Vinylidene chloride methylacrylate itaconic acid

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Vinylidene chloride methylacrylate itaconic acid
• 英文别名: 1,1-dichloroethene;2-methylidenebutanedioic acid;methyl prop-2-enoate
• 化学式: C11H14Cl2O6
• 分子量: 313.13
• InChiKey: HATRZINXSXGGHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.38
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  101
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  、 丙烯酸甲酯（MA） 、 衣康酸 、 sodium dodecyl-sulfate 、 4,4'-偶氮双(4-氰基戊酸) 、 4-氰基戊酸 、 1,1-二氯乙烯 、 在 氮气 作用下， 以 水 为溶剂， 反应 22.17h， 以to give a terpoly(vinylidene chloride-methylacrylate-itaconic acid) latex with 17.5 weight percent solids的产率得到Vinylidene chloride methylacrylate itaconic acid
  参考文献：
  名称：

  Photographic element comprising antistatic layer

  摘要：

  一种摄影元件，包括聚合物薄膜基材、银卤化物乳剂层和抗静电层，其中抗静电层包括胶态氧化钒和乙烯基添加物分散物，其干重比为1：30至1：500。抗静电层可以作为支撑层存在于基材相对于银卤化物乳剂层的一侧，可以作为单面或双面涂覆的摄影元件中基材和乳剂层之间的粘合层，也可以作为基材和不同支撑层之间的粘合层。抗静电层上没有使用障壁层。

  公开号：

  US05914222A1

文献信息

• Sheet or web material having antistatic properties
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0554588A1

  公开（公告）日：1993-08-11

  A sheet or web material comprising a hydrophobic resin support or paper support coated with at least one hydrophobic resin layer wherein said resin support or resin layer is coated with a transparent antistatic layer containing as an essential component a polythiophene with conjugated polymer backbone in the presence of a polymeric polyanion compound, characterized in that said antistatic layer is coated with an overlying adhering barrier layer applied from an aqueous polymer dispersion wherein the dispersed polymer has hydrophilic functionality sufficient to render said overlying layer adherent to a thereon coated hydrophilic colloid-containing layer.

  一种薄片或卷筒材料，包括至少涂有一层疏水性树脂层的疏水性树脂支架或纸支架，其中所述树脂支架或树脂层上涂有一层透明的抗静电层，该层的主要成分是在聚合物聚阴离子化合物存在下具有共轭聚合物骨架的聚噻吩、其特征在于，在所述抗静电层上涂覆一层由水性聚合物分散体制成的附着阻隔层，其中分散聚合物具有亲水功能，足以使所述附着层附着在其上涂覆的含亲水胶体层上。
• Antistatic coating composition
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0593111A1

  公开（公告）日：1994-04-20

  An aqueous coating composition suited for the production of an antistatic layer on a water resistant resin member which composition contains as an essential antistatic component a polythiophene with conjugated polymer backbone in the presence of a polymeric polyanion compound, characterized in that said composition also contains a dispersion of a hydrophobic polymer, said polymer having a glass transition temperature (Tg) of at least 40 °C and said composition being capable of forming a coherent layer on drying said dispersion.

  一种适用于在防水树脂构件上制作抗静电层的水性涂料组合物，该组合物的基本抗静电成分是一种具有共轭聚合物骨架的聚噻吩，其存在物是一种高分子聚阴离子化合物，其特征在于所述组合物还含有一种疏水性聚合物的分散体，所述聚合物的玻璃化转变温度（Tg）至少为 40 °C，并且所述组合物在干燥所述分散体时能够形成一个连贯的层。
• A novel class of non-sensitizing infra-red dyes for use in photosensitive elements
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0779540A1

  公开（公告）日：1997-06-18

  A novel class of non-sensitizing infra-red dyes derived from heptamethine dyes with indolenine nuclei is disclosed. They are useful as filter-, acutance- or antihalation dyes for photographic elements based on silver halide or for photothermographic elements.

  本发明公开了一类新型非致敏红外染料，它们来自具有吲哚啉核的七甲基染料。它们可用作基于卤化银的照相元件或光热成像元件的滤光、抗敏或防光晕染料。
• Thermographic material with outermost organic antistatic layer
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0779539A1

  公开（公告）日：1997-06-18

  A (photo)thermographic recording material comprising a (photo-addressable) thermosensitive element, a support and an outermost antistatic layer, the thermosensitive element comprising a substantially light-insensitive organic silver salt, an organic reducing agent for the substantially light-insensitive organic silver salt in thermal working relationship therewith and a binder, characterized in that the outermost antistatic layer is an organic layer with a resistivity of < 1010Ω/□ at a relative humidity of 30%. The outermost antistatic layer may comprise a polythiophene with conjugated polymer backbone in the presence of a polymeric polyanion compound and a hydrophobic organic polymer having a glass transition value (Tg) of at least 40°C, the polythiophene being present at a coverage of at least 0.001g/m2 and the weight ratio of the polythiophene to the hydrophobic organic polymer being in the range of 1/10 to 1/1000. A production process for the thermographic recording material and a thermographic recording process therefor are also provided.

  一种(光)热成像记录材料，包括(可光敏寻址的)热敏元件、支架和最外层抗静电层，热敏元件包括基本上不感光的有机银盐、与基本上不感光的有机银盐有热工作关系的有机还原剂和粘结剂，其特征在于最外层抗静电层是在相对湿度为30％时电阻率小于1010Ω/□的有机层。最外层抗静电层可以由具有共轭聚合物骨架的聚噻吩和聚阴离子化合物以及玻璃化转变值（Tg）至少为 40°C 的疏水性有机聚合物组成，聚噻吩的覆盖率至少为 0.001g/m2，聚噻吩与疏水性有机聚合物的重量比在 1/10 至 1/1000 之间。此外，还提供了热成像记录材料的生产工艺及其热成像记录工艺。
• Photothermographic recording material comprising sensitizing dyes and a recording process therefor
  申请人：AGFA-GEVAERT N.V.

  公开号：EP0821266A1

  公开（公告）日：1998-01-28

  A photothermographic recording material comprising a support and a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a binder, characterized in that the dye corresponds to the general formula (I): with an anion if necessary for charge compensation, wherein Z1 and Z2 independently represent S, O or Se; R1 and R13 independently represent an alkylene group; X1 and X2 independently represent a -(C=O)-R18, a -(SO2)-R19 or a -(S=O)-R20 group where R18, R19 and R20 independently represent an alkoxy-, aryloxy-, amino- or substituted amino-group; R2, R3, R4, R5, R14, R15, R16 and R17 independently represent hydrogen, chlorine, bromine, fluorine, iodine or a keto-, sulfo-, carboxy-, ester-, sulfonamide-, amide-, dialkylamino-, nitro-, cyano-, alkyl-, alkenyl-, hetero-aromatic, aryl-, alkoxy- or aryloxy-group, which groups may be substituted; or each of R2 together with R3, R3 together with R4, R4 together with R5, R14 together with R15, R15 together with R16 and R16 together with R17 may independently constitute the atoms necessary to complete a benzene ring which may be substituted; R6, R7, R8, R9, R10, R11 and R12 independently represent hydrogen, chlorine, bromine, fluorine, iodine, an alkyl group, a substituted alkyl group, an alkoxy group, an aryloxy group, a thioalkyl group, a disubstituted amino group, where the substituents may constitute the atoms necessary to complete a 5-ring atom or 6-ring atom heterocyclic ring, or each of R6 together with R8, R8 together with R10, R10 together with R12, R7 together with R9 and R9 together with R11 may independently constitute the atoms necessary to complete a 5-atom or 6-atom carbocylic or heterocyclic ring which may be substituted; and each of R1 together with R6 and R13 together with R12 may independently constitute the atoms necessary to complete a 5-ring atom or 6-ring atom heterocyclic ring which may be substituted.

  一种光热成像记录材料，包括一个支撑体和一个可光敏热显影元件，该元件包括基本上不感光的有机银盐、与之有热工作关系的还原剂、用染料分光敏化并与基本上不感光的有机银盐和粘合剂催化结合的光敏卤化银，其特征在于染料对应于通式(I)： 其中 Z1 和 Z2 独立地代表 S、O 或 Se；R1 和 R13 独立地代表亚烷基；X1 和 X2 独立地代表-(C=O)-R18、-(SO2)-R19 或-(S=O)-R20 基团，其中 R18、R19 和 R20 独立地代表烷氧基、芳氧基、氨基或取代氨基；R2、R3、R4、R5、R14、R15、R16 和 R17 独立地代表氢、氯、溴、氟、碘或酮基、磺基、羧基、酯基、磺酰胺基、酰胺基、二烷基氨基、硝基、氰基、烷基、烯基、杂芳基、芳基、烷氧基或芳氧基，这些基团可以被取代；或 R2 连同 R3、R3 连同 R4、R4 连同 R5、R14 连同 R15、R15 连同 R16 和 R16 连同 R17 中的每一个可独立构成完成苯环所需的原子，该苯环可被取代；R6、R7、R8、R9、R10、R11 和 R12 可独立代表氢、氯、溴、氟、碘、烷基、取代烷基、烷氧基、芳氧基、硫代烷基、二取代氨基，其中取代基可构成完成 5 环原子或 6 环原子杂环所需的原子、或 R6 与 R8、R8 与 R10、R10 与 R12、R7 与 R9 和 R9 与 R11 中的每一个可独立构成完成可被取代的 5 原子或 6 原子碳环或杂环所需的原子；R1 与 R6 和 R13 与 R12 可各自独立地构成完成可被取代的 5 环原子或 6 环原子杂环所需的原子。