1-Acetoxymethyl-cyclopentadien | 2619-26-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-Acetoxymethyl-cyclopentadien
• 英文别名: 1-acetoxymethyl-cyclopenta-1,3-diene；Cyclopenta-1,3-dien-1-ylmethyl acetate
• CAS: 2619-26-3
• 化学式: C₈H₁₀O₂
• 分子量: 138.166
• InChiKey: RRCVMVRQUOAQEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Acetoxymethyl-cyclopentadien 在 sodium methylate 、 溶剂黄146 、 锌 作用下， 以 氯仿 为溶剂， 生成 1-Hydroxymethyl-cis-1--4-hydroxy-cyclopenten-(2)
  参考文献：
  名称：

  Kresze,G. et al., Justus Liebigs Annalen der Chemie, 1963, vol. 666, p. 45 - 53

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸氯甲酯 、 环戊二烯 生成 1-Acetoxymethyl-cyclopentadien
  参考文献：
  名称：

  Kresze,G. et al., Justus Liebigs Annalen der Chemie, 1963, vol. 666, p. 45 - 53

  摘要：

  DOI：

文献信息

• MONOMER HAVING ELECTRON-WITHDRAWING SUBSTITUENT AND LACTONE SKELETON, POLYMERIC COMPOUND, AND PHOTORESIST COMPOSITION
  申请人：Koyama Hiroshi

  公开号：US20100297555A1

  公开（公告）日：2010-11-25

  Disclosed is a monomer having an electron-withdrawing substituent and a lactone skeleton, represented by following Formula (1), wherein R a represents, e.g., a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; R 1 represents, e.g., a halogen atom or an alkyl or haloalkyl group having 1 to 6 carbon atoms; “A” represents an alkylene group having 1 to 6 carbon atoms, oxygen atom, sulfur atom, or nonbonding; “m” denotes an integer of 0 to 8; Xs each represent an electron-withdrawing substituent; “n” denotes an integer of 1 to 9; and Y represents a bivalent organic group having 1 to 6 carbon atoms. The monomer is useful typically as a monomer component typically for a highly functional polymer, because, when the monomer is applied typically to a resist resin, the resin is satisfactory stable and resistant typically to chemicals, is highly soluble in organic solvents, and has improved hydrolyzability and/or solubility in water after hydrolysis.

  揭示了一种具有吸电子取代基和内酯骨架的单体，由以下式（1）表示，其中R代表，例如，氢原子或具有1至6个碳原子的烷基基团；R1代表，例如，卤素原子或具有1至6个碳原子的烷基或卤代烷基基团；“A”代表具有1至6个碳原子的烷基基团、氧原子、硫原子或非键合基团；“m”表示0至8的整数；Xs各自代表吸电子取代基；“n”表示1至9的整数；Y代表具有1至6个碳原子的二价有机基团。该单体通常用作高功能聚合物的单体组分，因为当该单体通常应用于抗蚀树脂时，树脂通常具有较高的稳定性和抗化学品性能，对有机溶剂具有较高的溶解性，并在水解后具有改善的水解性和/或水溶性。
• Polycyclic Ester Containing Cyano Group and Lactone Skeleton
  申请人：Inoue Keizo

  公开号：US20080319160A1

  公开（公告）日：2008-12-25

  Disclosed is a polycyclic ester containing a cyano group and a lactone skeleton, represented by following Formula (1): wherein R a represents, for example, a hydrogen atom or an alkyl group having one to six carbon atoms which may have a halogen atom; R 1 s each represent, for example, a halogen atom or an alkyl or haloalkyl group having one to six carbon atoms; “m” is the number of R 1 s; “n” is the number of cyano groups; and CH 2 ═C(R a )COO— group may have either of an endo conformation and an exo conformation. Accordingly, there is provided a novel polycyclic ester containing a cyano group and a lactone skeleton which is useful typically as a monomeric component for highly functional polymers. A polymer, for example, derived from this compound is highly soluble in an organic solvent while remaining stable typically to chemicals and exhibits improved hydrolyzability and/or improved solubility in water after hydrolysis.

  本发明公开了一种含有氰基和内酯骨架的多环酯，其化学式如下（1）所示：其中，R是氢原子或具有1-6个碳原子的烷基基团，该基团可以具有卤原子；R1分别表示卤原子或具有1-6个碳原子的烷基或卤代烷基基团；“m”是R1的数量；“n”是氰基的数量；而CH2═C(Ra)COO—基团可以具有内式构象或外式构象。因此，本发明提供了一种新型的含有氰基和内酯骨架的多环酯，通常可用作高功能聚合物的单体组分。例如，由该化合物衍生的聚合物在有机溶剂中高度溶解，同时在化学上保持稳定，并在水解后表现出改善的水解性和/或改善的水溶性。
• POLYCYCLIC ESTER CONTAINING CYANO GROUP AND LACTONE SKELETON
  申请人：Inoue Keizo

  公开号：US20100081778A1

  公开（公告）日：2010-04-01

  Disclosed is a polycyclic ester containing a cyano group and a lactone skeleton, represented by following Formula (1): wherein R a represents, for example, a hydrogen atom or an alkyl group having one to six carbon atoms which may have a halogen atom; R 1 s each represent, for example, a halogen atom or an alkyl or haloalkyl group having one to six carbon atoms; “m” is the number of R 1 s; “n” is the number of cyano groups; and CH 2 ═C(R a )COO— group may have either of an endo conformation and an exo conformation. Accordingly, there is provided a novel polycyclic ester containing a cyano group and a lactone skeleton which is useful typically as a monomeric component for highly functional polymers. A polymer, for example, derived from this compound is highly soluble in an organic solvent while remaining stable typically to chemicals and exhibits improved hydrolyzability and/or improved solubility in water after hydrolysis.

  本发明公开了一种多环酯，其含有氰基和内酯骨架，由以下式（1）表示：其中，R代表氢原子或具有1至6个碳原子的烷基，其可能具有卤素原子；R1分别表示卤素原子或具有1至6个碳原子的烷基或卤代烷基；“m”是R1的数量；“n”是氰基的数量；而CH2═C(Ra)COO-基团可以具有内式构象和外式构象。因此，本发明提供了一种新型的多环酯，其含有氰基和内酯骨架，通常作为高功能聚合物的单体组分非常有用。例如，从该化合物衍生的聚合物在有机溶剂中高度溶解，同时保持对化学物质的稳定性，并在水解后表现出改善的水解性和/或改善的水溶性。
• CYANO-CONTAINING POLYCYCLIC ESTERS HAVING LACTONE SKELETONS
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1930328B1

  公开（公告）日：2012-06-13
• MONOMER, RESIN FOR PHOTORESIST, RESIN COMPOSITION FOR PHOTORESIST, AND PATTERN FORMING METHOD
  申请人：DAICEL CORPORATION

  公开号：US20220267494A1

  公开（公告）日：2022-08-25

  Provided is a monomer that improves solubility in organic solvents, hydrolyzability, and solubility in water after hydrolysis of a resin as well as imparts higher heat resistance to a resin. A resin for a photoresist containing a polymerization unit represented by Formula (Y), wherein R h represents a halogen atom or an alkyl group having from 1 to 6 carbons and having a halogen atom; R 1 is a substituent attached to a ring and represents a halogen atom, an alkyl group that has from 1 to 6 carbons and may have a halogen atom, a hydroxyalkyl group that has from 1 to 6 carbons and may have a halogen atom and has a hydroxyl group moiety which may be protected by a protecting group, a carboxyl group that may form a salt, or a substituted oxycarbonyl group; A represents an alkylene group having from 1 to 6 carbons, an oxygen atom, a sulfur atom, or no bond; m is the number of R 1 and represents an integer from 0 to 8; X represents an electron-withdrawing substituent; n is the number of X and represents an integer from 1 to 9; B represents a single bond or a linking group; and a steric position of a COOB-group attached to a polymer chain may be either endo or exo.