物溶剂溶液，在反应器中留下残余的反应混合溶液，或将残余的反应混合溶液返回到反应器中，以0.01至15克/小时（以每单位质量（克）支撑钯催化剂的共聚物计），从而进行氢化反应。