Butyric acid 1-tert-butylperoxy-ethyl ester | 88482-93-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Butyric acid 1-tert-butylperoxy-ethyl ester
• 英文别名: 1-(tert-Butylperoxy)ethyl butanoate；1-tert-butylperoxyethyl butanoate
• CAS: 88482-93-3
• 化学式: C₁₀H₂₀O₄
• 分子量: 204.266
• InChiKey: KGHWJKQFKRSREI-UHFFFAOYSA-N

物化性质

• 沸点：
  220.1±23.0 °C(Predicted)
• 密度：
  0.971±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(1-氯乙基过氧)-2-甲基丙烷 、 丁酸 在 三乙胺 作用下， 以 氯仿 为溶剂， 以95%的产率得到Butyric acid 1-tert-butylperoxy-ethyl ester
  参考文献：
  名称：

  Synthesis of α-hydroxyalkyl peroxide esters and ethers as initiators of radical processes

  摘要：

  alpha-Hydroxyalkyl peroxide esters and ethers containing, along with the peroxy bond, also acyloxy and alkoxy groups, are effective initiators of radical processes. The initiation efficiency is due to the capability of these molecules to generate simultaneously oxygen- and carbon-centered radicals capable of hydrogen abstraction from the substrate and of addition to > C=CaOE (c) bonds. The selectivity of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers is mainly determined by the steps of the synthesis and isolation of the intermediate alpha-chloroalkyl peroxides, because of their high reactivity. Experimental conditions allowing control of the synthesis of alpha-hydroxyalkyl peroxide esters and ethers were found.

  DOI：

  10.1134/s1070427214120167

文献信息

• Yellow toner
  申请人：ZEON CORPORATION

  公开号：US11126101B2

  公开（公告）日：2021-09-21

  A yellow toner which provides, even in small amounts, a sharper color and brighter gloss, and higher reflection density than ever before, and which has excellent light resistance. The yellow toner contains a binder resin and a yellow colorant, wherein, as the yellow colorant, at least one of the compound A represented by the following general formula (1) and the compound B represented by the following general formula (2), and the compound C represented by the following formula (3) are contained:

  一种黄色调色剂，即使用量很少，也能提供比以往更鲜明的色彩、更明亮的光泽和更高的反射密度，并且具有极佳的耐光性。这种黄色调色剂含有粘合剂树脂和黄色着色剂，其中，作为黄色着色剂，至少含有由以下通式（1）表示的化合物 A 和由以下通式（2）表示的化合物 B 以及由以下通式（3）表示的化合物 C 中的一种：
• TONER AND PROCESS OF PRODUCTION OF THE SAME
  申请人：Sensui Keita

  公开号：US20090130578A1

  公开（公告）日：2009-05-21

  [Problems] To provide a toner superior in shelf stability, not giving off an offensive odor and degrading the surrounding environment when used for printing, and superior in durability at the time of use for continuous printing under high temperature, high humidity conditions. [Means for Solving Problems] A process of production of a toner containing colored polymer particles obtained by polymerizing a polymerizable monomer composition containing a polymerizable monomer and colorant in an aqueous medium in the presence of a polymerization initiator, wherein the polymerization initiator is an organic peroxide having a molecular weight of 205 or less, and a purity of 90% or more.
• YELLOW TONER
  申请人：ZEON CORPORATION

  公开号：US20200348610A1

  公开（公告）日：2020-11-05

  A yellow toner which provides, even in small amounts, a sharper color and brighter gloss, and higher reflection density than ever before, and which has excellent light resistance. The yellow toner contains a binder resin and a yellow colorant, wherein, as the yellow colorant, at least one of the compound A represented by the following general formula (1) and the compound B represented by the following general formula (2), and the compound C represented by the following formula (3) are contained:
• US8173345B2
  申请人：——

  公开号：US8173345B2

  公开（公告）日：2012-05-08