5-(3-fluorophenyl)-2,3-diphenylpyrazine | 1030621-68-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(3-fluorophenyl)-2,3-diphenylpyrazine
• CAS: 1030621-68-1
• 化学式: C₂₂H₁₅FN₂
• 分子量: 326.373
• InChiKey: ZUNSXJWKZIAZRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride trihydrate 、 5-(3-fluorophenyl)-2,3-diphenylpyrazine 以 乙二醇乙醚 、 水 为溶剂， 反应 5.0h， 以12%的产率得到
  参考文献：
  名称：

  트리아릴피라진 유도체의 제조방법

  摘要：

  本发明涉及三芳基吡啶衍生物的新合成方法，特别是在2,3,5-三芳基吡啶衍生物中，具有电子亲合性取代基的芳基在第5位位置的三芳基吡啶衍生物的合成方法，相对于传统方法可以提供更高产率的合成方法。

  公开号：

  KR101604237B1
• 作为产物：
  描述：

  5,6-二苯基-2,3-二羟基吡嗪 在 正丁基锂 、 potassium hydroxide 作用下， 以 四氢呋喃 、 正己烷 、 甘油 为溶剂， 反应 1.83h， 生成 5-(3-fluorophenyl)-2,3-diphenylpyrazine
  参考文献：
  名称：

  트리아릴피라진 유도체의 제조방법

  摘要：

  本发明涉及三芳基吡啶衍生物的新合成方法，特别是在2,3,5-三芳基吡啶衍生物中，具有电子亲合性取代基的芳基在第5位位置的三芳基吡啶衍生物的合成方法，相对于传统方法可以提供更高产率的合成方法。

  公开号：

  KR101604237B1

文献信息

• Light-emitting device
  申请人：Ohsawa Nobuharu

  公开号：US20080149923A1

  公开（公告）日：2008-06-26

  Light-emitting elements having high emission efficiency and long lifetime can be provided. By forming light-emitting devices including the light-emitting elements, the light-emitting devices having low power consumption and long lifetime can be provided. A light-emitting device comprises a light-emitting element including a light-emitting layer between a first electrode and a second electrode. The light-emitting layer includes a first organic compound having a hole-transporting property, a second organic compound having an electron transporting property, and an organometallic complex. A central metal of the organometallic complex is an element belonging to one of Group 9 and Group 10, and a ligand of the organometallic complex is a ligand having a pyrazine skeleton.

  可以提供具有高发射效率和长寿命的发光元件。通过形成包括这些发光元件的发光装置，可以提供低功耗和长寿命的发光装置。发光装置包括一个发光元件，该元件包括第一电极和第二电极之间的发光层。发光层包括具有传输空穴特性的第一有机化合物、具有电子传输特性的第二有机化合物和有机金属配合物。有机金属配合物的中心金属属于第9组和第10组元素，配体为具有吡嗪骨架的配体。
• Method for manufacturing triarylpyrazine derivative
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US07993494B2

  公开（公告）日：2011-08-09

  A novel synthesis method of a triarylpyrazine derivative, in particular, a manufacturing method by which a triarylpyrazine derivative, in specific, a 2,3,5-triarylpyrazine derivative in which an aryl group at a 5-position includes a substituent having an electron-withdrawing property can be synthesized with high yield as compared to a conventional method is provided. By using a synthesis method in which a mixture including a 1-aryl-2-(methylsulfinyl)ethanone derivative, meso-1,2-diarylethylenediamine, and a dehydrogenation agent is irradiated with a microwave to be reacted, the above object is achieved.

  一种新的三芳基吡嗪衍生物合成方法，特别是一种制造方法，其中比传统方法更高产率地合成三芳基吡嗪衍生物，特别是一种2,3,5-三芳基吡嗪衍生物，其中5位芳基包括具有电子吸引性取代基。通过使用混合物合成方法，包括1-芳基-2-（甲基磺酰基）乙酮衍生物，meso-1,2-二芳基乙二胺和脱氢剂，通过微波辐射反应，达到上述目的。
• Method for Manufacturing Triarylpyrazine Derivative
  申请人：Inoue Hideko

  公开号：US20090183982A1

  公开（公告）日：2009-07-23

  A novel synthesis method of a triarylpyrazine derivative, in particular, a manufacturing method by which a triarylpyrazine derivative, in specific, a 2,3,5-triarylpyrazine derivative in which an aryl group at a 5-position includes a substituent having an electron-withdrawing property can be synthesized with high yield as compared to a conventional method is provided. By using a synthesis method in which a mixture including a 1-aryl-2-(methylsulfinyl)ethanone derivative, meso-1,2-diarylethylenediamine, and a dehydrogenation agent is irradiated with a microwave to be reacted, the above object is achieved.

  提供了一种新颖的三芳基吡嗪衍生物的合成方法，特别是一种制造方法，通过该方法可以比传统方法更高产地合成具有电子吸引性取代基的5位芳基的2,3,5-三芳基吡嗪衍生物。通过使用一种混合物，包括1-芳基-2-（甲基亚磺酰基）乙酮衍生物，meso-1,2-二芳基乙二胺和脱氢剂，在微波辐射下反应，实现了上述目标。
• Light-emitting device using organometallic complex
  申请人：Ohsawa Nobuharu

  公开号：US10129947B2

  公开（公告）日：2018-11-13

  Light-emitting elements having high emission efficiency and long lifetime can be provided. By forming light-emitting devices including the light-emitting elements, the light-emitting devices having low power consumption and long lifetime can be provided. A light-emitting device comprises a light-emitting element including a light-emitting layer between a first electrode and a second electrode. The light-emitting layer includes a first organic compound having a hole-transporting property, a second organic compound having an electron transporting property, and an organometallic complex. A central metal of the organometallic complex is an element belonging to one of Group 9 and Group 10, and a ligand of the organometallic complex is a ligand having a pyrazine skeleton.

  可提供具有高发射效率和长寿命的发光元件。通过形成包括这些发光元件的发光器件，可以提供低功耗和长寿命的发光器件。发光器件包括发光元件，发光元件包括位于第一电极和第二电极之间的发光层。发光层包括具有空穴传输特性的第一有机化合物、具有电子传输特性的第二有机化合物和有机金属复合物。有机金属复合物的中心金属是属于第 9 族和第 10 族之一的元素，有机金属复合物的配体是具有吡嗪骨架的配体。
• Light-emitting device using organometallic complex having a pyrazine skeleton
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10764974B2

  公开（公告）日：2020-09-01

  Light-emitting elements having high emission efficiency and long lifetime can be provided. By forming light-emitting devices including the light-emitting elements, the light-emitting devices having low power consumption and long lifetime can be provided. A light-emitting device comprises a light-emitting element including a light-emitting layer between a first electrode and a second electrode. The light-emitting layer includes a first organic compound having a hole-transporting property, a second organic compound having an electron transporting property, and an organometallic complex. A central metal of the organometallic complex is an element belonging to one of Group 9 and Group 10, and a ligand of the organometallic complex is a ligand having a pyrazine skeleton.

  可提供具有高发射效率和长寿命的发光元件。通过形成包括这些发光元件的发光器件，可以提供低功耗和长寿命的发光器件。发光器件包括发光元件，发光元件包括位于第一电极和第二电极之间的发光层。发光层包括具有空穴传输特性的第一有机化合物、具有电子传输特性的第二有机化合物和有机金属复合物。有机金属复合物的中心金属是属于第 9 族和第 10 族之一的元素，有机金属复合物的配体是具有吡嗪骨架的配体。