N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide | 39847-43-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide
• 英文别名: N,N-bis(perfluoro-n-butylsulfonyl)methylamine；N-methyl bis(nonafluorobutanesulfonyl)imide；1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl-N-(1,1,2,2,3,3,4,4,4-nonafluorobutylsulfonyl)butane-1-sulfonamide
• CAS: 39847-43-3
• 化学式: C₉H₃F₁₈NO₄S₂
• 分子量: 595.23
• InChiKey: ZLPQCYHCZUNXRT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  34
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  88.3
• 氢给体数：
  0
• 氢受体数：
  23

反应信息

• 作为反应物：
  描述：

  1-乙基咪唑 、 N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide 以 氯仿 为溶剂， 反应 5.0h， 以100%的产率得到1-ethyl-3-methylimidazolium bis(nonafluorobutane-1-sulfonyl)imide
  参考文献：
  名称：

  咪唑和吡啶衍生物的直接甲基化和三氟乙基化。

  摘要：

  使用N-甲基双（（全氟烷基）磺酰基）酰亚胺或三氟乙基苯基碘鎓双（（三氟甲基）磺酰基）酰亚胺对咪唑和吡啶衍生物进行直接甲基化或三氟乙基化，可得到高产率的相应盐。此方法提供了通往各种室温离子液体（RTIL）的简单途径。

  DOI：

  10.1039/b307230d
• 作为产物：
  描述：

  碳酸二甲酯 、 双(九氟-1-丁烷磺酰)亚胺钾盐 在 硫酸 作用下， 反应 24.0h， 以83%的产率得到N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide
  参考文献：
  名称：

  FLUORINE-CONTAINING N-ALKYLSULFONYLIMIDE COMPOUND, MANUFACTURING METHOD THEREFOR, AND METHOD OF MANUFACTURING AN IONIC COMPOUND

  摘要：

  根据制备含氟N-烷基磺酰亚胺化合物的方法，可以通过用二烷基硫酸或二烷基碳酸烷基化含氟磺酰亚胺酸或含氟磺酰亚胺酸盐来安全地高回收率地生产含氟N-烷基磺酰亚胺化合物。

  公开号：

  US20120022269A1

文献信息

• Design of Electrophoretic and Biocompatible Poly(2-oxazoline)s Initiated by Perfluoroalkanesulfoneimides and Electrophoretic Deposition with Bioactive Glass
  作者：Terunari Hayashi、Akinori Takasu

  DOI：10.1021/acs.biomac.5b00043

  日期：2015.4.13

  N-Methyl bis[(nonafluorobutane)sulfonyl]imide (Nf2NMe) was synthesized to serve as an initiator for polymerization of 2-oxazolines and the polymerization activity and control of molecular weight were compared with conventional methyl triflate (TfOMe). Ring-opening polymerization of the vinyl-containing 2-oxazoline, 2-(3-butenyl)-2-oxazoline, and a subsequent thiol–ene click reaction and oxidation resulted in the successful synthesis of electrophoretic poly(2-oxazoline)s containing pendent sulfone. It was possible to coat the polymeric sulfones obtained via oxone oxidation (conversion, >99%) on a stainless-steel anode selectively. Furthermore, hybridization of the poly(2-oxazoline)s with bioactive glass (Bioglass45S5) by electrophoretic deposition (EPD) was investigated, and the biocompatibility of the hybrid was also evaluated.

  合成了N-甲基双[(九氟丁烷)磺酰基]亚胺(Nf2NMe)作为2-恶唑啉聚合的引发剂，并与传统的三氟甲磺酸甲酯(TfOMe)进行了聚合活性和分子量控制的比较。含乙烯基的2-恶唑啉、2-(3-丁烯基)-2-恶唑啉的开环聚合，以及随后的硫醇-烯点击反应和氧化，成功合成了含有悬挂的砜。可以将通过过氧化氢氧化（转化率>99%）获得的聚合砜选择性地涂覆在不锈钢阳极上。此外，通过电泳沉积（EPD）研究了聚（2-恶唑啉）与生物活性玻璃（Bioglass45S5）的杂交，并评估了混合物的生物相容性。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.2, 1.3.3, page 120 - 137
  作者：

  DOI：——

  日期：——
• Messdoerffer, J. N.; Niederpruem, H., Chemiker-Zeitung, 1972, vol. 96, p. 582 - 583
  作者：Messdoerffer, J. N.、Niederpruem, H.

  DOI：——

  日期：——
• SYMMETRICAL OR ASYMMETRICAL ALKYLSULFONYL IMIDE OR CYCLIC ALKYLENE SULFONYLIMIDE SALTS AS CATHODE ADDITIVES, ELECTROLYTE ADDITIVES, OR SI ANODE ADDITIVES FOR SI ANODE-BASED LI-ION CELLS
  申请人：Enevate Corporation

  公开号：US20220131193A1

  公开（公告）日：2022-04-28

  Electrode or electrolyte additives for energy storage devices comprising symmetrical or asymmetrical alkylsulfonyl imide or cyclic alkylene sulfonylimide salts are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, and an electrolyte composition. Symmetrical or asymmetrical alkylsulfonyl imide or cyclic alkylene sulfonylimide salts may serve as additives to the electrodes or to the electrolyte composition, or both.
• FLUORINE-CONTAINING N-ALKYLSULFONYLIMIDE COMPOUND, MANUFACTURING METHOD THEREFOR, AND METHOD OF MANUFACTURING AN IONIC COMPOUND
  申请人：Honda Tsunetoshi

  公开号：US20120022269A1

  公开（公告）日：2012-01-26

  According to the method for producing fluorine-containing N-alkylsulfonylimide compound, the fluorine-containing N-alkylsulfonylimide compound can be produced safely with a high recovery rate by alkylating fluorine-containing sulfonylimide acid or fluorine-containing sulfonylimide acid salt with dialkylsulfuric acid or dialkylcarbonic acid.

  根据制备含氟N-烷基磺酰亚胺化合物的方法，可以通过用二烷基硫酸或二烷基碳酸烷基化含氟磺酰亚胺酸或含氟磺酰亚胺酸盐来安全地高回收率地生产含氟N-烷基磺酰亚胺化合物。