(1-phenylethane-1,2-diyl)bis((4-methoxyphenyl)sulfane) | 1313220-32-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: (1-phenylethane-1,2-diyl)bis((4-methoxyphenyl)sulfane)
• 英文别名: 1-Methoxy-4-[2-(4-methoxyphenyl)sulfanyl-1-phenylethyl]sulfanylbenzene；1-methoxy-4-[2-(4-methoxyphenyl)sulfanyl-1-phenylethyl]sulfanylbenzene
• CAS: 1313220-32-4
• 化学式: C₂₂H₂₂O₂S₂
• 分子量: 382.547
• InChiKey: QJVMTEJSFYTJQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  69.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯乙烯 、 4,4'-二甲氧基二苯二硫 在 碘 作用下， 以 水 为溶剂， 反应 12.0h， 以96%的产率得到(1-phenylethane-1,2-diyl)bis((4-methoxyphenyl)sulfane)
  参考文献：
  名称：

  Iodine-catalyzed disulfidation of alkenes

  摘要：

  The disulfidation reactions of alkenes with disulfides were thoroughly investigated in this paper. Using H(2)O or DCE as the solvent, most reactions occurred smoothly to give the corresponding disulfidated products in good to high yields at room temperature within 12 h. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.04.081

文献信息

• Air-Induced Disulfenylation of Alkenes: Facile Synthesis of Vicinal Dithioethers
  作者：Guodian Yu、Yingcong Ou、Danyao Chen、Yuanting Huang、Yan Yan、Qian Chen

  DOI：10.1055/s-0039-1691493

  日期：2020.1

  A novel disulfenylation of alkenes with thiophenols and their corresponding disulfides by using air as the oxidant has been achieved. This transformation provides a facile and practical protocol for the synthesis of vicinal dithioethers under mild conditions.

  通过使用空气作为氧化剂，实现了烯烃与苯硫酚及其相应的二硫化物的新型二磺基化反应。这种转化为在温和条件下合成邻位二硫醚提供了一种简便实用的方案。
• Dithiolation of Alkenyl Sulfonium Salts with Arylthiols to Access 1,2-Dithioalkanes
  作者：Jie Zhu、Jinghui Sun、Yifei Yan、Zhuyong Dong、Yinhua Huang

  DOI：10.1021/acs.joc.3c01806

  日期：2023.11.17
• Iodine-catalyzed disulfidation of alkenes
  作者：Xiu-Ren Wang、Fan Chen

  DOI：10.1016/j.tet.2011.04.081

  日期：2011.6

  The disulfidation reactions of alkenes with disulfides were thoroughly investigated in this paper. Using H(2)O or DCE as the solvent, most reactions occurred smoothly to give the corresponding disulfidated products in good to high yields at room temperature within 12 h. (C) 2011 Elsevier Ltd. All rights reserved.