trans-3-(9-anthryl)-1-(4-methoxyphenyl)prop-2-en-1-one | 97580-11-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: trans-3-(9-anthryl)-1-(4-methoxyphenyl)prop-2-en-1-one
• 英文别名: (E)-3-(anthracen-10-yl)-1-(4-methoxyphenyl)prop-2-en-1-one；3-(9-Anthryl)-1-(4-methoxyphenyl)prop-2-en-1-one；(E)-3-anthracen-9-yl-1-(4-methoxyphenyl)prop-2-en-1-one
• CAS: 97580-11-5
• 化学式: C₂₄H₁₈O₂
• 分子量: 338.406
• InChiKey: DEGUZIIIXRXDKA-CCEZHUSRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trans-3-(9-anthryl)-1-(4-methoxyphenyl)prop-2-en-1-one 以 乙酸乙酯 为溶剂， 反应 3.0h， 以67%的产率得到2-(4-Methoxy-phenyl)-8H-1-oxa-dibenzo[e,h]azulene
  参考文献：
  名称：

  蒽发色团的光化学：1-（9-蒽基）-2-苯甲酰基乙烯的新型异构化

  摘要：

  光激发的顺式-1-（9-蒽基）2-苯甲酰基乙烯通过骨架重排经历新型异构化反应，从而生成呋喃基退火的5H-二苯并[a，d]环庚烯。

  DOI：

  10.1016/s0040-4039(00)98559-9
• 作为产物：
  描述：

  (Z)-3-(9-Anthryl)-1-(4-methoxyphenyl)prop-2-en-1-one 生成 trans-3-(9-anthryl)-1-(4-methoxyphenyl)prop-2-en-1-one
  参考文献：
  名称：

  BECKER, H. -D.;BECKER, H. -CH.;SANDROS, K.;ANDERSSON, K., TETRAHEDRON LETT., 1985, 26, N 12, 1589-1592

  摘要：

  DOI：

文献信息

• Unraveling relation between nonlinear absorption and structure of push pull ornamented anthracenyl chalcone derivatives
  作者：Amrita Saha、Asha Singh、Rama Chari、J. Jayabalan

  DOI：10.1016/j.molstruc.2020.128578

  日期：2020.11

  Using green chemical method a series of fifteen systematically substituted 3-(9-substituted anthracen-10-yl)-1-(4-phenyl substituted)prop-2-en-1-one derivatives having high nonlinear absorption coefficient have been synthesized. The nonlinear absorption properties of these compounds were studied using nanosecond pulses at 532 nm wavelength. All 15 derivatives are found to show high nonlinear absorption in the range of 35-640 cm/GW. Among these the derivatives with-NO2 as one of the substitution group show higher nonlinear absorption. The origin of high nonlinear absorption with low linear absorption in the compounds has been attributed to two-step two-photon absorption process. We have shown that the energy bands of these compounds are distributed such that for excitation at 532 nm they have strong nonlinear absorption. These properties of the reported compounds make them a potential candidate for biological imaging and other applications which are based on nonlinear absorption. (C) 2020 Elsevier B.V. All rights reserved.