Bis(2-methylprop-2-enyl) benzene-1,2-dicarboxylate | 5085-00-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis(2-methylprop-2-enyl) benzene-1,2-dicarboxylate
• CAS: 5085-00-7
• 化学式: C₁₆H₁₈O₄
• 分子量: 274.31
• InChiKey: HCUWXGSNCVPNHI-UHFFFAOYSA-N

物化性质

• 沸点：
  165-175 °C(Press: 1 Torr)
• 密度：
  1.079±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  20
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  disodium;phthalate 、 3-氯-2-甲基丙烯 生成 Bis(2-methylprop-2-enyl) benzene-1,2-dicarboxylate
  参考文献：
  名称：

  OTA, XIDEHNORI;SATO, TOSIXIRO;KOBAYASI, MASAO

  摘要：

  DOI：

文献信息

• HOLOGRAM RECORDING MATERIAL
  申请人：NITTO DENKO CORPORATION

  公开号：EP1873593A1

  公开（公告）日：2008-01-02

  The present invention provides a hologram recording material which can modulate its refractive index effectively with visible light laser and is excellent also in transparency after this modulation. The present invention relates to a hologram recording material comprising a polymer (A) having a radically polymerizable side chain vinyl group in the molecule thereof, said polymer (A) being a polymer of monomers comprising as an essential component an acryl-vinyl monomer represented by the following formula (1): C⁢H2=CR1⁢C=O⁢O-R2=C⁢H2 wherein R1 represents a hydrogen atom or methyl group, and R2 represents a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms, which may contain hetero atoms or halogen atoms in the molecule thereof; and a photopolymerization initiation source (B) which generates an active seed by visible light, and particularly relates to a hologram recording material having the aforementioned constitution in which the aforementioned photopolymerization initiation source (B) is a photopolymerization initiator which absorbs visible light to generate an active seed or a mixture of visible light-sensitizing dye and photopolymerization initiator.

  本发明提供了一种全息图记录材料，它可以用可见光激光有效地调节其折射率，并且在调节后透明度极佳。本发明涉及一种全息图记录材料，它包括一种聚合物（A），其分子中具有可辐射聚合的侧链乙烯基，所述聚合物（A）是一种单体聚合物，其基本成分包括由下式（1）表示的丙烯酰乙烯基单体：C⁢H2=CR1⁢C=O⁢O-R2=C⁢H2 其中 R1 代表氢原子或甲基，R2 代表具有 1 至 20 个碳原子的饱和或不饱和烃基，其分子中可含有杂原子或卤素原子；以及通过可见光产生活性种子的光聚合引发源 (B)，尤其涉及具有上述结构的全息图记录材料，其中上述光聚合引发源 (B) 是吸收可见光产生活性种子的光聚合引发剂或可见光敏化染料和光聚合引发剂的混合物。
• POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL, AND MOLDED ARTICLE
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3722840A1

  公开（公告）日：2020-10-14

  The polymerizable composition for an optical material of the present invention includes an allyl carbonate compound (A) including two or more allyloxycarbonyl groups which is represented by General Formula (1); a (meth)acrylate compound (B) including two or more (meth)acryl groups which is represented by General Formula (2); at least one kind of compound (C), selected from compounds represented by General Formulas (3) to (6) and dyes described below; and a polymerization initiator (D) including at least a radical polymerization initiator (D1) and a radical polymerization initiator (D2), in which, in 100% by weight in a total of the compound (A) and the compound (B), the compound (A) is included in an amount of more than 0% by weight and 30% by weight or less and the compound (B) is included in an amount of 70% by weight or more and less than 100% by weight, the radical polymerization initiator (D1) has a radical residual ratio after 5 hours at 50°C of 20% or more and less than 100% and a radical residual ratio after 5 hours at 70°C of 0% or more and less than 30%, and the radical polymerization initiator (D2) has a radical residual ratio after 5 hours at 70°C of 30% or more and less than 98%.

  本发明光学材料的可聚合组合物包括通式(1)表示的包括两个或两个以上烯丙氧羰基的碳酸烯丙酯化合物(A)；通式(2)表示的包括两个或两个以上(甲基)丙烯酰基的(甲基)丙烯酸酯化合物(B)；至少一种化合物(C)，选自通式(3)至(6)表示的化合物和下述染料；和聚合引发剂 (D)，至少包括自由基聚合引发剂 (D1) 和自由基聚合引发剂 (D2)，其中化合物 (A) 和化合物 (B) 的总重量为 100%，化合物 (A) 的含量大于 0%（以重量计）且小于 30%（以重量计），化合物 (B) 的含量大于 70%（以重量计）且小于 100%（以重量计）、自由基聚合引发剂（D1）在 50°C 下 5 小时后的自由基残留率为 20%或以上且小于 100%，在 70°C 下 5 小时后的自由基残留率为 0%或以上且小于 30%，自由基聚合引发剂（D2）在 70°C 下 5 小时后的自由基残留率为 30%或以上且小于 98%。
• Polymerizable composition for optical material and molded product
  申请人：Mitsui Chemicals, Inc.

  公开号：US11248077B2

  公开（公告）日：2022-02-15

  A polymerizable composition for an optical material of the present invention includes (A) an allyl carbonate compound represented by General Formula (1) and including two or more allyloxycarbonyl groups; (B) a (meth)acrylate compound represented by General Formula (2) and including two or more (meth)acryl groups; and (C) a photochromic compound, in which, in 100% by weight in a total of the compound (A) and the compound (B), the compound (A) is included in an amount of more than 0% by weight and 30% by weight or less and the compound (B) is included in an amount of 70% by weight or more and less than 100% by weight.

  本发明光学材料的可聚合组合物包括：(A)通式(1)代表的碳酸烯丙酯化合物，包括两个或两个以上的烯丙氧羰基；(B)通式(2)代表的(甲基)丙烯酸酯化合物，包括两个或两个以上的(甲基)丙烯酰基；(C) 一种光致变色化合物，其中化合物(A)和化合物(B)的总重量为 100%，化合物(A)的含量为 0%以上 30%以下，化合物(B)的含量为 70%以上 100%以下。
• OTA, XIDEHNORI;SATO, TOSIXIRO;KOBAYASI, MASAO
  作者：OTA, XIDEHNORI、SATO, TOSIXIRO、KOBAYASI, MASAO

  DOI：——

  日期：——
• Resin composition for cast polymerization
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0430209B1

  公开（公告）日：1996-02-28