1-methoxy-2,3,4,5,6-pentamethylbenzene | 14804-37-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-methoxy-2,3,4,5,6-pentamethylbenzene
• 英文别名: 2,3,4,5,6-pentamethyl-anisole；2,3,4,5,6-Pentamethyl-anisol；6-Methoxy-1.2.3.4.5-pentamethyl-benzol；Methyl-(pentamethyl-phenyl)-aether；Benzene, methoxypentamethyl-
• CAS: 14804-37-6
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: SNPOZKMCSJMKKV-UHFFFAOYSA-N

物化性质

• 沸点：
  155-156 °C
• 密度：
  0.915±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-methoxy-2,3,4,5,6-pentamethylbenzene 在 氟磺酸 作用下， 生成
  参考文献：
  名称：

  Detsina, A. N.; Sidorova, N. V.; Mainagashev, I. Ya., Journal of Organic Chemistry USSR (English Translation), 1983, vol. 19, p. 1688 - 1693

  摘要：

  DOI：
• 作为产物：
  描述：

  3,4,5-Trimethylanisole 在 氢氧化钾 、 一水合肼 、 三氯氧磷 、 二乙二醇 作用下， 反应 4.0h， 生成 1-methoxy-2,3,4,5,6-pentamethylbenzene
  参考文献：
  名称：

  Buu-Hoi et al., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1955, vol. 240, p. 2241

  摘要：

  DOI：

文献信息

• Methylation of phenol and its derivatives with dimethyl carbonate in the presence of Mn2(CO)10, W(CO)6, and Co2(CO)8
  作者：R. I. Khusnutdinov、N. A. Shchadneva、Yu. Yu. Mayakova

  DOI：10.1134/s1070428015030070

  日期：2015.3

  Aryl methyl ethers were synthesized by reactions of phenol, substituted phenols, and α- and β-naphthols with dimethyl carbonate in the presence of manganese, tungsten, and cobalt carbonyls. Optimal reactant and catalyst ratios and reaction conditions were found to ensure selective formation of aryl methyl ethers.

  在锰，钨和羰基钴的存在下，通过苯酚，取代的苯酚以及α-和β-萘酚与碳酸二甲酯的反应合成芳基甲基醚。发现最佳的反应物和催化剂比例以及反应条件可确保选择性形成芳基甲基醚。
• Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
  申请人：Small L. Brooke

  公开号：US20070021608A1

  公开（公告）日：2007-01-25

  Methods for making α-diimine metal complexes are described. The methods comprise forming an α-diimine metal complex imine bond in the presence of a metal salt or an α-acylimine metal complex. The method is particularly using for the production of α-diimine metal complexes having two different α-diimine nitrogen groups. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins.

  描述了制备α-二亚胺金属配合物的方法。该方法包括在金属盐或α-酰亚胺金属配合物存在下形成α-二亚胺金属配合物亚胺键。该方法特别适用于生产具有两个不同α-二亚胺氮基团的α-二亚胺金属配合物。这些α-二亯金属配合物对于聚合或寡聚烯烃很有用。
• Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
  申请人：Small L. Brooke

  公开号：US20070027334A1

  公开（公告）日：2007-02-01

  Novel α-diimine metal complexes, particularly iron complexes are disclosed. The α-diimine metal complexes are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. α-diimine metal complexes having two different α-diimine nitrogen groups may be produced. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins.

  本发明揭示了新型α-二亚胺金属配合物，尤其是铁配合物。α-二亚胺金属配合物是通过在金属盐或α-酰基亚胺金属配合物的存在下形成其中一个α-二亚胺金属配合物亚胺键而产生的。可以制备具有两种不同α-二亚胺氮基团的α-二亚胺金属配合物。这些α-二亚胺金属配合物可用于聚合或寡聚烯烃。
• TRIAZINE COMPOUNDS, POLYMERS COMPRISING TRIAZINE STRUCTURAL UNITS, AND METHOD
  申请人：Brown Bruce Sterling

  公开号：US20080097040A1

  公开（公告）日：2008-04-24

  In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.

  在各种实施方式中，本发明包括2,4,6-三取代-1,3,5-三嗪封端剂，其中包括一个、两个或三个离去基团作为取代基，其余取代基基本上对与聚合物或单体上的亲核基反应无反应性，或者与聚合物或单体上的亲核基反应速率比任何离去基团慢。本发明还包括具有嘧啶基团封端的聚合物或单体。本发明的其他实施方式还包括用嘧啶类封端剂封闭聚合物或单体中的亲核基的过程，其中包括将聚合物或单体与含三嗪的封端剂结合并反应。
• Diimine Metal Complexes, Methods of Synthesis, and Methods of Using in Oligomerization and Polymerization
  申请人：Small Brooke L.

  公开号：US20100222577A1

  公开（公告）日：2010-09-02

  Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.

  本发明揭示了一种具有苯基硫醇或取代苯基硫醇金属配合基的 Novel α-二亚胺金属配合物，特别是铁配合物。通过在金属盐或α-酰亚胺金属配合物的存在下形成α-二亚胺金属配合物之一的亚胺键来制备具有苯基硫醇或取代苯基硫醇金属配合基的α-二亚胺金属配合物。具有苯基硫醇或取代苯基硫醇金属配合基的α-二亚胺金属配合物可用于聚合或寡聚烯烃。