5-methyl-4-(2-thiazolylazo)resorcinoxy ethyl vinyl ether | 1219448-30-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 5-methyl-4-(2-thiazolylazo)resorcinoxy ethyl vinyl ether
• 英文别名: [2,4-Bis(2-ethenoxyethoxy)-6-methylphenyl]-(1,3-thiazol-2-yl)diazene；[2,4-bis(2-ethenoxyethoxy)-6-methylphenyl]-(1,3-thiazol-2-yl)diazene
• CAS: 1219448-30-2
• 化学式: C₁₈H₂₁N₃O₄S
• 分子量: 375.448
• InChiKey: OSNVZJYYGJGJEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  26
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  5-methyl-4-(2-thiazolylazo)resorcinoxy ethyl vinyl ether 在 盐酸 、 水 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 以86%的产率得到5-methyl-4-(2-thiazolylazo)resorcinoxyethanol
  参考文献：
  名称：

  新型Y型含三氰乙烯基噻唑的聚氨酯的合成及其非线性光学性质。

  摘要：

  一种新型的Y型聚[亚氨基羰基氧乙基-5-甲基-4- {2-噻唑基唑基-4-（1,2,2-三氰基乙烯基）}间苯二氧基乙氧基羰基亚氨基（（3,3'-二甲氧基-4,4'-联苯））]制备并表征了4个含有5-甲基-4- {5-（1,2,2-三氰基乙烯基）-2-噻唑基偶氮}间苯二酚氧基作为非线性光学（NLO）发色团的结构，该结构构成了聚合物骨架的一部分。聚氨酯4可溶于常见的有机溶剂，例如丙酮和N，N-二甲基甲酰胺。在热重分析热分析图和玻璃化转变温度（T g从差示扫描量热法热分析图获得的温度为118℃左右。极化聚合物薄膜在1560 nm基本波长处的二次谐波产生系数（d 33）约为8.43×10 -9 esu。即使在高于T g的12°C时，偶极排列也表现出热稳定性，并且由于聚合物结构的部分主链特性，低于130°C时SHG不会衰减，这对于NLO器件应用是可以接受的。©2010 Wiley Periodicals，Inc

  DOI：

  10.1002/pola.23875
• 作为产物：
  描述：

  2-氯乙基乙烯基醚 、 5-甲基-4-(2-噻唑偶氮)雷琐辛 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 15.0h， 以88%的产率得到5-methyl-4-(2-thiazolylazo)resorcinoxy ethyl vinyl ether
  参考文献：
  名称：

  新型Y型含三氰乙烯基噻唑的聚氨酯的合成及其非线性光学性质。

  摘要：

  一种新型的Y型聚[亚氨基羰基氧乙基-5-甲基-4- {2-噻唑基唑基-4-（1,2,2-三氰基乙烯基）}间苯二氧基乙氧基羰基亚氨基（（3,3'-二甲氧基-4,4'-联苯））]制备并表征了4个含有5-甲基-4- {5-（1,2,2-三氰基乙烯基）-2-噻唑基偶氮}间苯二酚氧基作为非线性光学（NLO）发色团的结构，该结构构成了聚合物骨架的一部分。聚氨酯4可溶于常见的有机溶剂，例如丙酮和N，N-二甲基甲酰胺。在热重分析热分析图和玻璃化转变温度（T g从差示扫描量热法热分析图获得的温度为118℃左右。极化聚合物薄膜在1560 nm基本波长处的二次谐波产生系数（d 33）约为8.43×10 -9 esu。即使在高于T g的12°C时，偶极排列也表现出热稳定性，并且由于聚合物结构的部分主链特性，低于130°C时SHG不会衰减，这对于NLO器件应用是可以接受的。©2010 Wiley Periodicals，Inc

  DOI：

  10.1002/pola.23875

文献信息

• Synthesis and nonlinear optical properties of novel Y-type polyester containing tricyanovinylthiazolylazoresorcinoxy group with enhanced thermal stability of dipole alignment
  作者：You Jin Cho、Hyo Jin No、Mi Sung Kim、Ju-Yeon Lee

  DOI：10.1002/pola.24603

  日期：2011.4.15

  Novel Y‐type polyester 4 containing 5‐methyl‐4‐5‐(1,2,2‐tricyanovinyl)‐2‐thiazolylazo}resorcinoxy groups as nonlinear optical (NLO) chromophores, which are parts of the polymer backbone, was prepared, and its NLO properties were investigated. Polyester 4 is soluble in common organic solvents such as N,N‐dimethylformamide and dimethylsulfoxide. Polymer 4 shows a thermal stability up to 250 °C from

  制备了新型的Y型聚酯4，该聚酯包含5-甲基-4- 5-（1,2,2-三氰基乙烯基）-2-噻唑基偶氮}间苯二酚氧基作为非线性光学（NLO）生色团，是聚合物骨架的一部分。 ，并对其NLO性质进行了研究。聚酯4可溶于常见的有机溶剂，例如N，N-二甲基甲酰胺和二甲基亚砜。聚合物4在热重分析中显示出最高250°C的热稳定性，而差示扫描量热法在约94°C的条件下获得了玻璃化转变温度。极化聚合物薄膜在1560nm基本波长处的二次谐波产生（SHG）系数（d 33）为8.12×10 -9易。即使在比玻璃化转变温度（T g）高6°C的条件下，偶极排列仍显示出热稳定性，并且由于聚合物结构的部分主链特性，低于100°C时未观察到明显的SHG衰减。 NLO设备应用程序。©2011 Wiley Periodicals，Inc. J Polym Sci A部分：Polym Chem，2011年
• Synthesis and Nonlinear Optical Properties of Novel Y-Type Polyurethane Containing Cyanovinylthiazole
  作者：Hyo Jin No、You Jin Cho、Ju-Yeon Lee

  DOI：10.1080/15421400903584382

  日期：2010.4.13

  A novel Y-type polyurethane 4 containing 5-methyl-4-5-(1,2,2-tricyanovinyl)-2-thiazolylazo}resorcinoxy groups as nonlinear optical (NLO)-chromophores, which constituted parts of the polymer backbones, was prepared and characterized. Polyurethane 4 is soluble in common organic solvents such as acetone and N,N-dimethylformamide. It showed a thermal stability up to 250 degrees C in thermogravimetric analysis thermogram and the glass-transition temperature (T-g) obtained from differential scanning calorimetry thermogram was around 118 degrees C. The second harmonic generation (SHG) coefficient (d(33)) of poled polymer film at 1560 nm fundamental wavelength was around 8.43 x 10(-9) esu. The dipole alignment exhibited a thermal stability even at 12 degrees C higher than T-g, and there was no SHG decay below 130 degrees C due to the partial main-chain character of the polymer structure, which is acceptable for nonlinear optical device applications.
• Synthesis and Properties of Novel Y-type Nonlinear Optical Polyester Containing Tricyanovinylthiazole
  作者：Hyo Jin No、Mi Sung Kim、Ju-Yeon Lee

  DOI：10.1080/15421406.2011.566072

  日期：2011.5.31

  A novel Y-type polyester 4 containing 5-methyl-4-5-(1,2,2-tricyanovinyl)-2-thiazolylazo}resorcinoxy groups as nonlinear optical (NLO) chromophores was prepared and characterized. Polyester 4 is soluble in common organic solvents such as acetone and N,N-dimethylformamide. It shows a thermal stability up to 250 degrees C from thermogravimetric analysis thermogram with a glass-transition temperature (Tg) obtained from differential scanning calorimetry thermogram of around 94 degrees C. The second harmonic generation (SHG) coefficient (d33) of poled polymer film at 1064nm fundamental wavelength is 8.12x10-9esu. The dipole alignment exhibits a thermal stability even at 6 degrees C higher than Tg and there is no significant SHG decay below 100 degrees C due to the partial main-chain character of the polymer structure, which is acceptable for nonlinear optical device applications.