bis(2,4-di-tert-butylphenyl) fluorophosphite | 119735-70-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(2,4-di-tert-butylphenyl) fluorophosphite
• 英文别名: di(2,4-di-tert-butylphenyl) fluorophosphite；Bis(2,4-ditert-butylphenoxy)-fluorophosphane
• CAS: 119735-70-5
• 化学式: C₂₈H₄₂FO₂P
• 分子量: 460.612
• InChiKey: AHDAYPOGYUBTER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,4-二叔丁基苯酚 、 三氟化锑 在 anhydrous phosphorus trichloride 、 三乙胺 作用下， 以 四氢呋喃 、 正庚烷 、 乙腈 为溶剂， 生成 bis(2,4-di-tert-butylphenyl) fluorophosphite
  参考文献：
  名称：

  Alkenyl succinic anhydrides process

  摘要：

  具有较少焦油和色体的烯丙基琥珀酸酐可通过在芳基氟膦酸酯（例如2,2'-乙基亚甲基双（4,6-二叔丁基苯基）氟膦酸酯）和可选的受阻酚类抗氧化剂（例如2,4,6-三（3,5-二叔丁基-4-羟基苯基）甲苯）的存在下，将烯烃与马来酸酐反应而制得。

  公开号：

  US04958034A1

文献信息

• COMPOSITION WITH POLYMER AND AN OXIDATION-CATALYST
  申请人：Gijsman Pieter

  公开号：US20100048764A1

  公开（公告）日：2010-02-25

  The invention relates to a process for increasing the rate of oxo-biodegradation of a carbon-containing polymer which process at least comprises the step of adding a component containing at least one 1,2-oxo-hydroxy-moiety as an oxidation catalyst to the carbon-containing polymer. The invention further relates to a composition with an increased rate of oxo-biodegradability that is obtained by the process of the invention and to the product with increased rate of oxo-biodegradability made from the composition.

  本发明涉及一种增加含碳聚合物氧化降解速率的方法，该方法至少包括向含碳聚合物中添加至少含有一个1,2-氧代羟基基团的氧化催化剂组分的步骤。本发明还涉及通过该方法获得的具有增强的氧化降解性能的组合物以及由该组合物制成的具有增强的氧化降解性能的产品。
• Aqueous aryl fluorophosphite suspension
  申请人：ETHYL CORPORATION

  公开号：EP0301355A2

  公开（公告）日：1989-02-01

  Aryl fluorophosphites have been found to be effec­tive polymer stabilizers and are hydrolytically stable when used to form aqueous suspensions.

  芳基氟磷酸盐是一种有效的聚合物稳定剂，用于形成水性悬浮液时具有水解稳定性。
• Transhalogenation of halophosphorus compounds
  申请人：ETHYL CORPORATION

  公开号：EP0353598A2

  公开（公告）日：1990-02-07

  Phosphorus compounds having at least one chlorine, bromine or iodine bonded directly to phosphorus are trans­halogenated with fluorine by reaction with a hydrogen fluoride salt of a pyridine-type nitrogen base, e.g., pyridine hydrofluoride in an inert solvent.

  通过在惰性溶剂中与吡啶型氮基（如氟化氢吡啶）的氟化氢盐反应，使至少有一个氯、溴或碘直接与磷键合的磷化合物与氟发生反卤化反应。
• Polymer composition
  申请人：Tonen Chemical Corporation

  公开号：EP0382559A2

  公开（公告）日：1990-08-16

  A polymer composition comprising resin components comprising (a) 5-95 weight % of a polyamide resin, and (b) 5-95 weight % of a mixture of a polyolefin and an unsaturated carboxylic acid-modified polyolefin, and (c) additives comprising the following compounds in the following amounts per 100 parts by weight of the total composition: (1) 0.1-2 parts by weight of a substituted hydrazine; (2) 0.05-2 parts by weight of a sterically hindered phenol compound; (3) 0.05-0.5 parts by weight of a phosphite or phosphonite; and (4) 0.15-1 parts by weight of a thiodipropionate.

  一种聚合物组合物，其树脂成分包括：(a)5-95 重量％的聚酰胺树脂；(b)5-95 重量％的聚烯烃和不饱和羧酸改性聚烯烃混合物；以及(c)添加剂，添加剂包括下列化合物，其用量按组合物总量每 100 重量份计如下：(a) 5-95重量％的聚酰胺树脂；(b) 5-95重量％的聚烯烃和不饱和羧酸改性聚烯烃混合物；以及(c)添加剂： (1) 0.1-2 份（按重量计）取代肼； (2) 0.05-2 份（按重量计）立体受阻苯酚化合物 (3) 0.05-0.5 份（按重量计）亚磷酸酯或亚磷酸酯；以及 (4) 0.15-1 份（按重量计）硫代二丙酸酯。
• Chemical metal and oil treating composition and process
  申请人：Simon, Juanito A.

  公开号：EP0590574A1

  公开（公告）日：1994-04-06

  This invention is directed to a liquid metal and oil treating composition and to the process of preparing the composition. In the process there are first mixed together a vegetable oil such as cashew oil, anoleate ester such as magnesium oleate, and Ingredient A which is material selected from the group consisting of (a) ferric chloride, (b) at least one of pulverized lead oxide, ferric oxide, iron carbide, chromium carbide and tungsten carbide dispersed in an aqueous solution of acid selected from the group consisting of hydrochloric acid, perchloric acid and sulfuric acid. The acid solution is concentrated, preferably containing about 40 volume % acid. The mixture is heated and stirred and then distilled. The residue is then heated to about 100-150°F, while adding to it, with stirring, an antioxidant, a polar hydrocarbon, a carbonyl, a carboxyl amide, a viscosity improver, at least one of a tackifier and a sulfonate, and a petroleum oil until a homogeneous liquid is obtained.

  本发明涉及一种液态金属和油处理组合物以及制备该组合物的工艺。在该工艺中，首先将植物油（如腰果油）、油酸酯（如油酸镁）和配料 A 混合在一起，配料 A 是选自以下组别的材料：(a) 氯化铁；(b) 至少一种分散在选自盐酸、高氯酸和硫酸的酸水溶液中的粉碎氧化铅、氧化铁、碳化铁、碳化铬和碳化钨。酸溶液是浓缩的，最好含有约 40 体积百分比的酸。将混合物加热并搅拌，然后蒸馏。然后将残留物加热至约 100-150°F，同时在搅拌下加入抗氧化剂、极性烃、羰基、羧基酰胺、粘度改进剂、增粘剂和磺酸盐中的至少一种以及石油，直至得到均匀的液体。