6-mercaptohexyl hexanoate | 1350443-23-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 6-mercaptohexyl hexanoate
• 英文别名: 6-Sulfanylhexyl hexanoate；6-sulfanylhexyl hexanoate
• CAS: 1350443-23-0
• 化学式: C₁₂H₂₄O₂S
• 分子量: 232.387
• InChiKey: BSJKYWNCQKVZQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  27.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  6-巯基己-1-醇 、 己酸 在 2C₃₃H₃₇N*H₂O₇S₂ 作用下， 以 水 为溶剂， 反应 8.0h， 以86%的产率得到6-mercaptohexyl hexanoate
  参考文献：
  名称：

  Hydrophobic N,N-Diarylammonium Pyrosulfates as Dehydrative Condensation Catalysts under Aqueous Conditions

  摘要：

  Oil-soluble N,N-diarylammonium pyrosulfates as nonsurfactant-type catalysts for the dehydrative ester condensation under aqueous conditions are described. Preheat treatment of dibasic sulfuric acid with bulky N,N-diarylamines generates water-tolerant salts of pyrosulfuric acid as active catalyst species. The present catalysts in water can also widely be applied to unusual selective esterifications and dehydrative glycosylation.

  DOI：

  10.1021/ol2027366

文献信息

• [EN] USE OF AROMA GLYCOSIDES AS FLAVOR OR FRAGRANCE INGREDIENT<br/>[FR] UTILISATION DE GLYCOSIDES D'AROME EN TANT QU'INGREDIENT DE GOUT OU DE PARFUM
  申请人：POALIS AS

  公开号：WO2006087370A1

  公开（公告）日：2006-08-24

  [EN] Use of aroma glycosides as flavor or fragrance ingredients in food, feed, cleaning liquid or a washing powder products.
  [FR] Cette invention concerne l'utilisation de glycosides d'arôme en tant qu'ingrédients de goût ou de parfum pour de la nourriture humaine ou animale, des liquides de nettoyage ou des lessives en poudre.
• Hydrophobic <i>N,N-</i>Diarylammonium Pyrosulfates as Dehydrative Condensation Catalysts under Aqueous Conditions
  作者：Akira Sakakura、Yoshiki Koshikari、Matsujiro Akakura、Kazuaki Ishihara

  DOI：10.1021/ol2027366

  日期：2012.1.6

  Oil-soluble N,N-diarylammonium pyrosulfates as nonsurfactant-type catalysts for the dehydrative ester condensation under aqueous conditions are described. Preheat treatment of dibasic sulfuric acid with bulky N,N-diarylamines generates water-tolerant salts of pyrosulfuric acid as active catalyst species. The present catalysts in water can also widely be applied to unusual selective esterifications and dehydrative glycosylation.