NSC87887 | 62625-13-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: NSC87887
• 英文别名: N-[(2,4-dichloro-phenoxy)-acetyl]-DL-methionine；N-[(2,4-Dichlor-phenoxy)-acetyl]-DL-methionin；Methionine, N-[2-(2,4-dichlorophenoxy)acetyl]-；2-[[2-(2,4-dichlorophenoxy)acetyl]amino]-4-methylsulfanylbutanoic acid
• CAS: 62625-13-2
• 化学式: C₁₃H₁₅Cl₂NO₄S
• 分子量: 352.238
• InChiKey: UJTANULYSZODGX-UHFFFAOYSA-N

物化性质

• 沸点：
  609.9±55.0 °C(Predicted)
• 密度：
  1.401±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  101
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  DL-蛋氨酸 、 2-(2,6-二氯苯氧基)乙酰氯 在 sodium hydroxide 、 苯 作用下， 生成 NSC87887
  参考文献：
  名称：

  SYNTHETIC PLANT-GROWTH REGULATORS. III. 2,4-DICHLORO-PHENOXYACETYL DERIVATIVES OF AMINO ACIDS

  摘要：

  DOI：

  10.1021/jo01140a017

文献信息

• Intercalates and exfoliates formed with organic pesticide compounds and compositions containing the same
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0808568A1

  公开（公告）日：1997-11-26

  Intercalates formed by contacting an activated layered material, e.g., an activated phyllosilicate, with an intercalant pesticide to intercalate an intercalant pesticide between adjacent platelets of the layered material are disclosed. Sufficient intercalant pesticide is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 Å (as measured after water removal to a maximum of 5% by weight water) up to about 100 Å, and preferably in the range of about 10 to about 45 Å, so that, if desired, the intercalate can be exfoliated into individual platelets. The intercalate can be combined with an organic liquid to form a viscous composition for delivery of a pesticide compound. Alternatively, the intercalate can be exfoliated prior to combination with the organic liquid. The intercalated complex also can be admixed with solid particles to provide a granular, dust, or wettable powder pesticide composition.

  本发明公开了通过将活化的层状材料（例如活化的叶硅酸盐）与插层剂杀虫剂接触，使插层剂杀虫剂在层状材料的相邻小板之间插层而形成的互化物。相邻小板之间吸附了足够的插层农药，使相邻小板之间的间距扩大到至少约 5 Å（按除水至最多 5%（重量）水后的测量值）至约 100 Å，最好在约 10 Å 至约 45 Å 的范围内，这样，如果需要，插层可以剥离成单个小板。夹层可以与有机液体结合，形成一种粘性组合物，用于输送农药化合物。或者，也可以在与有机液体结合之前将中间产物剥离。夹层复合物还可以与固体颗粒混合，形成颗粒状、粉尘状或可湿性粉末状农药组合物。
• Method and compositions for controlling release of organic compositions
  申请人：Boyd A. Stephen

  公开号：US20060157667A1

  公开（公告）日：2006-07-20

  A method and compositions using layered clays with monovalent potassium, ammonium or cesium ions in the galleries of the clay which are also occupied by a preferably polar or semi polar organic compound. The method and compositions are particularly useful for controlled release of pesticides, insecticides, herbicides, fungicides, nematocides and contaminants in the presence of calcium or magnesium, or other naturally occurring inorganic cations as divalent displacement ions providing the release.

  一种使用层状粘土的方法和组合物，粘土的廊道中含有单价钾离子、铵离子或铯离子，这些离子也被优选的极性或半极性有机化合物占据。在有钙或镁或其他天然存在的无机阳离子作为二价置换离子提供释放的情况下，这种方法和组合物特别适用于杀虫剂、杀虫剂、除草剂、杀真菌剂、杀线虫剂和污染物的控制释放。
• LIU, FUAN;ZHANG, LANJUN;CUI, XIAOYUAN;HUANG, HUAMIN, TSZILIN DASYUEH TSZYZHAN KEHSYUEH SYUEHBAO,(1988) N, S. 70-71
  作者：LIU, FUAN、ZHANG, LANJUN、CUI, XIAOYUAN、HUANG, HUAMIN

  DOI：——

  日期：——
• SYNTHETIC PLANT-GROWTH REGULATORS. III. 2,4-DICHLORO-PHENOXYACETYL DERIVATIVES OF AMINO ACIDS
  作者：JOHN W. WOOD、THOMAS D. FONTAINE

  DOI：10.1021/jo01140a017

  日期：1952.6