1,3-di(but-3-enyl)-1,3-dimethyl-1,3-disilacyclobutane | 630046-96-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 1,3-di(but-3-enyl)-1,3-dimethyl-1,3-disilacyclobutane
• 英文别名: 1,3-Dimethyl-1,3-di(but-3-enyl)1,3-disilacyclobutane；1,3-bis(but-3-enyl)-1,3-dimethyl-1,3-disiletane
• CAS: 630046-96-7
• 化学式: C₁₂H₂₄Si₂
• 分子量: 224.494
• InChiKey: RWIJGFFBSNVTPQ-UHFFFAOYSA-N

物化性质

• 沸点：
  241.8±35.0 °C(Predicted)
• 密度：
  0.83±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.39
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (but-3-enyl)chloromethylmethylchlorosilane 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以49%的产率得到1,3-di(but-3-enyl)-1,3-dimethyl-1,3-disilacyclobutane
  参考文献：
  名称：

  Cross-Linkable Carbosilane Polymers with Imbedded Disilacyclobutane Rings Derived by Acyclic Diene Metathesis Polymerization

  摘要：

  Cyclolinear carbosilane polymers with disilacyclobutane (DSCB) rings in the main-chain structure were prepared by means of acyclic diene metathesis (ADMET) polymerization of the corresponding 1,3-dibutenyl-1,3-disilacyclobutanes. The copolymerization of a monomer of this type with a noncyclic organosilane diene allowed for the incorporation of a varying number of DSCB rings into the polymer backbone. Subsequent hydrogenation of the double bonds with p-toluenesulfonhydrazide resulted in a saturated hydrocarbon structure in the main chain without affecting the DSCB ring. All of the resultant polymers are well-defined materials with DSCB rings incorporated into the backbone structure, as evidenced by NMR spectroscopy and GPC analyses. The thermal behavior of these polymers was characterized by DSC and TGA. DSC indicated low T(g)s, and TGA evidenced high thermal stability in an inert atmosphere. In addition, large exothermic peaks were observed in the DSC, which indicated, along with the IR and solid-state Si-29 NMR spectra, that cross-linking occurs during heating to ca. 250 degreesC via opening of the imbedded DSCB rings. The swelling properties of the resultant, thermally stable, carbosilane network materials on exposure to various solvents were also examined.

  DOI：

  10.1021/ma049760a

文献信息

• Cross-Linkable Carbosilane Polymers with Imbedded Disilacyclobutane Rings Derived by Acyclic Diene Metathesis Polymerization
  作者：Zhizhong Wu、Jerry P. Papandrea、Tom Apple、Leonard V. Interrante

  DOI：10.1021/ma049760a

  日期：2004.7.1

  Cyclolinear carbosilane polymers with disilacyclobutane (DSCB) rings in the main-chain structure were prepared by means of acyclic diene metathesis (ADMET) polymerization of the corresponding 1,3-dibutenyl-1,3-disilacyclobutanes. The copolymerization of a monomer of this type with a noncyclic organosilane diene allowed for the incorporation of a varying number of DSCB rings into the polymer backbone. Subsequent hydrogenation of the double bonds with p-toluenesulfonhydrazide resulted in a saturated hydrocarbon structure in the main chain without affecting the DSCB ring. All of the resultant polymers are well-defined materials with DSCB rings incorporated into the backbone structure, as evidenced by NMR spectroscopy and GPC analyses. The thermal behavior of these polymers was characterized by DSC and TGA. DSC indicated low T(g)s, and TGA evidenced high thermal stability in an inert atmosphere. In addition, large exothermic peaks were observed in the DSC, which indicated, along with the IR and solid-state Si-29 NMR spectra, that cross-linking occurs during heating to ca. 250 degreesC via opening of the imbedded DSCB rings. The swelling properties of the resultant, thermally stable, carbosilane network materials on exposure to various solvents were also examined.