2-(1-phenyl-1H-tetrazol-5-ylthio)benzene-1,4-diol | 1660-27-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 2-(1-phenyl-1H-tetrazol-5-ylthio)benzene-1,4-diol
• 英文别名: 2-(1-phenyl-1H-tetrazol-5-ylsulfanyl)-benzene-1,4-diol；2-<1-Phenyl-tetrazolyl-(5)-mercapto>-hydrochinon；2-(1-Phenyl-5-tetrazolylthio)hydrochinon；1,4-Benzenediol, 2-[(1-phenyl-1H-tetrazol-5-yl)thio]-；2-(1-phenyltetrazol-5-yl)sulfanylbenzene-1,4-diol
• CAS: 1660-27-1
• 化学式: C₁₃H₁₀N₄O₂S
• mdl: MFCD00186095
• 分子量: 286.314
• InChiKey: QEOMLJRJPCAIPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  对苯二酚 、 1-苯基-5-巯基四氮唑 在 sodium acetate 作用下， 以 水 、 乙腈 为溶剂， 以96%的产率得到2-(1-phenyl-1H-tetrazol-5-ylthio)benzene-1,4-diol
  参考文献：
  名称：

  1,2-和1,4-二羟基苯与1-Phenyl-5-mercaptotetrazole的电氧化/ Michael型顺序反应制备多官能的噻唑类硫醚

  摘要：

  在存在1-苯基-5-巯基四唑作为亲核试剂的情况下，使用循环伏安法和控制电位库仑法研究了水溶液中1,2-和1,4-二羟基苯的电化学氧化。伏安法结果表明，硫醇根阴离子与电化学生成的苯醌之间发生电氧化/迈克尔型顺序反应，从而导致相应的多官能四唑硫醚。电化学反应的机制被证明是使用控制电位库仑法的EC途径。另外，已经在环境条件下使用具有高原子经济性的环境友好方法在未分割的电池中成功地进行了四唑硫醚的电合成。

  DOI：

  10.1021/jo702327m

文献信息

• CONDUCTIVE COMPOSITION, CONDUCTIVE MEMBER AND PRODUCTION METHOD THEREOF, TOUCH PANEL, AND SOLAR CELL
  申请人：FUJIFILM Corporation

  公开号：US20140202531A1

  公开（公告）日：2014-07-24

  A conductive composition includes at least: a) metal conductive fibers having an average minor axis length of from 1 nm to 150 nm; and b) a compound represented by the following Formula (1) or Formula (2) in an amount of from 0.1% by mass to 1000% by mass with respect to the metal conductive fibers: P—(CR 1 ═Y) n -Q  Formula (1) wherein, in Formula (1), P and Q each independently represent a group represented by OH, NR 2 R 3 or CHR 4 R 5 , in which R 2 and R 3 each independently represent a hydrogen atom or a group that can be substituted on a nitrogen atom, and R 4 and R 5 each independently represent a hydrogen atom or a substituent; Y represents CR 6 or a nitrogen atom; R 1 and R 6 each independently represent a hydrogen atom or a substituent; at least two of the groups represented by R 1 , R 2 , R 3 , R 4 , R 5 or R 6 may be bonded to each other to form a ring; n represents an integer from 0 to 5; when n is 0, neither P nor Q is a group represented by OH or CHR 4 R 5 ; and when n represents a number of 2 or greater, the plurality of atomic groups each represented by (CR 1 ═Y) may be the same as or different from each other; R 7 —C(═O)—H  Formula (2) wherein, in Formula (2), R 7 represents a hydrogen atom, an OH group, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group.
• ORGANIC SEMICONDUCTOR COMOSITION, ORGANIC THIN-FILM TRANSISTOR, ELECTRONIC PAPER, AND DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20160064674A1

  公开（公告）日：2016-03-03

  An object of the present invention is to provide an organic semiconductor composition, which improves the insulation reliability of an organic thin-film transistor without greatly reducing the mobility of the organic thin-film transistor, an organic thin-film transistor which is prepared by using the organic semiconductor composition, and electronic paper and a display device which use the organic thin-film transistor. The organic semiconductor composition of the present invention contains an organic semiconductor material (A) and a polymer compound (B) containing a repeating unit represented by the following Formula (B).
• US3975395A
  申请人：——

  公开号：US3975395A

  公开（公告）日：1976-08-17
• US4377634A
  申请人：——

  公开号：US4377634A

  公开（公告）日：1983-03-22
• US4401751A
  申请人：——

  公开号：US4401751A

  公开（公告）日：1983-08-30