1,1,2,3,3,4,4,5,5,6,6-Undecafluoro-1-octene | 811803-30-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,1,2,3,3,4,4,5,5,6,6-Undecafluoro-1-octene
• 英文别名: 1,1,2,3,3,4,4,5,5,6,6-undecafluorooct-1-ene
• CAS: 811803-30-2
• 化学式: C₈H₅F₁₁
• 分子量: 310.11
• InChiKey: QYAPQABXVPUWOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  11

文献信息

• POLYFLUOROALKYLPHOSPHONIC ACID ESTER AND PROCESS FOR PRODUCING THE SAME
  申请人：Murata Seiichiro

  公开号：US20120108849A1

  公开（公告）日：2012-05-03

  A polyfluoroalkylphosphonic acid ester represented by the general formula: C n F 2n+1 (CH 2 CF 2 ) a (CF 2 CF 2 ) b (CH 2 CH 2 ) c P(O)(OR) 2 (R is an alkyl group having 1 to 4 carbon atoms, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3) is produced by a process of reacting a polyfluoroalkyl iodide represented by the general formula: C n F 2n+1 (CH 2 CF 2 ) a (CF 2 CF 2 ) b (CH 2 CH 2 ) c I with a trialkyl phosphite represented by the general formula: P(OR) 3 or by a process of reacting a polyfluoro-1-alkene represented by the general formula: C n F 2n+1 (CH 2 CF 2 ) a (CF 2 CF 2 ) b CH═CH 2 with a dialkyl phosphite represented by the general formula: (RO) 2 P(O)H.

  通过将通用公式表示的多氟烷基磷酸酯与通用公式表示的三烷基磷酸酯反应，生产一种多氟烷基磷酸酯，该多氟烷基磷酸酯的通用公式为：CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2（R是具有1至4个碳原子的烷基基团，n是1至6的整数，a是1至4的整数，b是1至3的整数，c是1至3的整数）。或者通过将通用公式表示的多氟-1-烯与通用公式表示的二烷基磷酸酯反应，生产该多氟烷基磷酸酯。
• Processes for production and purification of hydrofluoroolefins
  申请人：Miller Newton Ralph

  公开号：US20060106263A1

  公开（公告）日：2006-05-18

  Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

  本文公开了通过脱氟制备氢氟烯的工艺。本文还公开了从氢氟碳和氟化氢中分离氢氟烯的工艺。
• PROCESSES FOR PRODUCTION AND PURIFICATION OF HYDROFLUOROOLEFINS
  申请人：MILLER RALPH NEWTON

  公开号：US20110118512A1

  公开（公告）日：2011-05-19

  Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

  本文揭示了通过脱氟制备氢氟烯的过程。同时，还揭示了从氢氟碳化物和氢氟酸中分离氢氟烯的过程。
• POLYFLUOROALKYLPHOSPHONIC ACID ESTERS AND PROCESSES FOR PRODUCTION OF SAME
  申请人：Unimatec Co., Ltd.

  公开号：EP2452945A1

  公开（公告）日：2012-05-16

  A polyfluoroalkylphosphonic acid ester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2 (R is an alkyl group having 1 to 4 carbon atoms, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3) is produced by a process of reacting a polyfluoroalkyl iodide represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI with a trialkyl phosphite represented by the general formula: P(OR)3 or by a process of reacting a polyfluoro-1-alkene represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)bCH=CH2 with a dialkyl phosphite represented by the general formula: (RO)2P(O)H.

  由通式表示的多氟烷基膦酸酯：CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2（R 是具有 1 至 4 个碳原子的烷基，n 是 1 至 6 的整数，a 是 1 至 4 的整数，b 是 1 至 3 的整数，c 是 1 至 3 的整数）是由通式为CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI与通式如下的三烷基亚磷酸酯反应制得：P(OR)3或通式如下的多氟-1-烯与通式如下的三烷基亚磷酸酯反应的过程CnF2n+1(CH2CF2)a(CF2CF2)bCH=CH2 与通式为(RO)2P(O)H.
• US7897823B2
  申请人：——

  公开号：US7897823B2

  公开（公告）日：2011-03-01