1-(decyloxy)-4-methoxybenzene | 20743-98-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(decyloxy)-4-methoxybenzene
• 英文别名: 1-methoxy-4-decyloxybenzene；Hydrochinon-methyl-n-decyl-aether；Hydrochinon-methyl-n-decyl-ether；Hydrochinon-methyl-decyl-aether；p-Decyloxy-benzylalkohol；Decyl 4-methoxyphenyl ether；1-decoxy-4-methoxybenzene
• CAS: 20743-98-0
• 化学式: C₁₇H₂₈O₂
• 分子量: 264.408
• InChiKey: WJRIMKYSGLYNDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(decyloxy)-4-methoxybenzene 在 硝酸 作用下， 以 溶剂黄146 为溶剂， 生成 1-Methoxy-4-decyloxy-2-nitro-benzol
  参考文献：
  名称：

  Chain length effects in paraffins—III

  摘要：

  DOI：

  10.1016/s0040-4020(01)82172-4
• 作为产物：
  描述：

  癸基溴 、 4-甲氧基苯酚 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以77%的产率得到1-(decyloxy)-4-methoxybenzene
  参考文献：
  名称：

  膦酸酯化的pillar [5]芳烃：在水中构建pH响应型超分子聚合物的合成及应用

  摘要：

  设计并合成了一种膦酸酯化的功能化copillar [5]芳烃。进行了1 H NMR，13 C NMR，ESI-MS和HR-MS，以提供所获得的Copillar [5]芳烃结构的融合证据。由癸基部分与柱[5]芳烃腔之间的疏水相互作用和CH-··π相互作用驱动，由这种膦酸酯官能化的AB型单体在水中制备pH响应的线性超分子聚合物。进行了浓度依赖性的1 H NMR，NOESY，DOSY和比粘度测定，以研究超分子聚合过程。

  DOI：

  10.1016/j.tetlet.2018.06.058

文献信息

• Formation of a Cyclic Dimer Containing Two Mirror Image Monomers in the Solid State Controlled by van der Waals Forces
  作者：Zibin Zhang、Guocan Yu、Chengyou Han、Jiyong Liu、Xia Ding、Yihua Yu、Feihe Huang

  DOI：10.1021/ol2018938

  日期：2011.9.16

  Two new copillar[5]arenes were prepared. They are arranged in two completely different motifs, a cyclic dimer containing two monomers with two different conformations that are mirror images of each other and linear supramolecular polymers in the solid state. Not only has it been shown that to form this kind of dimer is a unique feature associated with pillar[5]arene macrocycles but also it was demonstrated

  准备了两个新的copillar [5]芳烃。它们以两个完全不同的基序排列，一个环状二聚体，其中包含具有两个不同构象的两个单体，这两个构象彼此互为镜像，并且为固态的线性超分子聚合物。不仅表明形成这种二聚体是与支柱[5]芳烃大环相关的独特特征，而且还证明了弱范德华力可用于控制单体在超分子过程中的自组织。聚合过程。
• Fluorescence Modulation via Isomer-Dependent Energy Transfer in an Azobenzene-Functionalized Poly(phenylenevinylene) Derivative
  作者：Elizabeth J. Harbron、Diego A. Vicente、Mirth T. Hoyt

  DOI：10.1021/jp045651m

  日期：2004.12.1

  Fluorescence studies of poly(2-methoxy-5-(4-(phenylazo)phenyl-4'-(1,10-dioxydecyl))-1,4-phenylenevinylene) (MPA-10-PPV), a PPV derivative with alkyl-tethered azobenzene side chains that was first synthesized by Yoshino and co-workers, are presented. The emission intensity of MPA-10-PPV in dilute solution is partially quenched by energy transfer from the PPV backbone to the azobenzene side chains, and the energy transfer is more efficient to the cis azobenzene isomer than to the trans. Because of this differential, the emission intensity can be reversibly modulated by controlling the isomeric form of the azobenzene side chain with light. The energy transfer process sensitizes the cis to trans azobenzene isomerization, and this additional isomerization pathway alters the composition of the azobenzene photostationary state in MPA-10-PPV.
• A phosphonated copillar[5]arene: Synthesis and application in the construction of pH-responsive supramolecular polymer in water
  作者：Zhihua Zhang、Li Shao、Jie Yang

  DOI：10.1016/j.tetlet.2018.06.058

  日期：2018.8

  A phosphonated-functionalized copillar[5]arene was designed and synthesized. 1H NMR, 13C NMR, ESI-MS and HR-MS were performed to provide converging evidences of the structure of obtained copillar[5]arene. Driven by hydrophobic interactions and C–H···π interactions between the decyl moiety and the pillar[5]arene cavity, a pH-responsive linear supramolecular polymer was fabricated from this phosphonate-functionalized

  设计并合成了一种膦酸酯化的功能化copillar [5]芳烃。进行了1 H NMR，13 C NMR，ESI-MS和HR-MS，以提供所获得的Copillar [5]芳烃结构的融合证据。由癸基部分与柱[5]芳烃腔之间的疏水相互作用和CH-··π相互作用驱动，由这种膦酸酯官能化的AB型单体在水中制备pH响应的线性超分子聚合物。进行了浓度依赖性的1 H NMR，NOESY，DOSY和比粘度测定，以研究超分子聚合过程。
• Chain length effects in paraffins—III
  作者：F. Korte、W. Klein、E.D. Schmid

  DOI：10.1016/s0040-4020(01)82172-4

  日期：1966.1