9-(2-ethylhexyl)-9H-carbazol-3-amine | 1001164-83-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-(2-ethylhexyl)-9H-carbazol-3-amine
• 英文别名: 3-amino-9-(2-ethylhexyl)carbazole；9-(2-Ethylhexyl)carbazol-3-amine；9-(2-ethylhexyl)carbazol-3-amine
• CAS: 1001164-83-5
• 化学式: C₂₀H₂₆N₂
• 分子量: 294.44
• InChiKey: DESVXHKKPFNUSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  31
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-(1,4-dihydro-4-oxo-6-undecylpyrimidin-2-yl)-1H-imidazole-1-carboxamide 、 9-(2-ethylhexyl)-9H-carbazol-3-amine 以 二氯甲烷 为溶剂， 以95%的产率得到1-(9-(2-ethylhexyl)-9H-carbazol-3-yl)-3-(4-oxo-6-undecyl-1,4-dihydropyrimidin-2-yl)urea
  参考文献：
  名称：

  氢键环状四聚体，基于连接到3,6-咔唑基间隔基上的尿嘧啶嘧啶酮

  摘要：

  将两个2-脲基-4- [ 1H ]-嘧啶酮（UPy）亚基直接连接到3,6-咔唑基核上可得到高粘度的超分子聚合物。但是，如MALDI-TOF，DOSY和NOESY谱所示，在UPy和咔唑之间插入亚甲基间隔基会导致形成带状排列的明确的环状四聚体。

  DOI：

  10.1021/ol200946b

文献信息

• Synthesis of 5,5′-Diarylimino Quinoidal 2,2′-Bithiazoles
  作者：Maria Koyioni、Panayiotis A. Koutentis

  DOI：10.1021/acs.orglett.6b03474

  日期：2017.1.6

  (het)arylamines and subsequent in situ Ag2O-mediated oxidation provides access to cross-conjugated quinoidal 5,5′-diarylimino-2,2′-bithiazoles in moderate to high yield. The highly colored quinoidal 2,2′-bithiazoles were studied by UV/vis spectroscopy, cyclic voltammetry and computational methods.

  Pd（0）催化5,5'-二溴-2,2'-噻唑与（het）芳胺的双C–N偶联反应以及随后的原位Ag 2 O介导的氧化作用提供了交叉共轭醌5 5'-diarylimino-2,2'-bithiazoles，中等至高收率。通过紫外/可见光谱，循环伏安法和计算方法研究了高度着色的醌型2,2'-联噻唑。
• Hole transporting organic molecules containing enamine groups for optoelectronic and photoelectrochemical devices
  申请人：KAUNO TECHNOLOGIJOS UNIVERSITETAS

  公开号：US11329229B2

  公开（公告）日：2022-05-10

  The present invention relates to a compound of formula (I) based on enamine derivatives and used as organic hole conductors or hole transporting material in an optoelectronic or photoelectrochemical device. The present invention relates to the hole transporting compounds based on enamine derivatives for efficiency perovskite or dye sensitized solar cells and optoelectronic devices, organic light-emitting diode (OLED), field-effect transistors (FET).

  本发明涉及一种基于烯胺衍生物的式(I)化合物，用作光电或光电化学器件中的有机空穴导体或空穴传输材料。本发明涉及基于烯胺衍生物的空穴传输化合物，可用于高效包晶型或染料敏化型太阳能电池和光电器件、有机发光二极管（OLED）、场效应晶体管（FET）。
• [EN] HOLE TRANSPORTING ORGANIC MOLECULES CONTAINING ENAMINE GROUPS FOR OPTOELECTRONIC AND PHOTOELECTROCHEMICAL DEVICES<br/>[FR] MOLÉCULES ORGANIQUES DE TRANSPORT DE TROUS CONTENANT DES GROUPES ÉNAMINE POUR DES DISPOSITIFS OPTOÉLECTRONIQUES ET PHOTOÉLECTROCHIMIQUES
  申请人：UNIV TECH KAUNO

  公开号：WO2018051278A4

  公开（公告）日：2018-07-12
• Novel synthesis of poly(3,4-dinitro-thiophen-2-yl arylamine) derivatives via facile C–Br/N–H bulk polycondensation and its application of thermalsensor
  作者：Kai Peng、Qi Luo、Yichi Zhang、Jiangbin Xia

  DOI：10.1016/j.polymer.2020.122550

  日期：2020.6

  C-Br/N-H bulk polycondensation is firstly proposed and corresponding poly(3,4-dinitm-thiophen-2-yl aryl-amine)s derivatives have been successfully obtained with quantitative yield. Typical crystal analysis reveals that its effective reaction points distance (RPD, distance between Br and H atom) is 5.083 angstrom, which is 66.7% longer than the sum of van der Waals radius (r(w)) of bromine and hydrogen atoms (3.05 angstrom). Carbazole-based monomer was explored as a thermalsensor with excellent relative sensitivity (S-a) of 0.45% K-1.
• HOLE TRANSPORTING ORGANIC MOLECULES CONTAINING ENAMINE GROUPS FOR OPTOELECTRONIC AND PHOTOELECTROCHEMICAL DEVICES
  申请人：Kauno Technologijos Universitetas

  公开号：EP3515884A2

  公开（公告）日：2019-07-31