2,2'-(4,4'-(9H-fluorene-9,9-diyl)bis(2-allyl-4,1-phenylene))bis(oxy)bis(methylene)dioxirane | 1191457-71-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2,2'-(4,4'-(9H-fluorene-9,9-diyl)bis(2-allyl-4,1-phenylene))bis(oxy)bis(methylene)dioxirane
• 英文别名: 2-[[4-[9-[4-(Oxiran-2-ylmethoxy)-3-prop-2-enylphenyl]fluoren-9-yl]-2-prop-2-enylphenoxy]methyl]oxirane
• CAS: 1191457-71-2
• 化学式: C₃₇H₃₄O₄
• 分子量: 542.675
• InChiKey: BURRJNSZBKIZOS-UHFFFAOYSA-N

物化性质

• 沸点：
  635.6±55.0 °C(Predicted)
• 密度：
  1.199±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  41
• 可旋转键数：
  12
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2'-(4,4'-(9H-fluorene-9,9-diyl)bis(2-allyl-4,1-phenylene))bis(oxy)bis(methylene)dioxirane 在 platinum(IV) oxide 、 四乙基溴化铵 、 间氯过氧苯甲酸 、 sodium hydroxide 作用下， 以 四氢呋喃 、 二氯甲烷 、 甲苯 、 乙腈 为溶剂， 反应 30.0h， 生成
  参考文献：
  名称：

  EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD FOR PREPARING SAME, COMPOSITION COMPRISING SAME, CURED PRODUCT MADE THEREFROM, AND USE THEREOF

  摘要：

  公开号：

  EP2933257B1
• 作为产物：
  描述：

  双酚芴 在 potassium carbonate 、 sodium hydroxide 作用下， 以 水 、 邻二氯苯 、 异丙醇 、 丙酮 为溶剂， 反应 11.0h， 生成 2,2'-(4,4'-(9H-fluorene-9,9-diyl)bis(2-allyl-4,1-phenylene))bis(oxy)bis(methylene)dioxirane
  参考文献：
  名称：

  티올-엔 반응을 이용한 에폭시 화합물 및 그 제조방법, 및 그 경화 생성물을 포함하는 유기-무기재료 복합체 및 그 복합체 제조방법

  摘要：

  本发明涉及具有알科西基烷基-S-烷基基团的环氧化合物及其制备方法，以及包含硬化生成物的有机-无机材料复合物及其制备方法，更详细地说，涉及用于制造下一代半导体基板和PCB等高集成度和高性能电子元件时表现出改进的耐热性和热膨胀特性，并能提供出色硬化度的新型环氧化合物及其制备方法，以及包含硬化生成物的有机-无机材料复合物及其制备方法。

  公开号：

  KR20170070354A

文献信息

• EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING THE SAME, COMPOSITION AND CURED PRODUCT COMPRISING THE SAME, AND USES THEREOF
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20140179836A1

  公开（公告）日：2014-06-26

  Disclosed are an epoxy compound having an alkoxysilyl group, a composite of which exhibits good heat resistant properties and/or a cured product of which exhibits good flame retardant properties, a method of preparing the same, a composition comprising the same, and a cured product and a use of the composition. An alkoxysilylated epoxy compound comprising at least one of Chemical Formula S1 substituent and at least two epoxy groups in a core, a method of preparing the epoxy compound by an allylation, a claisen rearrangement, an epoxidation and an alkoxysilylation, an epoxy composition comprising the epoxy compound, and a cured product and a use of the composition are provided. The composite of the disclosed exhibits improved chemical bonding, good heat resistant properties, a low CTE, a high glass transition temperature or Tg-less The cured product of the composition exhibits good flame retardant properties.

  揭示了一种具有烷氧基硅基团的环氧化合物，其复合材料具有良好的耐热性能和/或其固化产物具有良好的阻燃性能，以及其制备方法，包括该化合物的组合物，固化产物和组合物的用途。所述的烷氧基硅化环氧化合物包括至少一种化学式S1取代基和至少两个环氧基团在核心中，通过烯丙基化、克莱森重排、环氧化和烷氧基硅化制备环氧化合物的方法，包括该环氧化合物的环氧组合物，固化产物和组合物的用途。所述的复合材料具有改善的化学键合、良好的耐热性能、低CTE、高玻璃转变温度或Tg-less。该组合物的固化产物具有良好的阻燃性能。
• COMPOSITION AND CURED ARTICLE COMPRISING INORGANIC PARTICLES AND EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, USE FOR SAME, AND PRODUCTION METHOD FOR EPOXY COMPOUND HAVING ALKOXYSILYL GROUP
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20150148452A1

  公开（公告）日：2015-05-28

  There is provided a composition including an alkoxysilylated epoxy compound, a composition of which exhibits good heat resistance properties, low CTE and high glass transition temperature or Tg-less and not requiring a separate coupling agent, and inorganic particles, a cured product formed of the composition, and a use of the cured product. An epoxy composition including an alkoxysilylated epoxy compound and inorganic particles, an epoxy composition including an epoxy compound, inorganic particles and a curing agent, a cured product of the composition, and a use of the composition are provided. Since chemical bonds may be formed between the alkoxysilyl group and the inorganic particles and between the alkoxysilyl groups, a composition of the composition including the alkoxysilylated epoxy compound and the inorganic particles exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg less.

  提供一种包括烷氧硅基化环氧化合物的组合物，该组合物的性质具有良好的耐热性能，低CTE和高玻璃转变温度或Tg-无需单独的偶联剂，并且包括无机颗粒，所述组合物形成的固化产物，以及所述固化产物的用途。提供一种包括烷氧硅基化环氧化合物和无机颗粒的环氧组合物，一种包括环氧化合物、无机颗粒和固化剂的环氧组合物，所述组合物的固化产物，以及所述组合物的用途。由于烷氧硅基团与无机颗粒之间以及烷氧硅基团之间可能形成化学键，因此包括烷氧硅基化环氧化合物和无机颗粒的组合物具有改善的耐热性能、降低的CTE和增加的玻璃转变温度或Tg less。
• EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD FOR PREPARING THE SAME, COMPOSITION INCLUDING THE SAME, CURED PRODUCT MADE FROM THE COMPOSITION, AND USE OF THE COMPOSITION
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US20150247033A1

  公开（公告）日：2015-09-03

  Provided are an alkoxysilylated epoxy compound, a composite of which exhibits good heat resistance properties, particularly low CTE and increased glass transition temperature, and a cured product thereof exhibits good flame retardancy and composition of which does not require additional silane coupling agent, a method for preparing the same and a composition and a cured product including the same. An alkoxysilylated epoxy compound including at least one alkoxysilyl group and at least two epoxy groups, a method for preparing the same by epoxide ring-opening reaction of starting material and alkoxysilylation, an epoxy composition including the epoxy compound, and a cured product and a use of the composition are provided. Since chemical bonds may be formed between alkoxysilyl group and filler and between alkoxysilyl groups, chemical bonding efficiency of the composite may be improved. Thus, the composite exhibits good heat resistance properties and the cured product exhibits good flame retardancy.

  提供一种含有烷氧基硅烷基化环氧化合物，其复合材料具有良好的耐热性能，特别是低CTE和增加的玻璃转变温度，其固化产物具有良好的阻燃性能，其组成物不需要额外的硅烷偶联剂，提供了一种制备该化合物的方法，以及包括该化合物的组合物和固化产物。提供了一种含有至少一个烷氧基硅烷基团和至少两个环氧基团的烷氧基硅烷基化环氧化合物，通过起始材料的环氧基开环反应和烷氧基硅烷基化的方法来制备该化合物，一种包括该环氧化合物的环氧树脂组合物，以及固化产物和使用该组合物的用途。由于烷氧基硅烷基团与填料之间以及烷氧基硅烷基团之间可能形成化学键，复合材料的化学键合效率可能得到提高。因此，该复合材料具有良好的耐热性能，固化产物具有良好的阻燃性能。
• NOVEL FLUORENE COMPOUND AND PROCESS FOR PREPARING THE SAME
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20140066636A1

  公开（公告）日：2014-03-06

  The present invention relates to an epoxy group-containing novel fluorene compound having a methallyl group at the end thereof represented by the following general formula (1): wherein R represents a hydrogen atom or a methyl group, which compound gives a compound excellent in regioselectivity at the time of hydrosilylation with a Si—H containing organosilicon compound, with a less formed amount of an internally added β adduct, as compared with the conventionally known fluorene compound having an allyl group, so that heat resistance of the resulting organosilicon compound is expected to be improved whereby it is a useful compound.

  本发明涉及一种含有环氧基的新型芴化合物，其末端具有甲烯丙基基团，表示为以下通式（1）：其中R表示氢原子或甲基基团。该化合物在与含有Si-H的有机硅化合物进行氢硅烷基化反应时，表现出优异的区域选择性，与传统的具有烯丙基基团的芴化合物相比，内部加成的β加合物生成量较少，因此预计可以提高所得有机硅化合物的热稳定性，是一种有用的化合物。
• Photocurable dry film, method for preparing same, patterning method and film for protecting electric and electronic parts
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2364847A1

  公开（公告）日：2011-09-14

  Disclosed herein is a photocurable dry film including a structure having a photocurable resin layer sandwiched between a support film and a protective film, the photocurable resin layer being formed of a photocurable resin composition including ingredients (A) to (D): (A) a silicone skeleton-containing polymer compound having the repeating units represented by the following general formula (1) wherein X and Y, respectively, a divalent organic group represented by the following general formula (2) or (3) wherein wherein (B) a crosslinking agent selected from formalin-modified or formalin-alcohol-modified amino condensates and phenolic compound having on average two or more methylol groups or alkoxymethylol groups in one molecule; (C) a photoacid generator capable of generating an acid by decomposition with light having a wavelength of 190 to 500 nm; and (D) a solvent.

  本文公开了一种光固化干膜，其结构包括夹在支撑膜和保护膜之间的光固化树脂层，光固化树脂层由包括成分(A)至(D)的光固化树脂组合物形成： (A) 含有机硅骨架的聚合物化合物，其重复单元由以下通式（1）表示 其中 X 和 Y 分别是由以下通式（2）或（3）表示的二价有机基团 其中 其中 (B) 选自福尔马林改性或福尔马林-酒精改性的氨基缩合物和酚类化合物的交联剂，它们在一个分子中平均具有两个或两个以上的甲醇基团或烷氧基甲醇基团； (C) 光酸发生器，能够通过波长为 190 至 500 纳米的光分解生成酸；以及 (D) 溶剂。