2,3-Dihydrothieno[3,4-b][1,4]dithiin-3-ylmethanol | 1019987-38-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2,3-Dihydrothieno[3,4-b][1,4]dithiin-3-ylmethanol
• 英文别名: 2,3-dihydrothieno[3,4-b][1,4]dithiin-3-ylmethanol
• CAS: 1019987-38-2
• 化学式: C₇H₈OS₃
• 分子量: 204.338
• InChiKey: BMJZIJIUKODXDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  99.1
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,3-Dihydrothieno[3,4-b][1,4]dithiin-3-ylmethanol 在 三溴化磷 作用下， 以 四氢呋喃 为溶剂， 生成 3-(Bromomethyl)-2,3-dihydrothieno[3,4-b][1,4]dithiine
  参考文献：
  名称：

  Functionalized 3,4-ethylenedithiathiophenes (EDTTs) as building blocks for poly (3,4-ethylenedithiathiophene) (PEDTT) derivatives

  摘要：

  A convenient and straightforward procedure has been developed for the preparation of functionalized 3,4-ethylenedithiathiophene (EDTT) derivatives by using a new bromomethyl-EDTT derivative as a versatile synthon. Based on this procedure a novel EDTT derivative endowed with 9,10-anthraquinone moieties has been synthesized and electrochemically polymerized to yield a donor-acceptor PEDTT derivative. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.02.004
• 作为产物：
  描述：

  3,4-二甲氧基噻吩 、 2,3-二巯基-1-丙醇 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 生成 2,3-Dihydrothieno[3,4-b][1,4]dithiin-3-ylmethanol
  参考文献：
  名称：

  Functionalized 3,4-ethylenedithiathiophenes (EDTTs) as building blocks for poly (3,4-ethylenedithiathiophene) (PEDTT) derivatives

  摘要：

  A convenient and straightforward procedure has been developed for the preparation of functionalized 3,4-ethylenedithiathiophene (EDTT) derivatives by using a new bromomethyl-EDTT derivative as a versatile synthon. Based on this procedure a novel EDTT derivative endowed with 9,10-anthraquinone moieties has been synthesized and electrochemically polymerized to yield a donor-acceptor PEDTT derivative. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.02.004

文献信息

• Functionalized 3,4-ethylenedithiathiophenes (EDTTs) as building blocks for poly (3,4-ethylenedithiathiophene) (PEDTT) derivatives
  作者：Raúl Blanco、Carlos Seoane、José L. Segura

  DOI：10.1016/j.tetlet.2008.02.004

  日期：2008.3

  A convenient and straightforward procedure has been developed for the preparation of functionalized 3,4-ethylenedithiathiophene (EDTT) derivatives by using a new bromomethyl-EDTT derivative as a versatile synthon. Based on this procedure a novel EDTT derivative endowed with 9,10-anthraquinone moieties has been synthesized and electrochemically polymerized to yield a donor-acceptor PEDTT derivative. (C) 2008 Elsevier Ltd. All rights reserved.