2-trifluoromethyl acrylic acid propyl ester | 105935-18-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-trifluoromethyl acrylic acid propyl ester
• 英文别名: Propyl 2-(trifluoromethyl)prop-2-enoate
• CAS: 105935-18-0
• 化学式: C₇H₉F₃O₂
• 分子量: 182.142
• InChiKey: OTPPJRROTZEJEB-UHFFFAOYSA-N

物化性质

• 沸点：
  163.9±40.0 °C(Predicted)
• 密度：
  1.146±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  丙醇 、 1,2-二溴-3,3,3-三氟丙烷 、 一氧化碳 在 bis-triphenylphosphine-palladium(II) chloride 三乙胺 作用下， 以 四氢呋喃 为溶剂， 120.0 ℃ 、1.0 MPa 条件下， 反应 5.0h， 以65.4%的产率得到2-trifluoromethyl acrylic acid propyl ester
  参考文献：
  名称：

  EP1637514

  摘要：

  公开号：

文献信息

• RESIST POLYMER, RESIST COMPOSITION, PROCESS FOR PATTERN FORMATION, AND STARTING COMPOUNDS FOR PRODUCTION OF THE RESIST POLYMER
  申请人：Momose Hikaru

  公开号：US20090198065A1

  公开（公告）日：2009-08-06

  To provide a resist polymer comprising, as a structural unit, an acid-decomposable unit having a structure represented by formula (1) or (2) which exhibits a small line edge roughness and produces little defects in DUV excimer laser lithography or the like. In formulas (1) and (2), n represents an integer of 2 to 24; J represents a single bond or a divalent hydrocarbon group which may have a substituent/heteroatom when n=2, or represents an n-valent hydrocarbon group which may have a substituent/heteroatom when n≧3; E represents a residue of a polymerization terminator, a chain transfer agent or a polymerization initiator; K 1 and K 2 each represent at least one selected from alkylene, cycloalkylene, oxyalkylene, arylene, a divalent thiazoline ring, a divalent oxazoline ring and a divalent imidazoline ring; L 1 and L 2 each represent at least one selected from —C(O)O—, —C(O)— and —OC(O)—; M 1 , M 2 and M 3 each represent at least one selected from alkylene, cycloalkylene, oxyalkylene and arylene; Y, Y 1 and Y 2 each represent an acid-decomposable linkage; k1, k2, l1, l2, m1, m2, and m3 each represent 0 or 1; and R 1 represents H or a methyl group.

  提供一种抗蚀聚合物，其由一个具有结构式（1）或（2）所表示的酸分解单元作为结构单元，能够在DUV准分子激光微影或类似工艺中表现出小的线边粗糙度并产生少量缺陷。在式（1）和（2）中，n表示2至24的整数；J表示单键或二价碳氢基团，当n=2时可以具有取代基/杂原子，或者当n≥3时可以表示n价碳氢基团，可以具有取代基/杂原子；E表示聚合终止剂、链转移剂或聚合引发剂的残基；K1和K2分别表示至少选择自烷基、环烷基、氧烷基、芳烃、二价噻唑环、二价噁唑环和二价咪唑环中的至少一种；L1和L2分别表示至少选择自—C（O）O—、—C（O）—和—OC（O）—中的至少一种；M1、M2和M3分别表示至少选择自烷基、环烷基、氧烷基和芳烃中的至少一种；Y、Y1和Y2分别表示酸分解键；k1、k2、l1、l2、m1、m2和m3分别表示0或1；R1表示H或甲基基团。
• METHOD FOR PRODUCING FLUORINE-CONTAINING ACRYLATE
  申请人：Tosoh F-Tech, Inc.

  公开号：EP1637514A1

  公开（公告）日：2006-03-22

  A process for producing a fluorine-containing acrylic acid ester represented by CH2=C(Rf) (COOR) characterized in that 1-bromo-1-perfluoroalkylethene represented by CH2=CBr-Rf, or 1,2-dibromo-1-perfluoroalkylethane represented by CH2CBr-CHBr-Rf is allowed to react with an alcohol represented by ROH in the presence of a palladium catalyst, carbon monoxide, and two or more kinds of bases. The fluorine-containing acrylic acid ester is a useful compound having wide applications in materials for pharmaceuticals and functional polymers.

  一种以 CH2=C(Rf) (COOR) 为代表的含氟丙烯酸酯的生产工艺，其特征在于以 CH2=CBr-Rf 为代表的 1-溴-1-全氟烷基乙烯或以 CH2CBr-CHBr-Rf 为代表的 1,2-二溴-1-全氟烷基乙烷在钯催化剂、一氧化碳和两种或两种以上碱的存在下与以 ROH 为代表的醇反应。这种含氟丙烯酸酯是一种有用的化合物，在药物材料和功能聚合物中有着广泛的应用。
• REINFORCING FIBERS AND PRODUCTION METHOD THEREFOR, AND MOLDED ARTICLE USING SAME
  申请人：Kuraray Co., Ltd.

  公开号：EP3805451A1

  公开（公告）日：2021-04-14

  Reinforcing fibers containing hydrophilic fibers and an adhesive component, wherein at least a part of the surfaces of the hydrophilic fibers have the adhesive component, the adhesive component contains a modified conjugated diene rubber having a hydrogen-bonding functional group in a part of the conjugated diene rubber, and the number of the hydrogen-bonding functional groups in the modified conjugated diene rubber is 2 to 150 per molecule on average; a method for producing the reinforcing fibers; and a molded article using the reinforcing fibers.

  含有亲水纤维和粘合剂成分的增强纤维，其中亲水纤维的至少一部分表面具有粘合剂成分，粘合剂成分含有改性共轭二烯橡胶，在共轭二烯橡胶的一部分中具有氢键官能团，改性共轭二烯橡胶中氢键官能团的数量平均为每分子 2 至 150 个；生产增强纤维的方法；以及使用增强纤维的模塑制品。
• REINFORCING FIBER, METHOD FOR MANUFACTURING SAME, AND MOLDED BODY USING SAME
  申请人：Kuraray Co., Ltd.

  公开号：EP3933101A1

  公开（公告）日：2022-01-05

  Provided are reinforcing fibers using an adhesive component not containing resorcinol and formaldehyde, which are excellent in adhesiveness to rubber and which can be efficiently produced while preventing contamination of production facilities, and a method for producing them, as well as a molded article using them. The reinforcing fibers have an adhesive component that contains a conjugated diene rubber and an oil, in at least a part of the surfaces thereof, wherein the vapor pressure at 20°C of the oil is 10 Pa or less.

  本发明提供了使用不含间苯二酚和甲醛的粘合剂成分的补强纤维，这种纤维与橡胶的粘合性极佳，可高效生产，同时可防止生产设备受到污染，还提供了生产这种纤维的方法以及使用这种纤维的成型品。这种增强纤维有一种粘合剂成分，至少在其表面的一部分含有共轭二烯橡胶和油，其中油在 20°C 时的蒸气压为 10 Pa 或更小。
• Solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery, and methods for manufacturing solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery
  申请人：FUJIFILM Corporation

  公开号：US10833351B2

  公开（公告）日：2020-11-10

  Provided are a solid electrolyte composition containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and a compound having an anionic polymerizable functional group, a solid electrolyte-containing sheet containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and an anionic polymer which bonds to the inorganic solid electrolyte, and an all-solid state secondary battery, and methods for manufacturing the solid electrolyte composition, the solid electrolyte-containing sheet, and the all-solid state secondary battery.

  本发明提供了一种固体电解质组合物，该组合物含有对属于元素周期表第 I 组或第 II 组的金属离子具有导电性的无机固体电解质和具有阴离子可聚合官能团的化合物、一种含固体电解质的薄片，其中含有对属于元素周期表第I或第II族的金属离子具有导电性的无机固体电解质和一种与无机固体电解质结合的阴离子聚合物，以及一种全固态二次电池，以及制造该固体电解质组合物、含固体电解质的薄片和全固态二次电池的方法。