1-chloro-2-(4-chlorophenylsulfonyl)benzene | 38980-51-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-chloro-2-(4-chlorophenylsulfonyl)benzene
• 英文别名: 2-chlorophenyl 4'-chlorophenyl sulfone；2,4’-dichlorodiphenylsulfone；2,4'-dichlorodiphenylsulfone；2,4'-DCDPS；(2-chloro-phenyl)-(4-chloro-phenyl)-sulfone；(2-Chlor-phenyl)-(4-chlor-phenyl)-sulfon；Benzene, 1-chloro-2-[(4-chlorophenyl)sulfonyl]-；1-chloro-2-(4-chlorophenyl)sulfonylbenzene
• CAS: 38980-51-7
• 化学式: C₁₂H₈Cl₂O₂S
• mdl: MFCD02628066
• 分子量: 287.166
• InChiKey: YKWDWSGYZBURDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-chloro-2-(4-chlorophenylsulfonyl)benzene 在 氢氧化钾 作用下， 生成 2,4-二羟基二苯砜
  参考文献：
  名称：

  Process for producing polyhydroxyarylsulphones

  摘要：

  公开号：

  US02288282A1
• 作为产物：
  描述：

  氯苯 在 三氧化硫 、 硫酸二甲酯 作用下， 反应 1.33h， 生成 4,4'-二氯二苯砜 、 1-chloro-2-(4-chlorophenylsulfonyl)benzene
  参考文献：
  名称：

  PROCESS FOR PREPARING 4,4'-DICHLORODIPHENYL SULFONE

  摘要：

  该发明涉及一种制备4,4'-二氯二苯基砜的方法，包括对单氯苯和液态三氧化硫进行反应，其中所使用的液态三氧化硫的硼含量最多为100 ppm，基于所使用的三氧化硫的总重量，包括所有次生成分。

  公开号：

  US20110263902A1

文献信息

• Method for acylation or sulphonylation of an aromatic compound
  申请人：Rhodia Chimie

  公开号：US06348631B1

  公开（公告）日：2002-02-19

  The present invention relates to a process for the acylation or sulphonylation of an aromatic compound. More particularly, the invention relates to a process for the acylation or sulphonylation of an activated or deactivated aromatic compound. The invention is applied to the preparation of aromatic ketones or sulphones. The process for the acylation or sulphonylation of an aromatic compound which consists in reacting at least one aromatic compound with an acylating or sulphonylating agent, in the presence of a Friedel-Crafts catalyst is characterized in that the acylation or sulphonylation reaction is carried out in liquid phase under microwave irradiation.

  本发明涉及一种芳香化合物的酰化或磺化过程。 更具体地，该发明涉及一种对活化或去活化的芳香化合物进行酰化或磺化的过程。 该发明应用于芳香酮或磺酮的制备。 将至少一种芳香化合物与酰化剂或磺化剂在弗里德尔-克拉夫茨催化剂存在下反应的芳香化合物酰化或磺化过程的特征在于，在微波辐射下在液相中进行酰化或磺化反应。
• [EN] (C)CRYSTAL COMPOSITION (CC) COMPRISING 4,4'-DICHLORODIPHENYLSULFONE CRYSTALS (C)<br/>[FR] COMPOSITION DE CRISTAUX (C) (CC) COMPRENANT DES CRISTAUX DE 4,4'-DICHLORODIPHÉNYLSULFONE
  申请人：BASF SE

  公开号：WO2021037797A1

  公开（公告）日：2021-03-04

  The invention relates to crystals (C) consisting of at least 98 % by weight of 4,4'- dichlorodiphenylsulfone, 0 to 2 % by weight of impurities and 0 to 2 % by weight of at least one solvent (c). Moreover, the present invention relates to a crystal composition (CC) comprising crystals (C) and a process for the production of the crystal composition (CC) and the crystals (C).

  该发明涉及由至少98%重量的4,4'-二氯二苯基砜（C）组成的晶体，0至2%重量的杂质和0至2%重量的至少一种溶剂（c）。此外，本发明涉及包括晶体（C）的晶体组合物（CC）以及用于生产晶体组合物（CC）和晶体（C）的工艺。
• PROCESS FOR THE PRODUCTION OF A SULFONE MONOMER
  申请人：Bandodkar Hemant Ratanakar

  公开号：US20120302795A1

  公开（公告）日：2012-11-29

  The present invention provides a method for the preparation of polymer grade 4,4′-dichlorodiphenyl sulfone in steps comprising reacting dimethyl sulfate and sulfur trioxide optionally containing a catalyst; reacting the formed dimethyl pyrosulfate with the unreacted sulfur trioxide optionally in the presence of a catalyst; reacting the reaction mixture with monochlorobenzene optionally containing a catalyst; optionally removing unreacted dimethyl sulfate; isolating crude 4,4′-dichlorodiphenyl sulfone using an organic solvent/organic solvent-water mixture; recovering the solvent from mother liquor; optionally recovering the isomeric mixture of dichlorodiphenyl sulfones from mother liquor; optionally, conversion of residual isomeric mixture of dichlorodiphenyl sulfones to a product selected from diphenyl sulfone, 2-aminodiphenyl sulfone; 2,4′-dihydroxydiphenyl sulfone, 4,4′-dihydroxydiphenyl sulfone; optionally recovering monochlorobenzene sulfonic acid and/or monochlorobenzene from the mother liquor; optionally recovering sulfuric acid from the residual liquor; optionally recycling the solvent; and purifying 4,4′-dichlorodiphenyl sulfone from crude followed by crystallization. Further the present invention discloses a process in which isomeric mixture of 4,4′-, 3,4′-, and 2,4′-dichlorodiphenyl sulfone produced during the preparation of 4,4′-dichlorodiphenyl sulfone is converted to value added products such as diphenyl sulfone, 2,4′-dihydroxydiphenyl sulfone, 4,4′-dihydroxydiphenyl sulfone and 2-aminodiphenyl sulfone.

  本发明提供一种制备高分子级4,4'-二氯二苯砜的方法，包括以下步骤：反应二甲基硫酸酯和三氧化硫，可选地含有催化剂；将生成的二甲基焦硫酸酯与未反应的三氧化硫反应，可选地在存在催化剂的情况下；将反应混合物与单氯苯反应，可选地含有催化剂；可选地去除未反应的二甲基硫酸酯；使用有机溶剂/有机溶剂-水混合物分离粗4,4'-二氯二苯砜；从母液中回收溶剂；可选地从母液中回收二氯二苯砜异构体混合物；可选地将剩余的二氯二苯砜异构体混合物转化为选择自二苯砜、2-氨基二苯砜、2,4'-二羟基二苯砜、4,4'-二羟基二苯砜的产品；可选地从母液中回收单氯苯磺酸和/或单氯苯；可选地从残留液中回收硫酸；可选地回收溶剂；并通过结晶纯化粗4,4'-二氯二苯砜。此外，本发明还揭示了一种过程，其中在制备4,4'-二氯二苯砜的过程中产生的4,4'-、3,4'-和2,4'-二氯二苯砜异构体混合物转化为增值产品，例如二苯砜、2,4'-二羟基二苯砜、4,4'-二羟基二苯砜和2-氨基二苯砜。
• Thermal recording material
  申请人：Fine Ace Corporation

  公开号：US09434199B2

  公开（公告）日：2016-09-06

  A thermal recording material having both of excellent coloring property and storage stability with a low cost is provided. The thermal recording material contains a leuco dye and a developer in a coloring layer, and the developer contains 2,4′-dihydroxydiphenylsulfone and 4,4′-dihydroxydiphenylsulfone with a specific ratio, and the above-mentioned two kinds of the dihydroxydiphenylsulfones are made a material obtained by sequentially undergoing a separating step for heightening the weight ratio of a 2,4′ material from a dichlorodiphenylsulfone mixture containing the 2,4′ material and a 4,4′ material, a reaction step of hydrolyzing the mixture to obtain a dihydroxydiphenylsulfone mixture, and a post-treatment step of subjecting to decolorization and purification.

  提供了一种具有优异的着色性能和储存稳定性且成本低廉的热记录材料。该热记录材料包含一个显色层中的亚乙基染料和显影剂，显影剂包含2,4'-二羟基二苯基砜和4,4'-二羟基二苯基砜，并具有特定比例，上述两种二羟基二苯基砜是通过依次经历提高2,4'材料的重量比的分离步骤，水解混合物以获得二羟基二苯基砜混合物的反应步骤和经过脱色和纯化的后处理步骤而获得的材料。
• [EN] IMPROVED PROCESS FOR MAKING DIARYL SULFONES<br/>[FR] PROCÉDÉ AMÉLIORÉ DE PRODUCTION DE DIARYLSULFONES
  申请人：VERTELLUS SPECIALTIES INC

  公开号：WO2016201039A1

  公开（公告）日：2016-12-15

  A process for preparing diaryl sulfones, such as 4,4'-dichlorodiphenylsulfone is disclosed. The process comprises contacting an aryl compound with sulfur trioxide to provide a benzene sulfonic acid. The benzene sulfonic acid is coupled to additional aryl compound in the presence of a catalyst. During the coupling step, the additional aryl compound is continuously added while water is removed.

  公开了一种制备二芳基砜（例如4,4'-二氯二苯基砜）的过程。该过程包括将芳基化合物与三氧化硫接触以提供苯磺酸。在催化剂存在下，将苯磺酸与其他芳基化合物偶联。在偶联步骤中，不断添加其他芳基化合物，同时去除水。