diallyl 1,1-cyclohexanedicarboxylate | 108233-78-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diallyl 1,1-cyclohexanedicarboxylate
• 英文别名: Bis(prop-2-enyl) cyclohexane-1,1-dicarboxylate
• CAS: 108233-78-9
• 化学式: C₁₄H₂₀O₄
• 分子量: 252.31
• InChiKey: WGLXPTSIIWVEDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diallyl 1,1-cyclohexanedicarboxylate 以65%的产率得到
  参考文献：
  名称：

  TSUJI JIRO; YAMADA TOSHIRO; MINAMI ICHIRO; YUHARA MASAMI; NISAR MOHAMMAD;+, J. ORG. CHEM., 52,(1987) N 14, 2988-2995

  摘要：

  DOI：
• 作为产物：
  描述：

  二甲基环己烷-1,1-二羧酸酯 、 烯丙醇 在 sodium hydride 作用下， 反应 24.0h， 以75%的产率得到diallyl 1,1-cyclohexanedicarboxylate
  参考文献：
  名称：

  Palladium-catalyzed decarboxylation-allylation of allylic esters of .alpha.-substituted .beta.-keto carboxylic, malonic, cyanoacetic, and nitroacetic acids

  摘要：

  DOI：

  10.1021/jo00390a007

文献信息

• Isononyl benzoates and their use
  申请人：OXENO OLEFINCHEMIE GMBH

  公开号：US20040015007A1

  公开（公告）日：2004-01-22

  The invention relates to isomeric nonyl benzoates, processes for their preparation, mixtures of the same with alkyl phthalate, alkyl adipate, or alkyl cyclohexanedicarboxylate, and also to the use of these mixtures.

  该发明涉及同分异构的壬基苯甲酸酯，其制备方法，与烷基邻苯二甲酸酯、烷基己二酸酯或烷基环己二羧酸酯的混合物，以及这些混合物的用途。
• Method for hydrogenating organic compounds by means of ru/sio2 catalysts
  申请人：——

  公开号：US20040199033A1

  公开（公告）日：2004-10-07

  In a process for hydrogenating at least one organic compound, the organic compound or compounds is/are brought into contact with a hydrogen-containing gas in the presence of a catalyst which comprises, as active metal, ruthenium either alone or together with at least one further metal of transition group I, VII or VIII of the Periodic Table applied to a support material based on amorphons silicon dioxide and is obtainable by: i) a single or multiple treatment of a support material based on amorphous silicon dioxide with a halogen-free aqueous solution of a low molecular weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reduction of the solid obtained in i) by means of hydrogen at from 100 to 350° C., with step ii) being carried out directly after step i).

  在至少一种有机化合物氢化的过程中，有机化合物或化合物被带入含氢气体中，在催化剂的存在下，该催化剂包括作为活性金属的钌单独或与周期表的I，VII或VIII族过渡金属中的至少一种进一步金属一起应用于基于非晶态二氧化硅的支撑材料，并且可以通过以下方式获得：i）用不含卤素的低分子量钌化合物的水溶液对基于非晶态二氧化硅的支撑材料进行单次或多次处理，并在低于200°C的条件下干燥处理所处理的支撑材料，ii）通过在100°C至350°C的温度下用氢还原i）中得到的固体，其中步骤ii）直接在步骤i）之后进行。
• Foamable compositions which comprise isononyl benzoate
  申请人：Grass Michael

  公开号：US20050049341A1

  公开（公告）日：2005-03-03

  Compositions for producing foamed products which comprise a chlorinated polymer such as PVC and at least one isomeric nonyl benzoate as a plasticizer, the use of these compositions, and products produced therefrom including PVC-containing floorcoverings, synthetic leather, and wallcoverings.

  本发明涉及一种用于生产发泡产品的组合物，其中包括氯化聚合物，例如PVC和至少一种异构的壬基苯甲酸酯作为增塑剂，以及这些组合物的使用和由其生产的产品，包括含有PVC的地板覆盖物、合成皮革和墙面覆盖物。
• CYCLOHEXANE POLYCARBOXYLIC ACID DERIVATIVES AS PLASTICIZERS FOR ADHESIVES AND SEALANTS
  申请人：Mack Helmut

  公开号：US20110232825A1

  公开（公告）日：2011-09-29

  The invention provides an adhesive or sealant comprising at least (A) one compound selected from the group consisting of silylated polyurethanes, silylated polyureas, silylated polyethers, silylated polysulfides and silyl-terminated acrylates, and at least (B) one cyclohexane polycarboxylic acid derivative. The composition has enhanced extensibility with good adhesion properties and high tensile strength. A process is disclosed for preparing the adhesive or sealant, and also disclosed is the use thereof for producing material bonds between parts to be joined.

  本发明提供了一种粘合剂或密封剂，包括至少（A）从包括硅化聚氨酯、硅化聚氨基甲酸酯、硅化聚醚、硅化聚硫化物和硅基终止丙烯酸酯的群组中选择的一种化合物，以及至少（B）一种环己烷聚羧酸衍生物。该组合物具有良好的粘附性和高拉伸强度的增强延展性。还公开了制备粘合剂或密封剂的过程，并公开了将其用于在要连接的零件之间产生材料粘结的用途。
• TRANSPARENT COMPOSITE MATERIAL
  申请人：Toita Ryoji

  公开号：US20120022191A1

  公开（公告）日：2012-01-26

  This invention relates to a transparent composite material having a low coefficient of liner thermal expansion and excellent transparency and flexibility, which is formed by curing a resin composition containing urethane (meth)acrylate, in which 10 to 40% by mass of synthetic smectite that is organized with a quaternary ammonium salt and/or a quaternary phosphonium salt and has a number average particle diameter of from 10 to 300 nm and an aspect ratio of from 10 to 300 is dispersed; and a transparent composite sheet using the material.

  本发明涉及一种透明的复合材料，具有低线性热膨胀系数和优异的透明度和柔韧性，该材料由固化含有脲基（甲基）丙烯酸酯的树脂组合物形成，其中分散了10至40重量％的合成粘土，该合成粘土是由季铵盐和/或季膦盐组成的，并且具有平均粒径为10至300 nm和纵横比为10至300；以及使用该材料的透明复合板。