N-(2-(phenylseleno)ethyl)-N-(1-methyl-imidazol-2-ylmethylene)amine | 1422347-33-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: N-(2-(phenylseleno)ethyl)-N-(1-methyl-imidazol-2-ylmethylene)amine
• 英文别名: 1-(1-methylimidazol-2-yl)-N-(2-phenylselanylethyl)methanimine
• CAS: 1422347-33-8
• 化学式: C₁₃H₁₅N₃Se
• 分子量: 292.242
• InChiKey: CMFUGSPQDCKPNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.29
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  30.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cobalt(II) chloride hexahydrate 、 N-(2-(phenylseleno)ethyl)-N-(1-methyl-imidazol-2-ylmethylene)amine 以 乙醇 、 二氯甲烷 为溶剂， 以45%的产率得到[N-(2-(phenylseleno)ethyl)-N-(1-methyl-imidazol-2-ylmethylene)amine]cobalt(II) dichloride
  参考文献：
  名称：

  Novel copper(II) and cobalt(II) complexes with selenium substituted imidazolyl imines. The molecular and crystal structure of [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(II) dichloride

  摘要：

  A series of copper(II) and cobalt(II) complexes with novel selenium containing Schiff base ligands obtained from 2- or 3-aminoalkyl phenyl selenides and imidazole carbaldehydes have been synthesized by the interaction of corresponding organic ligands with MCl2 center dot 6H(2)O (M = Cu, Co). The crystal structure of a copper(II) complex with N-(2-(phenylseleno)ethyl)-N-(imidazolyl-2-ylmethylene)amine has been solved by a single-crystal X-ray diffraction method. The copper(II) ions are coordinated by the imine and imidazole nitrogen atoms of organic ligands and two chloride anions in a distorted square planar geometry. The electrochemical investigations of the synthesized ligands and complexes have been made by cyclic voltammetry method. It is established that the first stage of complexes reduction takes place to metal and the reduced forms of complexes are stable in the solution. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.039
• 作为产物：
  描述：

  2-(phenylselanyl)ethanamine hydrochloride 在 potassium hydroxide 作用下， 以 乙醇 为溶剂， 反应 7.0h， 生成 N-(2-(phenylseleno)ethyl)-N-(1-methyl-imidazol-2-ylmethylene)amine
  参考文献：
  名称：

  Novel copper(II) and cobalt(II) complexes with selenium substituted imidazolyl imines. The molecular and crystal structure of [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(II) dichloride

  摘要：

  A series of copper(II) and cobalt(II) complexes with novel selenium containing Schiff base ligands obtained from 2- or 3-aminoalkyl phenyl selenides and imidazole carbaldehydes have been synthesized by the interaction of corresponding organic ligands with MCl2 center dot 6H(2)O (M = Cu, Co). The crystal structure of a copper(II) complex with N-(2-(phenylseleno)ethyl)-N-(imidazolyl-2-ylmethylene)amine has been solved by a single-crystal X-ray diffraction method. The copper(II) ions are coordinated by the imine and imidazole nitrogen atoms of organic ligands and two chloride anions in a distorted square planar geometry. The electrochemical investigations of the synthesized ligands and complexes have been made by cyclic voltammetry method. It is established that the first stage of complexes reduction takes place to metal and the reduced forms of complexes are stable in the solution. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.039

文献信息

• Novel copper(II) and cobalt(II) complexes with selenium substituted imidazolyl imines. The molecular and crystal structure of [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(II) dichloride
  作者：Elena K. Beloglazkina、Alexander G. Majouga、Roman L. Antipin、Kseniya A. Myannik、Anna A. Moiseeva、Nikolai V. Zyk

  DOI：10.1016/j.poly.2012.11.039

  日期：2013.2

  A series of copper(II) and cobalt(II) complexes with novel selenium containing Schiff base ligands obtained from 2- or 3-aminoalkyl phenyl selenides and imidazole carbaldehydes have been synthesized by the interaction of corresponding organic ligands with MCl2 center dot 6H(2)O (M = Cu, Co). The crystal structure of a copper(II) complex with N-(2-(phenylseleno)ethyl)-N-(imidazolyl-2-ylmethylene)amine has been solved by a single-crystal X-ray diffraction method. The copper(II) ions are coordinated by the imine and imidazole nitrogen atoms of organic ligands and two chloride anions in a distorted square planar geometry. The electrochemical investigations of the synthesized ligands and complexes have been made by cyclic voltammetry method. It is established that the first stage of complexes reduction takes place to metal and the reduced forms of complexes are stable in the solution. (C) 2012 Elsevier Ltd. All rights reserved.