14,14-dimethyl-pentadecanoic acid | 93815-57-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 14,14-dimethyl-pentadecanoic acid
• 英文别名: 14,14-Dimethyl-pentadecansaeure；14,14-Dimethylpen-tadecanoic acid；14,14-dimethylpentadecanoic acid
• CAS: 93815-57-7
• 化学式: C₁₇H₃₄O₂
• 分子量: 270.456
• InChiKey: RMSLIUYBDOGGFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  19
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  新戊酰基乙酸甲酯 在 氢氧化钾 、 potassium carbonate 、 一水合肼 、 2-戊酮 、 二乙二醇 作用下， 生成 14,14-dimethyl-pentadecanoic acid
  参考文献：
  名称：

  Arosenius et al., Arkiv foer Kemi, 1949, vol. 1, p. 413,417

  摘要：

  DOI：

文献信息

• Griseolic acid monoesters, their preparation and use
  申请人：SANKYO COMPANY LIMITED

  公开号：EP0319316A2

  公开（公告）日：1989-06-07

  Monoester griseolic acid derivatives of formula (I): (in which: R1 and R2 are the same or different and each represents a hydrogen atom, a hydroxy group or a protected hydroxy group; R3 and R4 each represents a hydrogen atom, or together represent an extra carbon-carbon bond between the two carbon atoms to which they are attached; one of RS and R6 represents a hydrogen atom and the other represents a carboxy-protecting group removable in the biochemical environment of the human eye); and pharmaceutically acceptable salts thereof have been found to have valuable properties in the treatment of ophthalmic disorders. They may be prepared by the selective esterification of the appropriate free acid.

  式(I)的单酯格栅羧酸衍生物： 其中R1和R2相同或不同，各自代表一个氢原子、一个羟基或一个受保护的羟基；R3和R4各自代表一个氢原子，或共同代表它们所连接的两个碳原子之间的一个额外的碳-碳键；RS和R6中的一个代表氢原子，另一个代表可在人眼的生化环境中去除的羧基保护基团）；以及它们的药学上可接受的盐类已被发现在治疗眼科疾病方面具有宝贵的特性。它们可以通过选择性酯化适当的游离酸来制备。
• REFRIGERATING MACHINE OIL COMPOSITIONS
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP1167495A1

  公开（公告）日：2002-01-02

  The invention provides a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing (a) a partial ester of a polyalcohol and a fatty acid and (b) an acid phosphate or its amine salt; and a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing any of (a) acid phosphates or their amine salts, (b) acetylene glycol alkylene oxide adducts, (c) potassium salts of fatty acids, etc., (d) organic acids, and (e) fatty acid amides. The refrigerator oil compositions have good lubricity and are especially effective for reducing the friction in both the oil region and the extreme-pressure region in the sliding area between aluminium materials and steel materials.

  本发明提供了一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 多元醇和脂肪酸的部分酯和 (b) 酸性磷酸盐或其胺盐；以及一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 酸性磷酸盐或其胺盐、(b) 乙二醇环氧烷加合物、(c) 脂肪酸钾盐等中的任何一种、(d) 有机酸，以及 (e) 脂肪酸酰胺。冷冻机油组合物具有良好的润滑性，尤其能有效减少铝材料和钢材料之间滑动区域的油区和极压区的摩擦。
• Refrigerating machine oil composition
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1681341A1

  公开（公告）日：2006-07-19

  The invention provides a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing (a) a partial ester of a polyalcohol and a fatty acid and (b) an acid phosphate or its amine salt; and a refrigerator oil composition comprising a base oil of a mineral oil and/or a synthetic oil, and containing any of (a) acid phosphates or their amine salts, (b) acetylene glycol alkylene oxide adducts, (c) potassium salts of fatty acids, etc., (d) organic acids, and (e) fatty acid amides. The refrigerator oil compositions have good lubricity and are especially effective for reducing the friction in both the oil region and the extreme-pressure region in the sliding area between aluminium materials and steel materials.

  本发明提供了一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 多元醇和脂肪酸的部分酯和 (b) 酸性磷酸盐或其胺盐；以及一种冷冻机油组合物，包括矿物油和/或合成油的基础油，并含有 (a) 酸性磷酸盐或其胺盐、(b) 乙二醇环氧烷加合物、(c) 脂肪酸钾盐等中的任何一种、(d) 有机酸，以及 (e) 脂肪酸酰胺。冷冻机油组合物具有良好的润滑性，尤其能有效减少铝材料和钢材料之间滑动区域的油区和极压区的摩擦。
• N-acryloylpiperazine derivatives, their preparation and their use as paf antagonists
  申请人：Sankyo Company Limited

  公开号：EP0395446B1

  公开（公告）日：1995-03-01
• FATTY ACIDS, SOAPS, SURFACTANT SYSTEMS, AND CONSUMER PRODUCTS BASED THEREON
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP1025190A2

  公开（公告）日：2000-08-09