trans-1,2,3,4-tetrachloro-2-butene | 65968-52-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: trans-1,2,3,4-tetrachloro-2-butene
• 英文别名: 2-Butene, 1,2,3,4-tetrachloro-；(E)-1,2,3,4-tetrachlorobut-2-ene
• CAS: 65968-52-7
• 化学式: C₄H₄Cl₄
• 分子量: 193.888
• InChiKey: LAAWIDUXQDGDCR-ONEGZZNKSA-N

物化性质

• 熔点：
  34 °C(Solv: ethanol (64-17-5))
• 沸点：
  85-87 °C(Press: 10 Torr)
• 密度：
  1.4999 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trans-1,2,3,4-tetrachloro-2-butene 在 臭氧 作用下， 以 正戊烷 为溶剂， 以16%的产率得到trans-3,5-Dichlor-3,5-bis(chlormethyl)-1,2,4-trioxolan
  参考文献：
  名称：

  cis-trans-Isomerization of an ozonide and a word of caution concerning stereochemical assignments of ozonides based on elution times

  摘要：

  DOI：

  10.1002/prac.199733901116
• 作为产物：
  描述：

  1,4-二氯-2-丁炔 在 偶氮二异丁腈 、 dichloriodbenzene 作用下， 以 氯仿 为溶剂， 反应 1.0h， 以41%的产率得到trans-1,2,3,4-tetrachloro-2-butene
  参考文献：
  名称：

  Griesbaum, Karl; Schlindwein, Konrad; Hilss, Michael, Chemische Berichte, 1993, vol. 126, # 8, p. 1843 - 1848

  摘要：

  DOI：

文献信息

• Nitrogen heterocycle biaryls for osteoporosis and other diseases
  申请人：Letourneau John Jeffrey

  公开号：US20050222203A1

  公开（公告）日：2005-10-06

  Nitrogen heterocycle biaryls having a carboxylate terminus are useful for treating endometriosis, osteoporosis, restenosis following angioplasty, rheumatoid arthritis, cancer, macular degeneration and obesity. Compounds of formula: are disclosed. A representative example is

  氮杂环联苯具有羧酸末端，可用于治疗子宫内膜异位症、骨质疏松症、血管成形术后再狭窄、类风湿关节炎、癌症、黄斑变性和肥胖症。 公开了以下化合物的结构： 代表性示例是
• METHOD FOR IMPROVING THE PRODUCTION OF A CHLORINATED ALKANE BY CHLORINATION OF A CHLOROALKENE USING A DILUENT
  申请人：BLUE CUBE IP LLC

  公开号：US20190300459A1

  公开（公告）日：2019-10-03

  The present invention provides improved processes for the production of a chlorinated alkane by chlorination of a chloroalkene in the presence of a diluent.

  本发明提供了一种在稀释剂存在下通过氯化氯烯烃的氯化反应来生产氯化烷的改进工艺。
• Unsaturated, halogenated thiocyanates, the preparation thereof and use as a biocide
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0316058A1

  公开（公告）日：1989-05-17

  A halogenated ethylene compound of the formula: X CR₁R₂C(Y₁) = C(Y₂)CR₁R₂ SCN where R₁ and R₂ are hydrogen, optionally substituted alkyl or together form a cyclohexyl group; X is bromine, chlorine or iodine and Y₁ and Y₂ are chlorine, bromine or iodine. A compound of this type is 2,3-dibromo-1-chloro-4-thiocyanato-2-butene. The compound has good anti-fungal and anti-bacterial properties. The compound can be used as an industrial biocide.

  式中的卤代乙烯化合物： x cr₁r₂c(y₁) = c(y₂)cr₁r₂ scn 其中 R₁ 和 R₂ 是氢、任选取代的烷基或共同形成环己基；X 是溴、氯或碘，Y₁ 和 Y₂ 是氯、溴或碘。这种化合物是 2,3-二溴-1-氯-4-硫氰基-2-丁烯。这种化合物具有良好的抗真菌和抗细菌特性。该化合物可用作工业杀菌剂。
• Flow reactors for chemical conversions with heterogeneous catalysts
  申请人：BP Corporation North America Inc.

  公开号：EP2314372A1

  公开（公告）日：2011-04-27

  A flow reactor comprising: (i) a plurality of walled conduits each having an outer surface disposed for contact with a heat-transfer medium, (ii) an inlet distribution manifold adapted for flow communication with a downstream manifold through channels formed by heterogeneous catalytic material disposed within each conduit during operation, (iii) a sequence of zones comprising at least two zones, said zones comprising said walled conduits, wherein (a) the walled conduits within each zone have the same or different length measured along the longitudinal coordinate of the zone, (b) the walled conduits within each zone have essentially uniform cross-section measured in a plane perpendicular to the longitudinal coordinate thereby defining volume of the zone, and (c) in the sequence of zones, the total cross-sectional area of the conduits in each downstream zone varies from the prior upstream zone, (iv) at least one crossover chamber in flow communication with the plurality of walled conduits of a downstream zone and the plurality of walled conduits of the prior upstream zone, (v) a shell adapted to maintain during operation the outer surface the plurality of walled conduits of each zone predominantly in contact with a heat-transfer medium, and (vi) the shell having an inlet in flow communication with an outlet for flow of the heat-transfer medium.

  流动反应器，包括 (i) 多个带壁导管，每个导管都有一个用于与传热介质接触的外表面、 (ii) 一个入口分配歧管，适于在运行期间通过由布置在每个导管内的异质催化材料形成的通道与下游歧管进行流动交流、 (iii) 由至少两个区组成的区序列，所述区包括所述带壁导管，其中 (a) 每个区域内的带壁导管沿区域纵坐标测量的长度相同或不同、 (b) 每个分区内的有壁导管在垂直于纵坐标的平面内具有基本一致的横截面，从而确定分区的体积，以及 (c) 在区段序列中，每个下游区段的导管总横截面积都不同于先前的上游区段、 (iv) 至少一个交叉室，与下游区的多个带壁导管和上游区的多个带壁导管相通、 (v) 壳体，用于在运行期间保持每个区的多个带壁导管的外表面主要与传热介质接触，以及 (vi) 壳体有一个与传热介质流出口相通的入口。
• Lavrent'eva, O. V.; Levanova, S. V.; Yakimova, N. A., Journal of applied chemistry of the USSR, 1991, vol. 64, # 8.2, p. 1563 - 1567
  作者：Lavrent'eva, O. V.、Levanova, S. V.、Yakimova, N. A.、Bolonina, E. V.

  DOI：——

  日期：——