monocyclohexyl adipate | 54812-72-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: monocyclohexyl adipate
• 英文别名: 6-(Cyclohexyloxy)-6-oxohexanoic acid；6-cyclohexyloxy-6-oxohexanoic acid
• CAS: 54812-72-5
• 化学式: C₁₂H₂₀O₄
• 分子量: 228.288
• InChiKey: DQSJGBWCBXHQCT-UHFFFAOYSA-N

物化性质

• 沸点：
  170-171 °C(Press: 1.5 Torr)
• 密度：
  1.0697 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 危险性防范说明：
  P501,P270,P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313,P301+P312+P330
• 危险性描述：
  H302,H315,H319

反应信息

• 作为反应物：
  描述：

  2-乙基己醇 、 monocyclohexyl adipate 在 硫酸 作用下， 以 甲苯 为溶剂， 以97%的产率得到cyclohexanol isooctyl adipate
  参考文献：
  名称：

  不对称己二酸环己醇异辛醇酯及其合成方法和应用

  摘要：

  本发明提供了一种不对称己二酸环己醇异辛醇酯及其合成方法和应用，由贵州省科技厅科技基金项目(黔科合J字[2015]2003号)和安顺学院博士基金项目(asubsjj201501)联合资助。其合成具体步骤为：将催化剂、带水剂、己二酸及环己醇加入到反应器中，加热回流分水，至无水生成；再向反应器中加入异辛醇，继续加热回流分水，至无水生成，冷却至室温；然后旋蒸除去带水剂；最后减压蒸馏得到不对称己二酸环己醇异辛醇酯。本发明作为环保增塑剂具有增塑效果好、耐寒性好、PVC制品柔软性好等优点。

  公开号：

  CN105503589A
• 作为产物：
  描述：

  己二酸 、 环己醇 在 硫酸 作用下， 以 甲苯 为溶剂， 生成 monocyclohexyl adipate
  参考文献：
  名称：

  不对称己二酸环己醇异辛醇酯及其合成方法和应用

  摘要：

  本发明提供了一种不对称己二酸环己醇异辛醇酯及其合成方法和应用，由贵州省科技厅科技基金项目(黔科合J字[2015]2003号)和安顺学院博士基金项目(asubsjj201501)联合资助。其合成具体步骤为：将催化剂、带水剂、己二酸及环己醇加入到反应器中，加热回流分水，至无水生成；再向反应器中加入异辛醇，继续加热回流分水，至无水生成，冷却至室温；然后旋蒸除去带水剂；最后减压蒸馏得到不对称己二酸环己醇异辛醇酯。本发明作为环保增塑剂具有增塑效果好、耐寒性好、PVC制品柔软性好等优点。

  公开号：

  CN105503589A

文献信息

• Plasticizer composition, plasticized polyvinyl butyral and interlayer thereof
  申请人：MONSANTO COMPANY

  公开号：EP0432124A2

  公开（公告）日：1991-06-12

  A composition of matter and an interlayer formed of such composition for a laminated glazing comprising polyvinyl butyral resin plasticized with a mixed adipate or a mixture of pure and mixed adipates made from: (a) at least one C₄ to C₉, preferably C₆, alkyl alcohol and (b) at least one cyclo (C₄ to C₁₀), preferably C₆, alcohol wherein the proportions of (a) and (b) in parts by weight per 100 parts of (a) and (b) are: (a) 10-90, preferably 30-80 and (b) 90-10, preferably 70-20. Also, a composition of matter comprising a mixed adipate or a mixture of pure and mixed adipates made from the alcohols of (a) and (b) above at the alcohol proportions noted above.

  一种用于层压玻璃的物质组合物和由该组合物形成的中间膜，其包含用混合己二酸酯或纯己二酸酯和混合己二酸酯的混合物塑化的聚乙烯醇缩丁醛树脂，该混合物由以下物质制成：(a) 至少一种 C₄至 C₉，最好是 C₆的烷基醇，和 (b) 至少一种环（C₄至 C₁₀），最好是 C₆的醇， 其中(a)和(b)的重量份数比例为每 100 份(a)和(b)的重量份数：(a) 10-90，优选 30-80；(b) 90-10，优选 70-20。另外，一种物质组合物，包括由上述(a)和(b)醇按上述醇比例制成的混合己二酸酯或纯己二酸酯和混合己二酸酯的混合物。
• Adipate compositions
  申请人：MONSANTO COMPANY

  公开号：EP0513470A2

  公开（公告）日：1992-11-19

  A composition of matter comprising a mixture of pure and mixed adipates made from: (a) n-hexanol and (b) cyclohexanol wherein the proportions of (a) and (b) in parts by weight per 100 parts of (a) and (b) are: (a)

  一种物质组合物，包括由以下物质制成的纯己二酸酯和混合己二酸酯混合物：(a) 正己醇和(b) 环己醇，其中(a)和(b)的重量份数比例为每 100 份(a)和(b)的重量份数：(a)
• INTERLAYER FOR LAMINATED GLASS AND LAMINATED GLASS
  申请人：Sekisui Chemical Co., Ltd.

  公开号：EP2623473A1

  公开（公告）日：2013-08-07

  The present invention aims to provide an intermediate film for laminated glass which, in the case of being used for constituting a laminated glass, enables to improve the sound-insulating property of a laminated glass to be obtained; and a laminated glass. The intermediate film 1 for laminated glass of the present invention comprises a first layer 2 which contains a polyvinyl acetal resin and a plasticizer and the degree of acetylation of the polyvinyl acetal resin contained in the first layer 2 exceeds 30 mol%; and The laminated glass of the present invention comprises first and second components for laminated glass, and the intermediate film 1 for laminated glass sandwiched between the first and second components for laminated glass.

  本发明的目的是提供一种夹层玻璃用中间膜，在用于构成夹层玻璃的情况下，该中间膜能够改善所获得的夹层玻璃的隔音性能；并提供一种夹层玻璃。本发明的夹层玻璃用中间膜 1 包括第一层 2，第一层 2 中含有聚乙烯醇缩醛树脂和增塑剂，第一层 2 中含有的聚乙烯醇缩醛树脂的乙酰化程度超过 30 摩尔%；以及 本发明的夹层玻璃包括夹层玻璃用第一和第二组分，以及夹在夹层玻璃用第一和第二组分之间的夹层玻璃用中间膜 1。
• LAMINATED GLASS INTERLAYER AND LAMINATED GLASS
  申请人：Sekisui Chemical Co., Ltd.

  公开号：EP2623474A1

  公开（公告）日：2013-08-07

  The present invention aims to provide an intermediate film for laminated glass which, in the case of being used for constituting a laminated glass, enables to improve the sound-insulating property of the obtained laminated glass, and a laminated glass. The intermediate film 1 for laminated glass of the present invention comprises a first layer 2 which contains a polyvinyl acetal resin and a plasticizer, and the polyvinyl acetal resin and the first plasticizer are a polyvinyl acetal resin and a first plasticizer which have a cloud point of 5°C or lower when the cloud point is measured using a solution prepared by dissolving 8 parts by weight of the polyvinyl acetal resin in 100 parts by weight of the first plasticizer; and the laminated glass 11 of the present invention comprises first and second components for laminated glass, and the intermediate film 1 for laminated glass sandwiched between the first and second components for laminated glass.

  本发明旨在提供一种用于夹层玻璃的中间膜，在用于构成夹层玻璃的情况下，该中间膜能够改善所获得的夹层玻璃和夹层玻璃的隔音性能。本发明的夹层玻璃中间膜 1 包括第一层 2，第一层 2 中含有聚乙烯醇缩醛树脂和增塑剂，聚乙烯醇缩醛树脂和第一增塑剂是聚乙烯醇缩醛树脂和第一增塑剂，在使用将 8 重量份的聚乙烯醇缩醛树脂溶解在 100 重量份的第一增塑剂中制备的溶液测量浊点时，浊点为 5°C 或更低；本发明的夹层玻璃 11 包括夹层玻璃的第一和第二组分，以及夹在夹层玻璃的第一和第二组分之间的夹层玻璃中间膜 1。
• INTERLAYER FILM FOR LAMINATED GLASS, AND LAMINATED GLASS
  申请人：Sekisui Chemical Co., Ltd.

  公开号：EP3357890A1

  公开（公告）日：2018-08-08

  There is provided an interlayer film for laminated glass with which the haze value of laminated glass can be lowered and the releasability of a lamination glass member from the interlayer film can be made moderately high. The interlayer film for laminated glass according to the present invention is a single-layered interlayer film provided with only a first layer or is a multi-layered interlayer film provided with a first layer and another layer, the first layer contains no magnesium or contains magnesium in a content of 50 ppm or less and the first layer contains a phosphorus compound having a polyoxyalkylene group or a silane compound having a polyoxyalkylene group, the first layer contains heat shielding particles in the case of the interlayer film provided with only the first layer, and at least one layer in the interlayer film contains heat shielding particles in the case of the interlayer film provided with the first layer and another layer.

  本发明提供了一种用于夹层玻璃的中间膜，使用该中间膜可以降低夹层玻璃的雾度值，并使夹层玻璃部件与中间膜的可剥离性适度提高。根据本发明的夹层玻璃中间膜是仅有第一层的单层中间膜，或者是有第一层和另一层的多层中间膜，第一层不含镁或含镁量在 50ppm 或以下，第一层含有具有聚氧亚烷基的磷化合物或具有聚氧亚烷基的硅烷化合物、在仅有第一层的夹层膜中，第一层含有热屏蔽颗粒；在有第一层和另一层的夹层膜中，夹层膜中至少有一层含有热屏蔽颗粒。