Cycloundecan-carbonsaeurechlorid | 83224-26-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: Cycloundecan-carbonsaeurechlorid
• 英文别名: Cycloundecanecarbonyl chloride
• CAS: 83224-26-4
• 化学式: C₁₂H₂₁ClO
• 分子量: 216.751
• InChiKey: NWVXYXOOMAJNCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Cycloundecan-carbonsaeurechlorid 在 ammonium hydroxide 作用下， 生成 Cycloundecan-carbonsaeureamid
  参考文献：
  名称：

  Lorenz,P. et al., Chemische Berichte, 1971, vol. 104, p. 3429 - 3455

  摘要：

  DOI：
• 作为产物：
  描述：

  2-氯环十二酮 在 氢氧化钾 、 氯化亚砜 作用下， 以 乙醇 为溶剂， 生成 Cycloundecan-carbonsaeurechlorid
  参考文献：
  名称：

  Synthesis of some cycloundecane derivatives from 1,5,9-cyclododecatriene

  摘要：

  DOI：

  10.1007/bf00920268

文献信息

• Synthesis and properties of some N,N-dialkylamides as new extractants
  作者：Hikmat N. Al-Jallo、Anwar A. Hussain、Halfah B. Mansoor、Ausama A. Sameh、Sinan K. Al-Saidi

  DOI：10.1021/je00038a033

  日期：1984.10
• Rearrangement, hydride abstraction, and retro ene reactions of dicarbonyl(.eta.5-cyclopentadienyl)iron vinylidene triflates
  作者：Robert S. Bly、Muthukrishna Raja、Ruta K. Bly

  DOI：10.1021/om00039a031

  日期：1992.3

  Several (CO)2CpFe (i.e. Fp) eta(1)-polymethylenevinylidene triflates, (CH2)nC = C = Fp+TfO- (3a-e, n = 4-7, 10), were prepared at -78-degrees-C from the corresponding Fp cycloalkylacyls (CH2)nCHC(O)Fp (1a-e, n = 4-7, 10) and triflic anhydride. Solutions of 3c-e in CH2Cl2, when warmed to 25-degrees-C and reacted completely before being diluted with diethyl ether, are converted exclusively to Fp eta(2)-homocycloalkyne triflate, Fp-[eta(2)-(CH2)n(C = C)]}+TfO- (5c-e, n = 7, 8, 10). This rearrangement, the organometallic analogue of an ''end-to-end'' alkyl shift in a vinyl cation, has not been previously observed in transition-metal vinylidenes. In contrast to 3c-e, solutions of 3a,b (and also 3c at 0-degrees-C) in CH2Cl2, when warmed to 25-degrees-C and diluted with diethyl ether, react with the diluent to yield mixtures of Fp eta(2)-methylenecycloalkane triflates, Fp-[eta(2)-(CH2)nC = CH2]}+TfO- (9a-c, n = 4-6), and Fp polymethyleneethoxycarbene triflates. Fp-[eta(1)-C-(OEt)CH(CH2)n]}+TfO- (12a-c, n = 4-6). 9b formed from 1b and triflic anhydride in perdeuteriodiethyl ether contains approximately 1.6 atoms of deuterium per molecule, suggesting that, in the absence of a viable course of rearrangement or a better nucleophile, 3a-c produce 9a-c by abstracting a hydride from diethyl ether.
• Zakharkin,L.N.; Korneva,V.V., Journal of Organic Chemistry USSR (English Translation), 1965, vol. 1, # 9, p. 1629 - 1635
  作者：Zakharkin,L.N.、Korneva,V.V.

  DOI：——

  日期：——
• AL-JALLO, HIKMAT, N.;HUSSAIN, ANWAR, A.;MANSOOR, HALFAH, B.;SAMEH, AUSAMA+, J. CHEM. AND ENG. DATA, 1984, 29, N 4, 479-481
  作者：AL-JALLO, HIKMAT, N.、HUSSAIN, ANWAR, A.、MANSOOR, HALFAH, B.、SAMEH, AUSAMA+

  DOI：——

  日期：——
• US7678802B2
  申请人：——

  公开号：US7678802B2

  公开（公告）日：2010-03-16