triethylene glycol di-isobutyrate | 133176-35-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: triethylene glycol di-isobutyrate
• 英文别名: 1,2-bis-(2-isobutyryloxy-ethoxy)-ethane；1,2-Bis-(2-isobutyryloxy-aethoxy)-aethan；Triethyleneglycol diisobutyrate；2-[2-[2-(2-methylpropanoyloxy)ethoxy]ethoxy]ethyl 2-methylpropanoate
• CAS: 133176-35-9
• 化学式: C₁₄H₂₆O₆
• 分子量: 290.357
• InChiKey: BWHUFOFOQUQKGR-UHFFFAOYSA-N

物化性质

• 沸点：
  349.5±22.0 °C(Predicted)
• 密度：
  1.036±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  20
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  三乙二醇二甲基丙烯酸酯 在 palladium on activated charcoal 氢气 作用下， 以 乙酸乙酯 为溶剂， 生成 triethylene glycol di-isobutyrate
  参考文献：
  名称：

  Propagation and Termination Kinetics of Cross-Linking Photopolymerizations Studied Using Electron Paramagnetic Resonance Spectroscopy in Conjunction with Near IR Spectroscopy

  摘要：

  The use of electron paramagnetic resonance (EPR) in conjunction with Fourier transform near infrared (FT-NIR) spectroscopy to address the complexities associated with the accurate measurement and evaluation of cross-linking polymerization kinetics over the entire conversion range is explored. Experimental protocols are developed providing a more complete picture of the mechanistic and kinetic underpinnings of these radical polymerizations, accessing information that is otherwise unavailable to these techniques individually. The kinetics of two multimethaerylate polymerization systems, one forming a rubbery and the other a glassy polymer network, are compared and contrasted revealing numerous differences in their attributes as characterized by this experimental combination. Steady-state and unsteady-state radical concentration profiles, propagating radical environments during polymerization, and persistent radical populations are explored and utilized to evaluate the underlying propagation and termination kinetics. Subsequently, kinetic parameters obtained with EPR and EPR/FT-NIR are compared with those obtained independently from FT-NIR, enabling evaluation of the assumptions that underlie each technique.

  DOI：

  10.1021/ma0506482

文献信息

• 一种三甘醇二羧酸酯的制备方法
  申请人：中国石油化工股份有限公司

  公开号：CN104045555B

  公开（公告）日：2016-02-24

  本发明公开了一种结构式为（Ⅰ）的三甘醇二羧酸酯的制备方法，该方法包括在含无水碳酸钾的催化剂存在下，将结构式为（Ⅱ）的三甘醇与羧酸酯RCOOR1和R’COOR1进行反应，生成包括结构式为（Ⅰ）的三甘醇二羧酸酯和相应的醇HOR1的产物；其中，R和R’相同或不同，各自独立选自直链的C2-C17烷基、支链的C3-C17烷基和C4-C8环烷基中的一种；R1选自C1-C5烷基中的一种。本发明方法利于环境保护；产物收率高，纯度好。
• POLYVINYL ACETAL COMPOSITION, LAMINATE, AND USE THEREOF
  申请人：Asanuma Yoshiaki

  公开号：US20120202070A1

  公开（公告）日：2012-08-09

  It is an object of the invention to provide a plasticized polyvinyl acetal composition that is suitably used for an intermediate film of a laminated glass and other applications, specifically, the polyvinyl acetal composition being characterized in that in cases when a layer that is composed of the polyvinyl acetal composition and another resin layer such as a resin layer of a polycarbonate, a poly(meth)acrylic acid ester, or a styrene thermoplastic elastomer are laminated, the plasticizer does not migrate from the polyvinyl acetal layer. The present invention relates to a polyvinyl acetal composition including 100 parts by mass of a polyvinyl acetal and 0.5 to 100 parts by mass of an ester plasticizer or ether plasticizer that is amorphous or has a melting point of 30° C. or less, and has a hydroxyl value of 15 to 450 mgKOH/g.

  本发明的目的是提供一种塑化的聚乙烯醇醛组合物，适用于夹层玻璃和其他应用的中间膜，具体而言，该聚乙烯醇醛组合物的特点在于，在由聚乙烯醇醛组合物和另一种树脂层（如聚碳酸酯、聚（甲基）丙烯酸酯或苯乙烯热塑性弹性体层的树脂层）组成的层层压合时，塑化剂不会从聚乙烯醇醛层中迁移。本发明涉及一种聚乙烯醇醛组合物，包括100份质量份的聚乙烯醇醛和0.5至100份质量份的酯类塑化剂或醚类塑化剂，其为非晶态或具有30°C或更低的熔点，并具有15至450mgKOH/g的羟值。
• POLYVINYL ACETAL FILM WITH OUTSTANDING TRANSPARENCY AND RESISTANCE TO HEAT-CRACKING PHENOMENON
  申请人：Kuraray Co., Ltd.

  公开号：EP3029090A1

  公开（公告）日：2016-06-08

  An object is to provide a polyvinyl acetal film which has excellent transparency and can suppress a thermal cracking phenomenon. The above object is achieved by providing a polyvinyl acetal film in which a ratio between a composite modulus (GPa) of the highest part in a convex part and a composite modulus (GPa) of the lowest part in a concave part on a surface of a film on a side in contact with glass, calculated by a nanoindentation measurement using a scanning probe microscope, is 0.90 or less, when a laminated glass is formed. In addition, the above object is achieved by providing a polyvinyl acetal film in which a ratio between a hardness (GPa) of the highest part in the convex part and a hardness (GPa) of the lowest part in the concave part, calculated by the SPM nanoindentation measurement, is 0.90 or less.

  目的是提供一种聚乙烯醇缩醛薄膜，它具有优异的透明度，并能抑制热裂纹现象。 实现上述目的的方法是提供一种聚乙烯醇缩醛薄膜，当形成层压玻璃时，通过使用扫描探针显微镜进行纳米压痕测量，计算出薄膜与玻璃接触一侧表面上凸部最高部分的复合模量（GPa）与凹部最低部分的复合模量（GPa）之比为 0.90 或以下。此外，通过提供一种聚乙烯醇缩醛薄膜，其中通过 SPM 纳米压痕测量法计算出的凸面部分最高部分的硬度（GPa）与凹面部分最低部分的硬度（GPa）之比为 0.90 或更小，从而达到上述目的。
• INTERMEDIATE FILM FOR LAMINATED GLASS
  申请人：Kuraray Co., Ltd.

  公开号：EP3438065A1

  公开（公告）日：2019-02-06

  Provided is an interlayer film for laminated glass which is excellent in sound insulation property and has improved sound insulation performance not only in a coincidence region but also in a mass-dominated region. The interlayer film for laminated glass includes a sound insulating layer which is formed from a composition (A) containing at least one resin (a1) selected from a thermoplastic resin and a thermosetting resin, wherein a tanδ obtained when a dynamic viscoelasticity of a sheet, which is obtained by molding the composition (A) to have a thickness of 0.8 mm, is measured at a frequency of 0.3 Hz in a tension mode has a maximal value at a temperature TA (°C), TA (°C) is in a range of -50 to 50°C, and the tanδ at TA (°C) is 2.5 or more.

  本发明提供了一种用于夹层玻璃的中间膜，它具有优异的隔音性能，不仅在重合区域，而且在质量主导区域的隔音性能都得到了改善。 该夹层玻璃用中间膜包括隔音层，该隔音层由含有至少一种选自热塑性树脂和热固性树脂的树脂（a1）的组合物（A）形成，其中通过模塑组合物（A）获得厚度为 0.8 mm，在拉伸模式下以 0.3 Hz 的频率测量，在温度 TA (℃)时具有最大值，TA (℃)的范围为 -50 至 50℃，TA (℃)时的 tanδ 为 2.5 或更大。
• RESIN COMPOSITION, RESIN SHEET, AND LAMINATED GLASS
  申请人：Kuraray Co., Ltd.

  公开号：EP4092003A1

  公开（公告）日：2022-11-23

  The present invention relates to a resin composition, comprising: a modified vinyl acetal resin which comprises 20 to 80 mol% of ethylene units and 4 to 76 mol% of vinyl alcohol units based on all monomer units constituting the resin, and has an acetalization degree of 5 to 80 mol%; and an alkali metal salt and/or an alkaline earth metal salt of a strong acid, wherein a total content of the alkali metal salt and/or the alkaline earth metal salt of the strong acid is 0.0005 to 0.06 part by mass with respect to 100 parts by mass of the modified vinyl acetal resin.

  本发明涉及一种树脂组合物，包括 改性乙烯基缩醛树脂，该树脂包含 20 至 80 摩尔%的乙烯单元和 4 至 76 摩尔%的乙烯醇单元（以构成该树脂的所有单体单元计），缩醛度为 5 至 80 摩尔%；以及 强酸的碱金属盐和/或碱土金属盐、 其中，相对于 100 质量份的改性乙烯基缩醛树脂，碱金属盐和/或强酸的碱土金属盐的总含量为 0.0005 至 0.06 质量份。