1,3-tridecanediol | 54831-33-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1,3-tridecanediol
• 英文别名: Tridecan-1,3-diol；1,3-Dihydroxytridecan；tridecane-1,3-diol
• CAS: 54831-33-3
• 化学式: C₁₃H₂₈O₂
• 分子量: 216.364
• InChiKey: HVEUXCYPTJKWQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-tridecanediol 在 chromium(VI) oxide 、 硫酸 作用下， 生成 1-hydroxy-tridecan-3-one
  参考文献：
  名称：

  Diacetyl-atractylodiol, a new acetylenic compound from Atractylodes japonica KOIDZUMI.

  摘要：

  DOI：

  10.1248/cpb.22.1943
• 作为产物：
  描述：

  (3-Decyloxiran-2-yl)methanol 在 红铝 作用下， 以 四氢呋喃 为溶剂， 以95%的产率得到1,3-tridecanediol
  参考文献：
  名称：

  2,3-环氧醇的区域选择性还原

  摘要：

  用双（2-甲氧基乙氧基）氢化铝钠（Red-al）将3-取代的2，3-环氧醇区域选择性还原成1，3-二醇是这些替代物的一般反应。

  DOI：

  10.1016/s0040-4039(00)85648-8

文献信息

• Zeolite (H-ZSM 5) catalysed regio and stereoselective reduction of 2,3-epoxy alcohols to 1,2-diols and vinylic epoxides to homoallylic alcohols with sodium cyanoborohydride
  作者：Anuradha Gupta、Yashwant D. Vankar

  DOI：10.1016/s0040-4039(98)02610-0

  日期：1999.2

  positions) undergo reduction with zeolite H-ZSM 5/NaCNBH3 combination of reagent system in refluxing dichloroethane to give 1,2-diols and homoallylic alcohols in moderate to good yields. Under these conditions acid sensitive groups such as an acetal and a THP ether are not affected which indicates the mildness of the reaction conditions.

  在回流二氯乙烷中，用沸石H-ZSM 5 / NaCNBH 3组合试剂体系，将各种2,3-环氧醇和乙烯基环氧化合物（在末端位置具有环氧部分）还原，得到1,2-二醇和均丙醇中等至良好的产量。在这些条件下，不影响酸敏感性基团如缩醛和THP醚，这表明反应条件温和。
• 1,3-FATTY DIOL COMPOUNDS AND DERIVATIVES THEREOF
  申请人：REG Life Sciences LLC

  公开号：US20180072645A1

  公开（公告）日：2018-03-15

  The disclosure relates to the field of specialty chemicals. In particular, the disclosure provides novel 1,3-fatty-diol compounds and derivatives thereof which are useful e.g., in the production of personal care products, surfactants, detergents, polymers, paints, coatings, and as emulsifiers, emollients, and thickeners in cosmetics and foods, as industrial solvents and plasticizers, etc.

  本公开涉及专业化学领域。具体而言，本公开提供了新颖的1,3-脂肪二醇化合物及其衍生物，可用于个人护理产品、表面活性剂、洗涤剂、聚合物、涂料、涂层的生产，以及作为化妆品和食品中的乳化剂、润肤剂和增稠剂，工业溶剂和增塑剂等。
• 1,3-FATTY DIOL COMPOUNDS AND GLYCOSYLATED DERIVATIVES THEREOF
  申请人：Genomatica, Inc.

  公开号：EP3795576A1

  公开（公告）日：2021-03-24

  The disclosure relates to the field of specialty chemicals. In particular, the disclosure provides novel 1,3-fatty-diol compounds and alkylpolyglycosides of formula (V), in which R1 and R2 are independently selected from the group consisting of H, a monosaccharide, a disaccharide, a trisaccharide and a polysaccharide, which are bound at an anomeric carbon. These compounds are are useful e.g. in the production of personal care products, surfactants, detergents, polymers, paints, coatings, and as emulsifiers, emollients, and thickeners in cosmetics and foods, as industrial solvents and plasticizers.

  本公开涉及特种化学品领域。特别是，本公开提供了新颖的 1,3-脂肪二醇化合物和式 (V) 烷基聚糖苷，其中 R1 和 R2 独立地选自由 H、单糖、二糖、三糖和多糖组成的组，它们在同分异构碳上结合。这些化合物可用于生产个人护理产品、表面活性剂、洗涤剂、聚合物、油漆、涂料，也可用作化妆品和食品中的乳化剂、润肤剂和增稠剂，还可用作工业溶剂和增塑剂。
• 1,3-fatty diol compounds and derivatives thereof
  申请人：REG Life Sciences LLC

  公开号：US10570074B2

  公开（公告）日：2020-02-25

  The disclosure relates to the field of specialty chemicals. In particular, the disclosure provides novel 1,3-fatty-diol compounds and derivatives thereof which are useful e.g., in the production of personal care products, surfactants, detergents, polymers, paints, coatings, and as emulsifiers, emollients, and thickeners in cosmetics and foods, as industrial solvents and plasticizers, etc.

  本公开涉及特种化学品领域。特别是，本公开提供了新型 1,3-脂肪二醇化合物及其衍生物，可用于生产个人护理产品、表面活性剂、洗涤剂、聚合物、油漆、涂料，也可用作化妆品和食品中的乳化剂、润肤剂和增稠剂，还可用作工业溶剂和增塑剂等。
• Microbial production of fatty diols
  申请人：REG Life Sciences, LLC

  公开号：US10676763B2

  公开（公告）日：2020-06-09

  The disclosure relates to fatty diols and recombinant microorganisms for producing them. More particularly, the disclosure relates to recombinant microorganisms engineered to produce fatty diols via fermentation. Further encompassed is a process that uses the microorganisms to produce fatty diols from a simple carbon source.

  本公开涉及脂肪二醇和生产脂肪二醇的重组微生物。更具体地说，本发明涉及通过发酵生产脂肪二醇的重组微生物。此外，还包括一种利用微生物从简单碳源生产脂肪二醇的工艺。